纳米空腔中的受限电化学：观点与技术

IF 6.9 2区化学 Q1 CHEMISTRY, PHYSICAL

Current Opinion in Electrochemistry Pub Date : 2025-08-14 DOI:10.1016/j.coelec.2025.101747

Din Zelikovich , Pavel Savchenko , Daniel Mandler

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引用次数: 0

摘要

了解到在纳米约束下进行的化学反应与在体中进行的化学反应明显不同，这促使电化学化学家研究纳米尺寸体积中的电化学过程。在纳米孔中，反应物和生成物在不同的地方进入和离开，已经进行了大量的工作。这主要应用于蛋白质和DNA测序。然而，很少有研究致力于研究只有一个开口的纳米腔中的电化学反应。本文综述了这一新兴领域的研究进展，包括纳米空腔的制备方法、纳米空腔的分析方法以及目前和未来的应用前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Confined electrochemistry in nanocavities: Perspective and techniques

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Confined electrochemistry in nanocavities: Perspective and techniques

The understanding that chemical reactions carried out under nanoconfinement behave significantly differently than in the bulk has motivated electrochemists to study electrochemical processes in nanometer-sized volumes. Significant work has been performed in nanopores where the reactants and products enter and leave at different places. This has been primarily applied to protein and DNA sequencing. Yet, fewer studies have been devoted to studying electrochemical reactions in nanocavities where there is only a single opening. This review summarizes the growing activity in this relatively new area, which includes the approaches for making nanocavities, the ways the nanocavities are analyzed, and the present and future applications.

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来源期刊

Current Opinion in Electrochemistry Chemistry-Analytical Chemistry

CiteScore

14.00

自引率

5.90%

发文量

272

审稿时长

73 days

期刊介绍： The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner: 1.The views of experts on current advances in electrochemistry in a clear and readable form. 2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications. In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle: • Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •