{"title":"高效A3偶联反应的多氧钨酸基磁性复合MOF催化剂的合成与表征","authors":"Fatemeh Etessamifar, Mojtaba Bagherzadeh, Arshad Bayrami, Mohsen Chegeni","doi":"10.1002/aoc.70318","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>This research investigates the development and implementation of 11-tungstocupro (II)-silicate incorporated into a magnetic metal–organic framework (MOF) Fe<sub>3</sub>O<sub>4</sub>/MIL-101(Cr) to serve as a catalyst. For this purpose, the catalyst Fe<sub>3</sub>O<sub>4</sub>/MIL-101(Cr)@POM underwent synthesis through the co-precipitation procedure, and its structure was perfectly confirmed by various techniques such as FT-IR, XRD, FE-SEM/EDX, and ICP-OES. Following that, during tests of a three-component reaction that combines amine and alkyne compounds with an aldehyde under the A<sup>3</sup> coupling reaction, the as-catalyst demonstrated an effectiveness profile, with the reaction conditions optimized to achieve 68.4% efficiency through a 24-h chloroform reflux procedure, whereas the solvent-free reaction route attained 64.5% efficiency, finishing in only 18 h. The reusable catalyst endured minimal degradation in activity while undergoing five cycles. Furthermore, the leaching test detected no leakage in Cu metal concentration for the filtrated solution after the catalytic reaction. This study could properly resolve solubility obstacles and separation limitations that typically restrict homogeneous polyoxometalate catalysts by incorporating polyoxotungstate into the magnetic MOF structure while developing an effective practical solution for field implementations.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of a Polyoxotungstate-Based Magnetic Composite MOF Catalyst for Efficient A3 Coupling Reactions\",\"authors\":\"Fatemeh Etessamifar, Mojtaba Bagherzadeh, Arshad Bayrami, Mohsen Chegeni\",\"doi\":\"10.1002/aoc.70318\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>This research investigates the development and implementation of 11-tungstocupro (II)-silicate incorporated into a magnetic metal–organic framework (MOF) Fe<sub>3</sub>O<sub>4</sub>/MIL-101(Cr) to serve as a catalyst. For this purpose, the catalyst Fe<sub>3</sub>O<sub>4</sub>/MIL-101(Cr)@POM underwent synthesis through the co-precipitation procedure, and its structure was perfectly confirmed by various techniques such as FT-IR, XRD, FE-SEM/EDX, and ICP-OES. Following that, during tests of a three-component reaction that combines amine and alkyne compounds with an aldehyde under the A<sup>3</sup> coupling reaction, the as-catalyst demonstrated an effectiveness profile, with the reaction conditions optimized to achieve 68.4% efficiency through a 24-h chloroform reflux procedure, whereas the solvent-free reaction route attained 64.5% efficiency, finishing in only 18 h. The reusable catalyst endured minimal degradation in activity while undergoing five cycles. Furthermore, the leaching test detected no leakage in Cu metal concentration for the filtrated solution after the catalytic reaction. This study could properly resolve solubility obstacles and separation limitations that typically restrict homogeneous polyoxometalate catalysts by incorporating polyoxotungstate into the magnetic MOF structure while developing an effective practical solution for field implementations.</p>\\n </div>\",\"PeriodicalId\":8344,\"journal\":{\"name\":\"Applied Organometallic Chemistry\",\"volume\":\"39 10\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2025-09-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70318\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70318","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Synthesis and Characterization of a Polyoxotungstate-Based Magnetic Composite MOF Catalyst for Efficient A3 Coupling Reactions
This research investigates the development and implementation of 11-tungstocupro (II)-silicate incorporated into a magnetic metal–organic framework (MOF) Fe3O4/MIL-101(Cr) to serve as a catalyst. For this purpose, the catalyst Fe3O4/MIL-101(Cr)@POM underwent synthesis through the co-precipitation procedure, and its structure was perfectly confirmed by various techniques such as FT-IR, XRD, FE-SEM/EDX, and ICP-OES. Following that, during tests of a three-component reaction that combines amine and alkyne compounds with an aldehyde under the A3 coupling reaction, the as-catalyst demonstrated an effectiveness profile, with the reaction conditions optimized to achieve 68.4% efficiency through a 24-h chloroform reflux procedure, whereas the solvent-free reaction route attained 64.5% efficiency, finishing in only 18 h. The reusable catalyst endured minimal degradation in activity while undergoing five cycles. Furthermore, the leaching test detected no leakage in Cu metal concentration for the filtrated solution after the catalytic reaction. This study could properly resolve solubility obstacles and separation limitations that typically restrict homogeneous polyoxometalate catalysts by incorporating polyoxotungstate into the magnetic MOF structure while developing an effective practical solution for field implementations.
期刊介绍:
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.