高熵合金颗粒和超声改性Al-13Cu合金晶粒细化机理的原位研究

IF 9.7 1区 化学 Q1 ACOUSTICS
Yuanzheng Cao , Xiaojuan Shang , Guangkai Yang , Jie Wang , Yiwang Jia , Qibin Liu , Yun Che , Sanquan Men , Xiang Li , Yuliang Zhao , Da Shu
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引用次数: 0

摘要

研究了FeCoCrNiAl高熵合金(HEA)改性al - 13wt % Cu合金超声凝固过程中初生α-Al的细化机制。采用原位x射线照相结合机器学习的计算机视觉技术,系统分析了α-Al晶粒的形核和生长行为。结果表明,随着HEA颗粒含量的增加和冷却速率的提高,晶粒细化效果显著。在1.0 K/s的冷却速率下,2.0 wt%的HEA颗粒显著减小了初生α-Al晶粒尺寸,晶粒尺寸约为213 μm。当冷却速率为0.2 K/s时,将HEA含量从0.5 wt%提高到2.0 wt%,可显著提高最大成核速率(从8.6个晶体/mm3/s提高到30.3个晶体/s),缩短晶粒停止生长所需的时间(从18 s缩短到10 s)。同样,在HEA含量固定(1.0 wt%)时,将冷却速率从0.2 K/s增加到1.0 K/s,可提高最大成核速率(从25.7个晶体/mm3/s增加到93.9个晶体/mm3/s),并缩短晶粒生长停止时间(从15 s减少到9 s)。粒度分布始终呈现正态分布模式。在凝固过程中,HEA颗粒的加入显著抑制了晶粒的生长,减少了溶质的富集。这些结果表明,FeCoCrNiAl HEA颗粒通过有效促进非均相形核和抑制晶粒长大来促进晶粒细化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
In-situ study on grain refinement mechanism of Al-13Cu alloys modified by high entropy alloy particles and ultrasonic treatment
This study explores the grain refinement mechanisms of primary α-Al during solidification of Al-13 wt% Cu alloy modified by FeCoCrNiAl high-entropy alloy (HEA) particles via ultrasonic treatment. In situ X-ray radiography combined with machine learning-based computer vision techniques was employed to systematically analyze the nucleation and growth behaviors of α-Al grains. Results indicate a significant grain refinement effect associated with increased HEA particle content and higher cooling rates. Specifically, the addition of 2.0 wt% HEA particles reduce the primary α-Al grain size notably, achieving approximately 213 μm at a cooling rate of 1.0 K/s. At a cooling rate of 0.2 K/s, raising the HEA content from 0.5 to 2.0 wt% markedly increases the maximum nucleation rate (from 8.6 to 30.3 crystals/mm3/s), shortens the time required for grain growth cessation (from 18 s to 10 s). Similarly, at a fixed HEA content (1.0 wt%), increasing the cooling rate from 0.2 K/s to 1.0 K/s enhances the maximum nucleation rate (from 25.7 to 93.9 crystals/mm3/s) and reduces the grain growth cessation time (from 15 s to 9 s). Grain size distributions consistently exhibit normal distribution patterns. The addition of HEA particles significantly inhibits grain growth and reduces solute enrichment during solidification. These findings demonstrate that FeCoCrNiAl HEA particles facilitate grain refinement by effectively promoting heterogeneous nucleation and inhibiting grain growth.
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来源期刊
Ultrasonics Sonochemistry
Ultrasonics Sonochemistry 化学-化学综合
CiteScore
15.80
自引率
11.90%
发文量
361
审稿时长
59 days
期刊介绍: Ultrasonics Sonochemistry stands as a premier international journal dedicated to the publication of high-quality research articles primarily focusing on chemical reactions and reactors induced by ultrasonic waves, known as sonochemistry. Beyond chemical reactions, the journal also welcomes contributions related to cavitation-induced events and processing, including sonoluminescence, and the transformation of materials on chemical, physical, and biological levels. Since its inception in 1994, Ultrasonics Sonochemistry has consistently maintained a top ranking in the "Acoustics" category, reflecting its esteemed reputation in the field. The journal publishes exceptional papers covering various areas of ultrasonics and sonochemistry. Its contributions are highly regarded by both academia and industry stakeholders, demonstrating its relevance and impact in advancing research and innovation.
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