{"title":"前言：用于适应性分子识别的柔性共价有机支柱的手性自分类","authors":"","doi":"10.1002/ange.202583601","DOIUrl":null,"url":null,"abstract":"<p>The cover illustrates the chiral self-sorting and adaptive host-guest behavior of <b>flex-COP-n</b>, a new family of flexible covalent organic pillars with deep-cavity architectures (e202509177). These nanotubular hosts form enantiomeric or <i>meso</i> duplexes via dynamic imine condensation and accommodate guest molecules through mutual deformation. Cartoon springs and character-filled cavities depict how host and guest adjust their shapes to achieve precise molecular recognition, echoing biological receptors.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 36","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202583601","citationCount":"0","resultStr":"{\"title\":\"Frontispiece: Chiral Self-Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition\",\"authors\":\"\",\"doi\":\"10.1002/ange.202583601\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The cover illustrates the chiral self-sorting and adaptive host-guest behavior of <b>flex-COP-n</b>, a new family of flexible covalent organic pillars with deep-cavity architectures (e202509177). These nanotubular hosts form enantiomeric or <i>meso</i> duplexes via dynamic imine condensation and accommodate guest molecules through mutual deformation. Cartoon springs and character-filled cavities depict how host and guest adjust their shapes to achieve precise molecular recognition, echoing biological receptors.\\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":7803,\"journal\":{\"name\":\"Angewandte Chemie\",\"volume\":\"137 36\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-09-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202583601\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ange.202583601\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202583601","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Frontispiece: Chiral Self-Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition
The cover illustrates the chiral self-sorting and adaptive host-guest behavior of flex-COP-n, a new family of flexible covalent organic pillars with deep-cavity architectures (e202509177). These nanotubular hosts form enantiomeric or meso duplexes via dynamic imine condensation and accommodate guest molecules through mutual deformation. Cartoon springs and character-filled cavities depict how host and guest adjust their shapes to achieve precise molecular recognition, echoing biological receptors.
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