Nouf H. Alotaibi, Khawar Abbas, Mehar Un Nisa, Saikh Mohammad, Shahroz Saleem, Muhammad Khalil, Abdul Ghafoor Abid
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引用次数: 0
摘要
钨基氧化物已成为(HER)析氢反应和(OER)析氧反应的潜在电催化剂。值得注意的是,钨氧化物在OER中的催化潜力还有待研究。在本工作中,我们提出了一种新的由BiLaWO6/PPY组成的纳米阵列结构电极。在碱性条件下,这种独特的电极催化OER和HER具有优异的稳定性和效率。与可逆氢电极相比,BiLaWO6/PPY纳米阵列结构显著增加了电极的氢气释放量,在初始电位245 mV和过电位78 mV下产生了10 mA cm−2的电流密度。此外,该BiLaWO6/PPY纳米复合材料的Tafel斜率为64 mVdec−1。另一方面,BiLaWO6/PPY纳米阵列表现出良好的OER活性,其起始电位为1.42,过电位为244 mV。此外,为了使用10 mA cm−2的电流密度验证反应过程,所得材料的OER显示出Tafel斜率(34 mVdec−1)。这表明它是一种很有前途的非贵金属催化剂,用于1m KOH的绿水裂解。因此,在本研究背景下,BiLaWO6/PPY纳米阵列的实现意味着推进OER电催化剂和其他用于能量转换和存储系统的器件的创新策略。
Advancing approaches for designing high-performance BiLaWO6/PPY nanocomposite for water splitting
The tungsten-based oxides have emerged as a potential electrocatalyst for (HER) hydrogen evolution reaction as well as (OER) oxygen evolution reaction. Notably, catalytic potential of tungsten oxides in the OER has yet to be studied. In present work, we offer a new nanoarray-structured electrode composed of BiLaWO6/PPY. In alkaline conditions, this unique electrode catalyzes both the OER and HER with excellent stability and efficiency. In comparison to the reversible hydrogen electrode, BiLaWO6/PPY nanoarray structure considerably increase hydrogen gas release from the electrode, generating a remarkable current density of 10 mA cm− 2 at an initial potential of 245 mV with a 78 mV overpotential for HER. Furthermore, this BiLaWO6/PPY nanocomposite displays Tafel slope of 64 mVdec− 1. On other hand, the BiLaWO6/PPY nanoarray shows good OER activity having 1.42 onset potential with overpotential of 244 mV. In order to validate the reaction process using current density of 10 mA cm− 2, additionally, resulting material displays a Tafel slope (34 mVdec− 1)for OER. This demonstrates that it is a promising non-noble metal catalyst for green water splitting using 1 M KOH. Consequently, the implementation of BiLaWO6/PPY nanoarray in the context of this research signifies an innovative strategy for advancing OER electrocatalysts and other devices utilized in energy conversion and storage system.
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Journal of the Australian Ceramic Society since 1965
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