Lu Zhang, Dongxue Liu, Guiting Du, Long Cai, Wanlei Dai, Yixin Dong, Huitao Dai, Yongshuai Gong, Shengxiong Zhang, Buyi Yan and Jizhong Yao
{"title":"报告钙钛矿组件室外老化性能与室内紫外线降解趋势的相关性。","authors":"Lu Zhang, Dongxue Liu, Guiting Du, Long Cai, Wanlei Dai, Yixin Dong, Huitao Dai, Yongshuai Gong, Shengxiong Zhang, Buyi Yan and Jizhong Yao","doi":"10.1039/D5NA00622H","DOIUrl":null,"url":null,"abstract":"<p >Perovskite solar cells have made remarkable progress in laboratory-scale efficiency, positioning them as a promising next-generation photovoltaic technology. However, their long-term operational stability under real-world conditions remains a critical barrier to commercial deployment. This study presents a three-year outdoor field investigation of a micro power station composed of 20 perovskite sub-modules (FA<small><sub>0.9</sub></small>Cs<small><sub>0.1</sub></small>PbI<small><sub>3</sub></small>-based, each measuring 30 cm × 40 cm), deployed in subtropical eastern China and fabricated using scalable, industry-compatible processes. The system was continuously monitored over a three-year period to assess its long-term energy output and operational stability under real-world conditions. In parallel, we developed a spectral-accelerated ageing protocol using a tailored ultraviolet to blue-violet light spectrum, with enhanced intensity in the 390–455 nm range. This method enabled a UV dose of 60 kWh m<small><sup>−2</sup></small> at 65 °C to effectively replicate approximately two years of outdoor degradation. The excellent agreement between the UV-aged and field-aged performance validates this as a practical and predictive tool for evaluating the outdoor lifetime of perovskite modules. The sub-modules demonstrated outstanding durability, with only a 2.83% decline in power conversion efficiency after three years of continuous outdoor operation. These findings support the implementation of perovskite-specific reliability testing frameworks and align with emerging international standards such as IEC TS 63624-1, highlighting the importance of tailored UV protocols in preparing perovskite technologies for commercial deployment.</p>","PeriodicalId":18806,"journal":{"name":"Nanoscale Advances","volume":" 19","pages":" 6248-6256"},"PeriodicalIF":4.6000,"publicationDate":"2025-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12380093/pdf/","citationCount":"0","resultStr":"{\"title\":\"Report on the relevance of perovskite module outdoor ageing performance and indoor UV degradation trend\",\"authors\":\"Lu Zhang, Dongxue Liu, Guiting Du, Long Cai, Wanlei Dai, Yixin Dong, Huitao Dai, Yongshuai Gong, Shengxiong Zhang, Buyi Yan and Jizhong Yao\",\"doi\":\"10.1039/D5NA00622H\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Perovskite solar cells have made remarkable progress in laboratory-scale efficiency, positioning them as a promising next-generation photovoltaic technology. However, their long-term operational stability under real-world conditions remains a critical barrier to commercial deployment. This study presents a three-year outdoor field investigation of a micro power station composed of 20 perovskite sub-modules (FA<small><sub>0.9</sub></small>Cs<small><sub>0.1</sub></small>PbI<small><sub>3</sub></small>-based, each measuring 30 cm × 40 cm), deployed in subtropical eastern China and fabricated using scalable, industry-compatible processes. The system was continuously monitored over a three-year period to assess its long-term energy output and operational stability under real-world conditions. In parallel, we developed a spectral-accelerated ageing protocol using a tailored ultraviolet to blue-violet light spectrum, with enhanced intensity in the 390–455 nm range. This method enabled a UV dose of 60 kWh m<small><sup>−2</sup></small> at 65 °C to effectively replicate approximately two years of outdoor degradation. The excellent agreement between the UV-aged and field-aged performance validates this as a practical and predictive tool for evaluating the outdoor lifetime of perovskite modules. The sub-modules demonstrated outstanding durability, with only a 2.83% decline in power conversion efficiency after three years of continuous outdoor operation. These findings support the implementation of perovskite-specific reliability testing frameworks and align with emerging international standards such as IEC TS 63624-1, highlighting the importance of tailored UV protocols in preparing perovskite technologies for commercial deployment.</p>\",\"PeriodicalId\":18806,\"journal\":{\"name\":\"Nanoscale Advances\",\"volume\":\" 19\",\"pages\":\" 6248-6256\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-08-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12380093/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanoscale Advances\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/na/d5na00622h\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale Advances","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/na/d5na00622h","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Report on the relevance of perovskite module outdoor ageing performance and indoor UV degradation trend
Perovskite solar cells have made remarkable progress in laboratory-scale efficiency, positioning them as a promising next-generation photovoltaic technology. However, their long-term operational stability under real-world conditions remains a critical barrier to commercial deployment. This study presents a three-year outdoor field investigation of a micro power station composed of 20 perovskite sub-modules (FA0.9Cs0.1PbI3-based, each measuring 30 cm × 40 cm), deployed in subtropical eastern China and fabricated using scalable, industry-compatible processes. The system was continuously monitored over a three-year period to assess its long-term energy output and operational stability under real-world conditions. In parallel, we developed a spectral-accelerated ageing protocol using a tailored ultraviolet to blue-violet light spectrum, with enhanced intensity in the 390–455 nm range. This method enabled a UV dose of 60 kWh m−2 at 65 °C to effectively replicate approximately two years of outdoor degradation. The excellent agreement between the UV-aged and field-aged performance validates this as a practical and predictive tool for evaluating the outdoor lifetime of perovskite modules. The sub-modules demonstrated outstanding durability, with only a 2.83% decline in power conversion efficiency after three years of continuous outdoor operation. These findings support the implementation of perovskite-specific reliability testing frameworks and align with emerging international standards such as IEC TS 63624-1, highlighting the importance of tailored UV protocols in preparing perovskite technologies for commercial deployment.