(101)锐钛矿表面纳米涂层增强Mg/TiO2光催化还原CO2的界面性能

IF 3.2 4区 工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY
Nurul Afiqah Mokri, Pei Ching Oh
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引用次数: 0

摘要

解决大气中二氧化碳浓度持续上升的问题是一项紧迫的挑战。开发可持续的方法将二氧化碳转化为有价值的产品,对于减缓全球变暖和满足长期能源需求至关重要。新型光催化剂的开发和利用太阳能光催化是实现co2 - ch3oh转化的关键。其中,TiO2锐钛矿光催化CO2还原效果显著;然而,其高带隙能量限制了其利用可见波长的效率,突出了进一步优化的必要性。通过Mg等碱土金属的掺杂策略,对锐钛矿型TiO2的电子性质进行了修饰,引入了更多的路易斯碱基位。此外,Nafion涂层促进质子耦合电子转移(PCET),稳定中间体,防止甲醇反氧化。在紫外-可见照射8 h下,Nafion/ Mg-TiO 2光催化co2制CH3OH的产率为1559.82 μmol−1 g−1 h−1,优于Mg-TiO2 (1350.20 μmol−1 g−1 h−1)和原始tio2 (930.96 μmol−1 g−1 h−1)。Langmuir-Hinshelwood (L-H)动力学模型表明,CO是该过程的中间产物,随后与氧反应生成CH3OH,标志着速率决定步骤。在tio2中掺入Nafion和Mg的协同作用优化了由Lewis 's碱和酸性质子化的Nafion形成的酸碱界面,实现了高效的电荷分离,增强了光催化活性。Nafion/ Mg-TiO 2是设计CO 2还原甲醇的先进光催化剂的一个很有前途的平台。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Enhanced Interfacial Properties of Nafion-Coated Mg/TiO2 with (101) Anatase Facet for Photocatalytic CO2 Reduction

Enhanced Interfacial Properties of Nafion-Coated Mg/TiO2 with (101) Anatase Facet for Photocatalytic CO2 Reduction

Enhanced Interfacial Properties of Nafion-Coated Mg/TiO2 with (101) Anatase Facet for Photocatalytic CO2 Reduction

Addressing the continual rise in atmospheric CO₂ levels is a pressing challenge. Developing sustainable methods to convert CO2 into valuable products is crucial for mitigating global warming and meeting long-term energy demands. The development of novel photocatalysts and the use of solar energy via photocatalysis are key to achieving CO2-to-CH3OH conversion. Among these, TiO2 anatase has shown significant results for photocatalytic CO2 reduction; however, its high bandgap energy restricts its efficiency in utilizing visible wavelengths, highlighting the need for further optimization. By doping strategy with alkaline earth metal like Mg, it modified the electronic properties of anatase TiO2 and introduced more Lewis basic sites. Furthermore, Nafion coating facilitates proton-coupled electron transfer (PCET), stabilizes intermediates, and prevents methanol back-oxidation. Under UV–Vis irradiation for 8 h, the CH3OH yield from the photocatalytic CO2-to-CH3OH by Nafion/Mg–TiO₂ is 1559.82 μmol−1 g−1 h−1, outperforming Mg–TiO2 (1350.20 μmol−1 g−1 h−1) and pristine TiO₂ (930.96 μmol−1 g−1 h−1). Langmuir–Hinshelwood (L–H) kinetic model reveals that CO is an intermediate product in this process, where its subsequent reaction with oxygen produces CH3OH, marking the rate-determining step. The synergistic effect of Nafion and Mg doping in TiO₂ optimizes acid–base interfaces contributed by Lewis’s base and acidic protonated Nafion, enabling efficient charge separation and enhanced photocatalytic activity. Nafion/Mg–TiO₂ is a promising platform for designing advanced photocatalysts for CO₂ reduction to methanol.

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来源期刊
Korean Journal of Chemical Engineering
Korean Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
4.60
自引率
11.10%
发文量
310
审稿时长
4.7 months
期刊介绍: The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.
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