{"title":"耐用,可回收,可拉伸的等离子体膜葡萄柚腐烂检测。","authors":"Limei Liu, Tingfeng Dai, Taimin Sun, Binghao Wang","doi":"10.1007/s00216-025-06077-7","DOIUrl":null,"url":null,"abstract":"<p><p>Flexible surface-enhanced Raman scattering (SERS) sensors show promise for non-destructive, on-site fruit quality monitoring; however, current SERS substrates frequently fail to meet the extended operational stability demands of cross-seasonal agricultural storage systems. This study presents a durable, recyclable, and stretchable plasmonic film (Au@AgNWs/PDMS) for decay detection in grapefruits. By partially embedding silver nanowires (AgNWs) in PDMS and functionalizing surfaces with gold nanoparticles via galvanic replacement, the composite film achieves high sensitivity (10⁻<sup>9</sup> M rhodamine 6G), mechanical resilience (85% tensile strain tolerance), and long-term stability (49 days). The substrate retains stable SERS performance through 1000 stretching cycles and supports five regeneration cycles without degradation. Practical validation demonstrated its capacity for in situ fungal biomarker tracking on grapefruit surfaces, correlating quinone accumulation with decay progression. Combining conformal adhesion, environmental resistance, and reusability, this technology offers a scalable solution for enhancing food security during storage.</p>","PeriodicalId":462,"journal":{"name":"Analytical and Bioanalytical Chemistry","volume":" ","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Durable, recyclable, and stretchable plasmonic film for grapefruit decay detection.\",\"authors\":\"Limei Liu, Tingfeng Dai, Taimin Sun, Binghao Wang\",\"doi\":\"10.1007/s00216-025-06077-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Flexible surface-enhanced Raman scattering (SERS) sensors show promise for non-destructive, on-site fruit quality monitoring; however, current SERS substrates frequently fail to meet the extended operational stability demands of cross-seasonal agricultural storage systems. This study presents a durable, recyclable, and stretchable plasmonic film (Au@AgNWs/PDMS) for decay detection in grapefruits. By partially embedding silver nanowires (AgNWs) in PDMS and functionalizing surfaces with gold nanoparticles via galvanic replacement, the composite film achieves high sensitivity (10⁻<sup>9</sup> M rhodamine 6G), mechanical resilience (85% tensile strain tolerance), and long-term stability (49 days). The substrate retains stable SERS performance through 1000 stretching cycles and supports five regeneration cycles without degradation. Practical validation demonstrated its capacity for in situ fungal biomarker tracking on grapefruit surfaces, correlating quinone accumulation with decay progression. Combining conformal adhesion, environmental resistance, and reusability, this technology offers a scalable solution for enhancing food security during storage.</p>\",\"PeriodicalId\":462,\"journal\":{\"name\":\"Analytical and Bioanalytical Chemistry\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-08-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical and Bioanalytical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s00216-025-06077-7\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical and Bioanalytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s00216-025-06077-7","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
Durable, recyclable, and stretchable plasmonic film for grapefruit decay detection.
Flexible surface-enhanced Raman scattering (SERS) sensors show promise for non-destructive, on-site fruit quality monitoring; however, current SERS substrates frequently fail to meet the extended operational stability demands of cross-seasonal agricultural storage systems. This study presents a durable, recyclable, and stretchable plasmonic film (Au@AgNWs/PDMS) for decay detection in grapefruits. By partially embedding silver nanowires (AgNWs) in PDMS and functionalizing surfaces with gold nanoparticles via galvanic replacement, the composite film achieves high sensitivity (10⁻9 M rhodamine 6G), mechanical resilience (85% tensile strain tolerance), and long-term stability (49 days). The substrate retains stable SERS performance through 1000 stretching cycles and supports five regeneration cycles without degradation. Practical validation demonstrated its capacity for in situ fungal biomarker tracking on grapefruit surfaces, correlating quinone accumulation with decay progression. Combining conformal adhesion, environmental resistance, and reusability, this technology offers a scalable solution for enhancing food security during storage.
期刊介绍:
Analytical and Bioanalytical Chemistry’s mission is the rapid publication of excellent and high-impact research articles on fundamental and applied topics of analytical and bioanalytical measurement science. Its scope is broad, and ranges from novel measurement platforms and their characterization to multidisciplinary approaches that effectively address important scientific problems. The Editors encourage submissions presenting innovative analytical research in concept, instrumentation, methods, and/or applications, including: mass spectrometry, spectroscopy, and electroanalysis; advanced separations; analytical strategies in “-omics” and imaging, bioanalysis, and sampling; miniaturized devices, medical diagnostics, sensors; analytical characterization of nano- and biomaterials; chemometrics and advanced data analysis.