{"title":"线性炔基n -烷氧基氨基甲酸酯转化为环碳酸溴酯。","authors":"Shyam Sathyamoorthi, Steven P Kelley","doi":"10.3390/chemistry7030099","DOIUrl":null,"url":null,"abstract":"<p><p>We present a protocol for the facile conversion of linear alkenyl <i>N</i>-alkoxy carbamates into cyclic bromo carbonates. The reaction is operationally simple, uses widely available, inexpensive reagents, and requires no rigorous exclusion of air or moisture. A broad range of functional groups is compatible, and the reaction diastereoselectivities range from good to excellent. The reactions are scalable, and the product carbonates can be further transformed.</p>","PeriodicalId":53216,"journal":{"name":"Chemistry-Switzerland","volume":"7 3","pages":""},"PeriodicalIF":2.4000,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12380031/pdf/","citationCount":"0","resultStr":"{\"title\":\"Transformation of Linear Alkenyl <i>N</i>-Alkoxy Carbamates into Cyclic Bromo Carbonates.\",\"authors\":\"Shyam Sathyamoorthi, Steven P Kelley\",\"doi\":\"10.3390/chemistry7030099\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>We present a protocol for the facile conversion of linear alkenyl <i>N</i>-alkoxy carbamates into cyclic bromo carbonates. The reaction is operationally simple, uses widely available, inexpensive reagents, and requires no rigorous exclusion of air or moisture. A broad range of functional groups is compatible, and the reaction diastereoselectivities range from good to excellent. The reactions are scalable, and the product carbonates can be further transformed.</p>\",\"PeriodicalId\":53216,\"journal\":{\"name\":\"Chemistry-Switzerland\",\"volume\":\"7 3\",\"pages\":\"\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2025-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12380031/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry-Switzerland\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/chemistry7030099\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/6/16 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry-Switzerland","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/chemistry7030099","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/6/16 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Transformation of Linear Alkenyl N-Alkoxy Carbamates into Cyclic Bromo Carbonates.
We present a protocol for the facile conversion of linear alkenyl N-alkoxy carbamates into cyclic bromo carbonates. The reaction is operationally simple, uses widely available, inexpensive reagents, and requires no rigorous exclusion of air or moisture. A broad range of functional groups is compatible, and the reaction diastereoselectivities range from good to excellent. The reactions are scalable, and the product carbonates can be further transformed.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
