由平面手性[2.2]副环环烷组成的旋光性环状化合物、带状和螺旋形化合物的合成。

IF 2.8 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemPlusChem Pub Date : 2025-09-02 DOI:10.1002/cplu.202500276

Ena Kumamoto, Nanami Miki, Ryo Inoue, Yasuhiro Morisaki

引用次数: 0

摘要

合成了两种基于平面手性[2.2]副环环烷骨架的旋光性环化合物。这些化合物包括四取代[2.2]副环烷作为手性交叉单元，其中π共轭苯-乙烯被折叠成带状和螺旋桨状结构。该化合物发出圆偏振发光（CPL），具有高各向异性因子（|glum|）和CPL亮度值（BCPL）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis of Optically Active Cyclic Compounds, Ribbon-Shaped and Propeller-Shaped Compounds, Consisting of Planar Chiral [2.2]Paracyclophane.

Two types of optically active cyclic compounds based on planar chiral [2.2]paracyclophane skeleton are synthesized. These compounds comprise tetrasubstituted [2.2]paracyclophanes as chiral crossing units, in which π-conjugated phenylene-ethynylenes are folded to construct ribbon- and propeller-shaped structures. The compounds emit circularly polarized luminescence (CPL) with high anisotropy factors (|g_lum|) and CPL brightness values (B_CPL).

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来源期刊

ChemPlusChem CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

5.90

自引率

0.00%

发文量

200

审稿时长

1 months

期刊介绍： ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.