AnnieCanisius D , P. Joselene Suzan Jennifer , M. Gladys Joysi , S. Muthupandi , E. Kavitha , J. Madhavan , M. Victor Antony Raj
{"title":"BiOCl-CuO纳米复合材料作为葡萄糖检测和能量存储的双功能材料","authors":"AnnieCanisius D , P. Joselene Suzan Jennifer , M. Gladys Joysi , S. Muthupandi , E. Kavitha , J. Madhavan , M. Victor Antony Raj","doi":"10.1016/j.rechem.2025.102646","DOIUrl":null,"url":null,"abstract":"<div><div>A BiOCl–CuO (BCC) nanocomposite was synthesized via a solvothermal method and characterized for its dual electrochemical applications in glucose sensing and supercapacitors. High-resolution scanning electron microscopy (HR-SEM) revealed a nanosphere morphology, while electrochemical impedance spectroscopy (EIS) and Brunauer–Emmett–Teller (BET) analysis demonstrated a low charge transfer resistance (6.95 Ω) and a high specific surface area (124.5 m<sup>2</sup>/g), respectively. The synergistic interaction between BiOCl and CuO enhanced glucose adsorption and oxidation, yielding a sensitivity of 0.718 mA mM<sup>−1</sup> cm<sup>−2</sup> and a detection limit of 0.48 mM, as determined by chronoamperometry. In supercapacitor applications, BCC exhibited superior electrochemical performance compared to pure BiOCl, with a higher specific capacitance of 684.92 Fg<sup>−1</sup>, prolonged discharge time, and excellent cycling stability. These findings highlight the potential of BCC as a multifunctional material for high-performance glucose sensors and energy storage devices.</div></div>","PeriodicalId":420,"journal":{"name":"Results in Chemistry","volume":"17 ","pages":"Article 102646"},"PeriodicalIF":4.2000,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"BiOCl–CuO nanocomposite as a bifunctional material for glucose detection and energy storage\",\"authors\":\"AnnieCanisius D , P. Joselene Suzan Jennifer , M. Gladys Joysi , S. Muthupandi , E. Kavitha , J. Madhavan , M. Victor Antony Raj\",\"doi\":\"10.1016/j.rechem.2025.102646\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A BiOCl–CuO (BCC) nanocomposite was synthesized via a solvothermal method and characterized for its dual electrochemical applications in glucose sensing and supercapacitors. High-resolution scanning electron microscopy (HR-SEM) revealed a nanosphere morphology, while electrochemical impedance spectroscopy (EIS) and Brunauer–Emmett–Teller (BET) analysis demonstrated a low charge transfer resistance (6.95 Ω) and a high specific surface area (124.5 m<sup>2</sup>/g), respectively. The synergistic interaction between BiOCl and CuO enhanced glucose adsorption and oxidation, yielding a sensitivity of 0.718 mA mM<sup>−1</sup> cm<sup>−2</sup> and a detection limit of 0.48 mM, as determined by chronoamperometry. In supercapacitor applications, BCC exhibited superior electrochemical performance compared to pure BiOCl, with a higher specific capacitance of 684.92 Fg<sup>−1</sup>, prolonged discharge time, and excellent cycling stability. These findings highlight the potential of BCC as a multifunctional material for high-performance glucose sensors and energy storage devices.</div></div>\",\"PeriodicalId\":420,\"journal\":{\"name\":\"Results in Chemistry\",\"volume\":\"17 \",\"pages\":\"Article 102646\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Results in Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2211715625006290\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Results in Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2211715625006290","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
BiOCl–CuO nanocomposite as a bifunctional material for glucose detection and energy storage
A BiOCl–CuO (BCC) nanocomposite was synthesized via a solvothermal method and characterized for its dual electrochemical applications in glucose sensing and supercapacitors. High-resolution scanning electron microscopy (HR-SEM) revealed a nanosphere morphology, while electrochemical impedance spectroscopy (EIS) and Brunauer–Emmett–Teller (BET) analysis demonstrated a low charge transfer resistance (6.95 Ω) and a high specific surface area (124.5 m2/g), respectively. The synergistic interaction between BiOCl and CuO enhanced glucose adsorption and oxidation, yielding a sensitivity of 0.718 mA mM−1 cm−2 and a detection limit of 0.48 mM, as determined by chronoamperometry. In supercapacitor applications, BCC exhibited superior electrochemical performance compared to pure BiOCl, with a higher specific capacitance of 684.92 Fg−1, prolonged discharge time, and excellent cycling stability. These findings highlight the potential of BCC as a multifunctional material for high-performance glucose sensors and energy storage devices.