{"title":"双金属钯金核壳二聚体的光谱响应和传感性能","authors":"Mohammed Alsawafta","doi":"10.1007/s11468-025-03240-9","DOIUrl":null,"url":null,"abstract":"<div><p>A comprehensive investigation of both spectral characterizations and sensing performance of a Pd-Au core–shell dimer is conducted theoretically by the finite-difference time-domain (FDTD) numerical tool. The extinction spectrum of the two-particle model exhibits the excitation of three hybrid resonance modes, which introduces a reliable multi-site sensing platform for bio/chemical molecules. Altering either the core size (<i>r</i><sub><i>c</i></sub>) or the shell thickness (<i>t</i>) significantly impacts the overall optical properties, illustrating controlled optical tunability over a wide range of frequencies extending from the UV to the visible region. Increasing the shell thickness considerably improves sensing capability to changes in the dielectric properties of the host matrix. To maintain simultaneous and effective sensing standards at several spectral sites, a structural ratio of <i>t</i> ≤ (3/2)<i>r</i><sub><i>c</i></sub> should be maintained. Otherwise, the sensing performance of the high-energy site is degraded with any further increase in <i>t</i>. The optimal sensing performance is achieved for a core radius of <i>r</i><sub><i>c</i></sub> = 10 nm and a shell thickness of <i>t</i> = 15 nm, where both low- and high-energy plasmonic modes exhibit enhanced sensitivity factors. The structural tunability of the proposed bimetallic dimer provides detailed guidelines for designing plasmon-based nanosensors. Additionally, we conclude that our theoretical observations will have profound implications for the use of extinction cross-section spectra in characterizing bimetallic core–shell dimers.</p></div>","PeriodicalId":736,"journal":{"name":"Plasmonics","volume":"20 8","pages":"6249 - 6265"},"PeriodicalIF":4.3000,"publicationDate":"2025-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Spectral Response and Sensing Capability of Bimetallic Pd-Au Core–Shell Dimers\",\"authors\":\"Mohammed Alsawafta\",\"doi\":\"10.1007/s11468-025-03240-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A comprehensive investigation of both spectral characterizations and sensing performance of a Pd-Au core–shell dimer is conducted theoretically by the finite-difference time-domain (FDTD) numerical tool. The extinction spectrum of the two-particle model exhibits the excitation of three hybrid resonance modes, which introduces a reliable multi-site sensing platform for bio/chemical molecules. Altering either the core size (<i>r</i><sub><i>c</i></sub>) or the shell thickness (<i>t</i>) significantly impacts the overall optical properties, illustrating controlled optical tunability over a wide range of frequencies extending from the UV to the visible region. Increasing the shell thickness considerably improves sensing capability to changes in the dielectric properties of the host matrix. To maintain simultaneous and effective sensing standards at several spectral sites, a structural ratio of <i>t</i> ≤ (3/2)<i>r</i><sub><i>c</i></sub> should be maintained. Otherwise, the sensing performance of the high-energy site is degraded with any further increase in <i>t</i>. The optimal sensing performance is achieved for a core radius of <i>r</i><sub><i>c</i></sub> = 10 nm and a shell thickness of <i>t</i> = 15 nm, where both low- and high-energy plasmonic modes exhibit enhanced sensitivity factors. The structural tunability of the proposed bimetallic dimer provides detailed guidelines for designing plasmon-based nanosensors. Additionally, we conclude that our theoretical observations will have profound implications for the use of extinction cross-section spectra in characterizing bimetallic core–shell dimers.</p></div>\",\"PeriodicalId\":736,\"journal\":{\"name\":\"Plasmonics\",\"volume\":\"20 8\",\"pages\":\"6249 - 6265\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-07-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Plasmonics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11468-025-03240-9\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plasmonics","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s11468-025-03240-9","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Spectral Response and Sensing Capability of Bimetallic Pd-Au Core–Shell Dimers
A comprehensive investigation of both spectral characterizations and sensing performance of a Pd-Au core–shell dimer is conducted theoretically by the finite-difference time-domain (FDTD) numerical tool. The extinction spectrum of the two-particle model exhibits the excitation of three hybrid resonance modes, which introduces a reliable multi-site sensing platform for bio/chemical molecules. Altering either the core size (rc) or the shell thickness (t) significantly impacts the overall optical properties, illustrating controlled optical tunability over a wide range of frequencies extending from the UV to the visible region. Increasing the shell thickness considerably improves sensing capability to changes in the dielectric properties of the host matrix. To maintain simultaneous and effective sensing standards at several spectral sites, a structural ratio of t ≤ (3/2)rc should be maintained. Otherwise, the sensing performance of the high-energy site is degraded with any further increase in t. The optimal sensing performance is achieved for a core radius of rc = 10 nm and a shell thickness of t = 15 nm, where both low- and high-energy plasmonic modes exhibit enhanced sensitivity factors. The structural tunability of the proposed bimetallic dimer provides detailed guidelines for designing plasmon-based nanosensors. Additionally, we conclude that our theoretical observations will have profound implications for the use of extinction cross-section spectra in characterizing bimetallic core–shell dimers.
期刊介绍:
Plasmonics is an international forum for the publication of peer-reviewed leading-edge original articles that both advance and report our knowledge base and practice of the interactions of free-metal electrons, Plasmons.
Topics covered include notable advances in the theory, Physics, and applications of surface plasmons in metals, to the rapidly emerging areas of nanotechnology, biophotonics, sensing, biochemistry and medicine. Topics, including the theory, synthesis and optical properties of noble metal nanostructures, patterned surfaces or materials, continuous or grated surfaces, devices, or wires for their multifarious applications are particularly welcome. Typical applications might include but are not limited to, surface enhanced spectroscopic properties, such as Raman scattering or fluorescence, as well developments in techniques such as surface plasmon resonance and near-field scanning optical microscopy.