双金属钯金核壳二聚体的光谱响应和传感性能

IF 4.3 4区 物理与天体物理 Q2 CHEMISTRY, PHYSICAL
Mohammed Alsawafta
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引用次数: 0

摘要

利用时域有限差分(FDTD)数值工具对钯金核壳二聚体的光谱表征和传感性能进行了理论研究。双粒子模型的消光谱表现出三种混合共振模式的激发,为生物/化学分子提供了可靠的多位点传感平台。改变核心尺寸(rc)或外壳厚度(t)都会显著影响整体光学特性,说明在从紫外到可见光区域的广泛频率范围内可控的光学可调性。增加壳体厚度可显著提高对基体介电性能变化的感知能力。为了在多个光谱点保持同时有效的传感标准,应保持t≤(3/2)rc的结构比。否则,随着t的进一步增加,高能位点的传感性能会下降。当核心半径rc = 10 nm,壳层厚度t = 15 nm时,实现了最佳的传感性能,其中低能和高能等离子体模式都表现出增强的灵敏度因子。所提出的双金属二聚体的结构可调性为设计基于等离子体的纳米传感器提供了详细的指导。此外,我们得出的结论是,我们的理论观察将对使用消光截面谱来表征双金属核壳二聚体具有深远的意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Spectral Response and Sensing Capability of Bimetallic Pd-Au Core–Shell Dimers

A comprehensive investigation of both spectral characterizations and sensing performance of a Pd-Au core–shell dimer is conducted theoretically by the finite-difference time-domain (FDTD) numerical tool. The extinction spectrum of the two-particle model exhibits the excitation of three hybrid resonance modes, which introduces a reliable multi-site sensing platform for bio/chemical molecules. Altering either the core size (rc) or the shell thickness (t) significantly impacts the overall optical properties, illustrating controlled optical tunability over a wide range of frequencies extending from the UV to the visible region. Increasing the shell thickness considerably improves sensing capability to changes in the dielectric properties of the host matrix. To maintain simultaneous and effective sensing standards at several spectral sites, a structural ratio of t ≤ (3/2)rc should be maintained. Otherwise, the sensing performance of the high-energy site is degraded with any further increase in t. The optimal sensing performance is achieved for a core radius of rc = 10 nm and a shell thickness of t = 15 nm, where both low- and high-energy plasmonic modes exhibit enhanced sensitivity factors. The structural tunability of the proposed bimetallic dimer provides detailed guidelines for designing plasmon-based nanosensors. Additionally, we conclude that our theoretical observations will have profound implications for the use of extinction cross-section spectra in characterizing bimetallic core–shell dimers.

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来源期刊
Plasmonics
Plasmonics 工程技术-材料科学:综合
CiteScore
5.90
自引率
6.70%
发文量
164
审稿时长
2.1 months
期刊介绍: Plasmonics is an international forum for the publication of peer-reviewed leading-edge original articles that both advance and report our knowledge base and practice of the interactions of free-metal electrons, Plasmons. Topics covered include notable advances in the theory, Physics, and applications of surface plasmons in metals, to the rapidly emerging areas of nanotechnology, biophotonics, sensing, biochemistry and medicine. Topics, including the theory, synthesis and optical properties of noble metal nanostructures, patterned surfaces or materials, continuous or grated surfaces, devices, or wires for their multifarious applications are particularly welcome. Typical applications might include but are not limited to, surface enhanced spectroscopic properties, such as Raman scattering or fluorescence, as well developments in techniques such as surface plasmon resonance and near-field scanning optical microscopy.
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