综述了双金属Ni-Re催化剂催化生物质衍生物转化为高价值燃料和化学品的研究进展

IF 7.7 2区工程技术 Q1 CHEMISTRY, APPLIED

Fuel Processing Technology Pub Date : 2025-09-04 DOI:10.1016/j.fuproc.2025.108326

Pratikkumar Lakhani, Atthapon Srifa

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引用次数: 0

摘要

Ni- re双金属催化剂提供了来自Ni的氢化活性和来自ReOX的亲氧酸性的良好协同作用，允许有效地将生物质衍生分子转化为燃料和化学品。本文综述了Ni-Re催化剂的合成、结构-性能关系以及在糠醛、5-羟甲基糠醛、乙酰丙酸升级和脂肪酸酯加氢脱氧等关键转化中的应用。重点讨论了控制选择性的双功能机制、氢溢出和金属支持相互作用。还讨论了催化剂失活的挑战和再生策略。最后，提出了未来的研究方向，重点是原子级催化剂的设计、绿色氢的集成和可持续生物炼制的工业应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A comprehensive review of the catalytic transformation for biomass derivatives into high-value fuels and chemicals over bimetallic Ni-Re catalysts

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A comprehensive review of the catalytic transformation for biomass derivatives into high-value fuels and chemicals over bimetallic Ni-Re catalysts

Ni-Re bimetallic catalysts provide an excellent synergy of hydrogenation activity from Ni and oxophilic acidity from ReO_X, allowing for effective conversion of biomass-derived molecules into fuels and chemicals. This review highlights recent developments in Ni-Re catalyst synthesis, structure-performance relationships, and applications in key transformations such as furfural, 5-hydroxymethylfurfural, and levulinic acid upgrading, and hydrodeoxygenation of fatty acid esters. The discussion highlights bifunctional mechanisms, hydrogen spillover, and metal-support interactions in controlling selectivity. Catalyst deactivation challenges and regeneration strategies are also addressed. Finally, future research directions are suggested with emphasis on atomic-scale catalyst design, integration of green hydrogen, and industrial use in sustainable biorefineries.

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来源期刊

Fuel Processing Technology 工程技术-工程：化工

CiteScore

13.20

自引率

9.30%

发文量

398

审稿时长

26 days

期刊介绍： Fuel Processing Technology (FPT) deals with the scientific and technological aspects of converting fossil and renewable resources to clean fuels, value-added chemicals, fuel-related advanced carbon materials and by-products. In addition to the traditional non-nuclear fossil fuels, biomass and wastes, papers on the integration of renewables such as solar and wind energy and energy storage into the fuel processing processes, as well as papers on the production and conversion of non-carbon-containing fuels such as hydrogen and ammonia, are also welcome. While chemical conversion is emphasized, papers on advanced physical conversion processes are also considered for publication in FPT. Papers on the fundamental aspects of fuel structure and properties will also be considered.