陶瓷增材制造的核壳粉末策略:在碳化硅直接粉末床选择性激光加工中的应用

IF 2.1 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Alejandro Montón, Francis Maury, Geoffroy Chevallier, Claude Estournès, Marc Ferrato, David Grossin
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引用次数: 0

摘要

通过颗粒的表面功能化生产创新陶瓷粉末,具有核壳结构,加速质量扩散,提高烧结性能。这种方法对增材制造领域产生了重大影响。在本研究中,一种来自聚碳硅烷家族的商业SiC预陶瓷化合物,特别是聚硅乙烯,被接枝到碳化硅(SiC)颗粒的表面,形成一个共形分子层。粉末床选择性激光加工,也称为选择性激光烧结/熔化,用于制造3D SiC和表面改性的SiC零件,从而对表面改性在制造过程中的效率和影响进行了比较分析。表面功能化增加密度至少5%,而不影响制造零件的最终阶段。此外,采用火花等离子烧结(SPS)作为后处理,进一步提高样品的密度,增加其最终密度,消除残余的硅和碳,这是由于在制造过程中不希望的SiC分解而产生的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Core–shell powder strategy for additive manufacturing of ceramics: application to direct powder bed selective laser processing of silicon carbide

The production of innovative ceramic powders through surface functionalization of grains, featuring a core–shell structure, accelerates mass diffusion and enhances sintering behavior. This approach significantly impacts the additive manufacturing field. In this study, a commercial SiC preceramic compound from the polycarbosilane family, specifically poly(silaethylene), was grafted onto the surface of Silicon Carbide (SiC) particles, forming a conformal molecular layer. Powder Bed Selective Laser Processing, also known as Selective Laser Sintering/Melting, was employed to fabricate 3D SiC and surface-modified SiC parts, enabling a comparative analysis of the efficiency and impact of surface modification in the manufacturing process. The surface functionalization increases densification by at least 5% without affecting the final phases of the manufactured parts. Additionally, Spark Plasma Sintering (SPS) was employe as a post-treatment to further densify the samples, increasing their final density and eliminating residual silicon and carbon, which are produced due to the undesired decomposition of SiC during the manufacturing process.

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来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society Materials Science-Materials Chemistry
CiteScore
3.70
自引率
5.30%
发文量
123
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
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