{"title":"(101)锐钛矿表面纳米涂层增强Mg/TiO2光催化还原CO2的界面性能","authors":"Nurul Afiqah Mokri, Pei Ching Oh","doi":"10.1007/s11814-025-00484-3","DOIUrl":null,"url":null,"abstract":"<div><p>Addressing the continual rise in atmospheric CO₂ levels is a pressing challenge. Developing sustainable methods to convert CO<sub>2</sub> into valuable products is crucial for mitigating global warming and meeting long-term energy demands. The development of novel photocatalysts and the use of solar energy via photocatalysis are key to achieving CO<sub>2</sub>-to-CH<sub>3</sub>OH conversion. Among these, TiO<sub>2</sub> anatase has shown significant results for photocatalytic CO<sub>2</sub> reduction; however, its high bandgap energy restricts its efficiency in utilizing visible wavelengths, highlighting the need for further optimization. By doping strategy with alkaline earth metal like Mg, it modified the electronic properties of anatase TiO<sub>2</sub> and introduced more Lewis basic sites. Furthermore, Nafion coating facilitates proton-coupled electron transfer (PCET), stabilizes intermediates, and prevents methanol back-oxidation. Under UV–Vis irradiation for 8 h, the CH<sub>3</sub>OH yield from the photocatalytic CO<sub>2</sub>-to-CH<sub>3</sub>OH by Nafion/Mg–TiO₂ is 1559.82 μmol<sup>−1</sup> g<sup>−1</sup> h<sup>−1</sup>, outperforming Mg–TiO<sub>2</sub> (1350.20 μmol<sup>−1</sup> g<sup>−1</sup> h<sup>−1</sup>) and pristine TiO₂ (930.96 μmol<sup>−1</sup> g<sup>−1</sup> h<sup>−1</sup>). Langmuir–Hinshelwood (L–H) kinetic model reveals that CO is an intermediate product in this process, where its subsequent reaction with oxygen produces CH<sub>3</sub>OH, marking the rate-determining step. The synergistic effect of Nafion and Mg doping in TiO₂ optimizes acid–base interfaces contributed by Lewis’s base and acidic protonated Nafion, enabling efficient charge separation and enhanced photocatalytic activity. Nafion/Mg–TiO₂ is a promising platform for designing advanced photocatalysts for CO₂ reduction to methanol.</p></div>","PeriodicalId":684,"journal":{"name":"Korean Journal of Chemical Engineering","volume":"42 11","pages":"2523 - 2542"},"PeriodicalIF":3.2000,"publicationDate":"2025-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced Interfacial Properties of Nafion-Coated Mg/TiO2 with (101) Anatase Facet for Photocatalytic CO2 Reduction\",\"authors\":\"Nurul Afiqah Mokri, Pei Ching Oh\",\"doi\":\"10.1007/s11814-025-00484-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Addressing the continual rise in atmospheric CO₂ levels is a pressing challenge. Developing sustainable methods to convert CO<sub>2</sub> into valuable products is crucial for mitigating global warming and meeting long-term energy demands. The development of novel photocatalysts and the use of solar energy via photocatalysis are key to achieving CO<sub>2</sub>-to-CH<sub>3</sub>OH conversion. Among these, TiO<sub>2</sub> anatase has shown significant results for photocatalytic CO<sub>2</sub> reduction; however, its high bandgap energy restricts its efficiency in utilizing visible wavelengths, highlighting the need for further optimization. By doping strategy with alkaline earth metal like Mg, it modified the electronic properties of anatase TiO<sub>2</sub> and introduced more Lewis basic sites. Furthermore, Nafion coating facilitates proton-coupled electron transfer (PCET), stabilizes intermediates, and prevents methanol back-oxidation. Under UV–Vis irradiation for 8 h, the CH<sub>3</sub>OH yield from the photocatalytic CO<sub>2</sub>-to-CH<sub>3</sub>OH by Nafion/Mg–TiO₂ is 1559.82 μmol<sup>−1</sup> g<sup>−1</sup> h<sup>−1</sup>, outperforming Mg–TiO<sub>2</sub> (1350.20 μmol<sup>−1</sup> g<sup>−1</sup> h<sup>−1</sup>) and pristine TiO₂ (930.96 μmol<sup>−1</sup> g<sup>−1</sup> h<sup>−1</sup>). Langmuir–Hinshelwood (L–H) kinetic model reveals that CO is an intermediate product in this process, where its subsequent reaction with oxygen produces CH<sub>3</sub>OH, marking the rate-determining step. The synergistic effect of Nafion and Mg doping in TiO₂ optimizes acid–base interfaces contributed by Lewis’s base and acidic protonated Nafion, enabling efficient charge separation and enhanced photocatalytic activity. Nafion/Mg–TiO₂ is a promising platform for designing advanced photocatalysts for CO₂ reduction to methanol.</p></div>\",\"PeriodicalId\":684,\"journal\":{\"name\":\"Korean Journal of Chemical Engineering\",\"volume\":\"42 11\",\"pages\":\"2523 - 2542\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Korean Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11814-025-00484-3\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Korean Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11814-025-00484-3","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Enhanced Interfacial Properties of Nafion-Coated Mg/TiO2 with (101) Anatase Facet for Photocatalytic CO2 Reduction
Addressing the continual rise in atmospheric CO₂ levels is a pressing challenge. Developing sustainable methods to convert CO2 into valuable products is crucial for mitigating global warming and meeting long-term energy demands. The development of novel photocatalysts and the use of solar energy via photocatalysis are key to achieving CO2-to-CH3OH conversion. Among these, TiO2 anatase has shown significant results for photocatalytic CO2 reduction; however, its high bandgap energy restricts its efficiency in utilizing visible wavelengths, highlighting the need for further optimization. By doping strategy with alkaline earth metal like Mg, it modified the electronic properties of anatase TiO2 and introduced more Lewis basic sites. Furthermore, Nafion coating facilitates proton-coupled electron transfer (PCET), stabilizes intermediates, and prevents methanol back-oxidation. Under UV–Vis irradiation for 8 h, the CH3OH yield from the photocatalytic CO2-to-CH3OH by Nafion/Mg–TiO₂ is 1559.82 μmol−1 g−1 h−1, outperforming Mg–TiO2 (1350.20 μmol−1 g−1 h−1) and pristine TiO₂ (930.96 μmol−1 g−1 h−1). Langmuir–Hinshelwood (L–H) kinetic model reveals that CO is an intermediate product in this process, where its subsequent reaction with oxygen produces CH3OH, marking the rate-determining step. The synergistic effect of Nafion and Mg doping in TiO₂ optimizes acid–base interfaces contributed by Lewis’s base and acidic protonated Nafion, enabling efficient charge separation and enhanced photocatalytic activity. Nafion/Mg–TiO₂ is a promising platform for designing advanced photocatalysts for CO₂ reduction to methanol.
期刊介绍:
The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.