Jidun Sha, Shaoqing Wang*, Xiaomei Zhang* and Jingzhe Zhang,
{"title":"涡旋结构与扭曲石墨烯之间联系的证据","authors":"Jidun Sha, Shaoqing Wang*, Xiaomei Zhang* and Jingzhe Zhang, ","doi":"10.1021/acs.cgd.5c00447","DOIUrl":null,"url":null,"abstract":"<p >The objective of this study is to ascertain the fundamental characteristics of the turbostratic structure through direct means. The employment of contrast features intrinsic to nanoporous carbon curved layers has been demonstrated to facilitate the observation of rotation between parallel layers. This observation is made through the application of high-resolution transmission electron microscopy in the direction of layer distribution. This outcome directly corroborates the hypothesis that the turbostratic structure is the result of multiple layers of twisted graphene that have been stacked together. Through the implementation of precise XRD peak fitting procedures, we have further substantiated that the fundamental structural alterations occurring during the late stage of graphitization are attributed to modifications in the stacking order. The underlying cause of these alterations has been identified as variations in the twist angles of twisted graphene layers within the turbostratic structure.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":"25 17","pages":"7074–7080"},"PeriodicalIF":3.4000,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Evidence of a Connection between Turbostratic Structure and Twisted Graphene\",\"authors\":\"Jidun Sha, Shaoqing Wang*, Xiaomei Zhang* and Jingzhe Zhang, \",\"doi\":\"10.1021/acs.cgd.5c00447\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The objective of this study is to ascertain the fundamental characteristics of the turbostratic structure through direct means. The employment of contrast features intrinsic to nanoporous carbon curved layers has been demonstrated to facilitate the observation of rotation between parallel layers. This observation is made through the application of high-resolution transmission electron microscopy in the direction of layer distribution. This outcome directly corroborates the hypothesis that the turbostratic structure is the result of multiple layers of twisted graphene that have been stacked together. Through the implementation of precise XRD peak fitting procedures, we have further substantiated that the fundamental structural alterations occurring during the late stage of graphitization are attributed to modifications in the stacking order. The underlying cause of these alterations has been identified as variations in the twist angles of twisted graphene layers within the turbostratic structure.</p>\",\"PeriodicalId\":34,\"journal\":{\"name\":\"Crystal Growth & Design\",\"volume\":\"25 17\",\"pages\":\"7074–7080\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2025-08-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Growth & Design\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.cgd.5c00447\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Growth & Design","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.5c00447","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Evidence of a Connection between Turbostratic Structure and Twisted Graphene
The objective of this study is to ascertain the fundamental characteristics of the turbostratic structure through direct means. The employment of contrast features intrinsic to nanoporous carbon curved layers has been demonstrated to facilitate the observation of rotation between parallel layers. This observation is made through the application of high-resolution transmission electron microscopy in the direction of layer distribution. This outcome directly corroborates the hypothesis that the turbostratic structure is the result of multiple layers of twisted graphene that have been stacked together. Through the implementation of precise XRD peak fitting procedures, we have further substantiated that the fundamental structural alterations occurring during the late stage of graphitization are attributed to modifications in the stacking order. The underlying cause of these alterations has been identified as variations in the twist angles of twisted graphene layers within the turbostratic structure.
期刊介绍:
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.