能量密集锂金属电池的相间特性协方差与快速充电性

IF 60.1 1区 材料科学 Q1 ENERGY & FUELS
Hyeokjin Kwon, Seongyeong Kim, Jonghyun Hyun, Ha Eun Lee, Seong Su Kim, Yesom Kim, Il Ju Kim, Kyungjae Shin, Sejin Kim, Changhoon Park, Hongsin Kim, Dongseok Shin, Hee-Tak Kim
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引用次数: 0

摘要

锂金属电池可以实现高能量密度,缓解电动汽车的里程焦虑。然而,快速充电条件下合理的界面设计仍然是一个难题。本文研究了一系列在快速充电条件下具有不同取代阴离子的吡喃基电解质,并观察到弱Li+缔合阴离子在快速充电条件下有利于均匀镀锂。我们展示了锂金属电池在4C (8.4 mA cm - 2)充电速率下,在350次重复循环中,在12分钟内达到5-70%的充电状态(SoC),以及在180次循环中,在17分钟内提供386 Wh kg - 1的预计能量密度达到10-80%的SoC。我们提出,快速充电性能的提高与弱Li+缔合阴离子抑制固体电解质界面内无机物质聚集的能力有关,并证明了基于所提出的机制的电解质进步的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Covariance of interphasic properties and fast chargeability of energy-dense lithium metal batteries

Covariance of interphasic properties and fast chargeability of energy-dense lithium metal batteries

Covariance of interphasic properties and fast chargeability of energy-dense lithium metal batteries
Lithium metal batteries can achieve high energy density, alleviating range anxiety for electric vehicles. However, the rational interphase design under fast charging conditions remains difficult. Here we explore a series of pyran-based electrolytes with various substitutional anions under a fast charging condition and observe weakly Li+-associating anions facilitating uniform lithium plating under a fast charging condition. We demonstrate lithium metal batteries achieving a 5–70% state of charge (SoC) within 12 min over 350 repeated cycles at a 4C (8.4 mA cm−2) charging rate, as well as high-energy designs delivering projected energy densities of 386 Wh kg−1 reaching a 10–80% SoC within 17 min over 180 cycles. We propose that the improved fast charging performance is in tandem with the ability of the weakly Li+ associating anions to suppress inorganic species clustering within the solid–electrolyte interphase and demonstrate the potential for electrolyte advancement based on the proposed mechanism. Lithium metal batteries offer high energy density for electric vehicles but face challenges with fast charging. This study investigates pyran-based electrolytes containing various substituted anions, revealing that weakly Li+-associating anions enhance fast-charging performance.
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来源期刊
Nature Energy
Nature Energy Energy-Energy Engineering and Power Technology
CiteScore
75.10
自引率
1.10%
发文量
193
期刊介绍: Nature Energy is a monthly, online-only journal committed to showcasing the most impactful research on energy, covering everything from its generation and distribution to the societal implications of energy technologies and policies. With a focus on exploring all facets of the ongoing energy discourse, Nature Energy delves into topics such as energy generation, storage, distribution, management, and the societal impacts of energy technologies and policies. Emphasizing studies that push the boundaries of knowledge and contribute to the development of next-generation solutions, the journal serves as a platform for the exchange of ideas among stakeholders at the forefront of the energy sector. Maintaining the hallmark standards of the Nature brand, Nature Energy boasts a dedicated team of professional editors, a rigorous peer-review process, meticulous copy-editing and production, rapid publication times, and editorial independence. In addition to original research articles, Nature Energy also publishes a range of content types, including Comments, Perspectives, Reviews, News & Views, Features, and Correspondence, covering a diverse array of disciplines relevant to the field of energy.
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