大戟属植物地上部分的倍半萜类和单萜类南开

IF 2 4区生物学 Q4 BIOCHEMISTRY & MOLECULAR BIOLOGY

Biochemical Systematics and Ecology Pub Date : 2025-09-02 DOI:10.1016/j.bse.2025.105120

Yang Liu , Jie Chen , Wan-Wan Yu , Yong-Ming Luo , Meng-Li He , Xin-Yu Chen , Fang-You Chen

{"title":"大戟属植物地上部分的倍半萜类和单萜类南开","authors":"Yang Liu , Jie Chen , Wan-Wan Yu , Yong-Ming Luo , Meng-Li He , Xin-Yu Chen , Fang-You Chen","doi":"10.1016/j.bse.2025.105120","DOIUrl":null,"url":null,"abstract":"<div><div>Continual phytochemical investigation on the aerial parts of Sarcandra glabra (Thunb.) Nakai afforded fifteen compounds (1–15), comprising twelve sesquiterpenoids (1–12) and three monoterpenoids (13–15). The structures of these compounds were assigned by means of spectroscopic analysis, including 1D/2D NMR, HRESIMS, ECD calculations, and single-crystal X-ray diffractions. Compound 1 was a previously undescribed cadinane-type sesquiterpene, while compounds 4, 5, 9, and 12–15 were isolated from S. glabra for the first time. Moreover, the chemotaxonomic significance of these constituents was also discussed.</div></div>","PeriodicalId":8799,"journal":{"name":"Biochemical Systematics and Ecology","volume":"123 ","pages":"Article 105120"},"PeriodicalIF":2.0000,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sesquiterpenoids and monoterpenoids from the aerial parts of Sarcandra glabra (Thunb.) Nakai\",\"authors\":\"Yang Liu , Jie Chen , Wan-Wan Yu , Yong-Ming Luo , Meng-Li He , Xin-Yu Chen , Fang-You Chen\",\"doi\":\"10.1016/j.bse.2025.105120\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Continual phytochemical investigation on the aerial parts of Sarcandra glabra (Thunb.) Nakai afforded fifteen compounds (1–15), comprising twelve sesquiterpenoids (1–12) and three monoterpenoids (13–15). The structures of these compounds were assigned by means of spectroscopic analysis, including 1D/2D NMR, HRESIMS, ECD calculations, and single-crystal X-ray diffractions. Compound 1 was a previously undescribed cadinane-type sesquiterpene, while compounds 4, 5, 9, and 12–15 were isolated from S. glabra for the first time. Moreover, the chemotaxonomic significance of these constituents was also discussed.</div></div>\",\"PeriodicalId\":8799,\"journal\":{\"name\":\"Biochemical Systematics and Ecology\",\"volume\":\"123 \",\"pages\":\"Article 105120\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2025-09-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Biochemical Systematics and Ecology\",\"FirstCategoryId\":\"99\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0305197825001693\",\"RegionNum\":4,\"RegionCategory\":\"生物学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"BIOCHEMISTRY & MOLECULAR BIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Biochemical Systematics and Ecology","FirstCategoryId":"99","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0305197825001693","RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}

引用次数: 0

摘要

大鲵地上部植物化学的持续研究Nakai提供了15个化合物（1-15），包括12个倍半萜类（1-12）和3个单萜类（13-15）。这些化合物的结构通过光谱分析，包括1D/2D NMR， hresms， ECD计算和单晶x射线衍射来确定。其中化合物1为首次从该植物中分离得到，化合物4、5、9、12 ~ 15为首次从该植物中分离得到。并对这些成分的化学分类意义进行了讨论。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Sesquiterpenoids and monoterpenoids from the aerial parts of Sarcandra glabra (Thunb.) Nakai

Continual phytochemical investigation on the aerial parts of Sarcandra glabra (Thunb.) Nakai afforded fifteen compounds (1–15), comprising twelve sesquiterpenoids (1–12) and three monoterpenoids (13–15). The structures of these compounds were assigned by means of spectroscopic analysis, including 1D/2D NMR, HRESIMS, ECD calculations, and single-crystal X-ray diffractions. Compound 1 was a previously undescribed cadinane-type sesquiterpene, while compounds 4, 5, 9, and 12–15 were isolated from S. glabra for the first time. Moreover, the chemotaxonomic significance of these constituents was also discussed.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Biochemical Systematics and Ecology 生物-进化生物学

CiteScore

3.00

自引率

12.50%

发文量

147

审稿时长

43 days

期刊介绍： Biochemical Systematics and Ecology is devoted to the publication of original papers and reviews, both submitted and invited, in two subject areas: I) the application of biochemistry to problems relating to systematic biology of organisms (biochemical systematics); II) the role of biochemistry in interactions between organisms or between an organism and its environment (biochemical ecology). In the Biochemical Systematics subject area, comparative studies of the distribution of (secondary) metabolites within a wider taxon (e.g. genus or family) are welcome. Comparative studies, encompassing multiple accessions of each of the taxa within their distribution are particularly encouraged. Welcome are also studies combining classical chemosystematic studies (such as comparative HPLC-MS or GC-MS investigations) with (macro-) molecular phylogenetic studies. Studies that involve the comparative use of compounds to help differentiate among species such as adulterants or substitutes that illustrate the applied use of chemosystematics are welcome. In contrast, studies solely employing macromolecular phylogenetic techniques (gene sequences, RAPD studies etc.) will be considered out of scope. Discouraged are manuscripts that report known or new compounds from a single source taxon without addressing a systematic hypothesis. Also considered out of scope are studies using outdated and hard to reproduce macromolecular techniques such as RAPDs in combination with standard chemosystematic techniques such as GC-FID and GC-MS.