室温下磁性MIL-100(Fe)复合材料对双氯芬酸钠和2,4 -二氯苯氧乙酸的吸附

IF 3.2 4区 工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yanfen Niu, Yuwei Song, Aaron Albert Aryee, Rong Wang, Runping Han
{"title":"室温下磁性MIL-100(Fe)复合材料对双氯芬酸钠和2,4 -二氯苯氧乙酸的吸附","authors":"Yanfen Niu,&nbsp;Yuwei Song,&nbsp;Aaron Albert Aryee,&nbsp;Rong Wang,&nbsp;Runping Han","doi":"10.1007/s11814-025-00487-0","DOIUrl":null,"url":null,"abstract":"<div><p>Metal–organic frameworks (MOFs) have found a wide range of applications in the field of water treatment owing to their large specific surface area, well-developed cavities and abundant active centers. In this study, a magnetic MOF composite (Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe)) was synthesized via a one-pot synthesis at room temperature, and its adsorption capacities towards diclofenac sodium (DS) and 2,4-dichlorophenoxyacetic acid (2, 4-D) were assessed. The maximum adsorption capacity of Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe) was 249 mg·g<sup>–1</sup> for DS (pH 6.8, 313 K), whereas it was found to be 163 mg·g<sup>–1</sup> for 2, 4-D (pH 3.0, 293 K). Results from fitting isotherm models with the equilibrium data suggested that both the Langmuir and Koble–Corrigan models be suitable for describing the adsorption equilibrium data. Results from kinetic model analysis suggested that both the pseudo-second-order and double-constant model could describe the uptake of DS and 2, 4-D onto Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe) well, respectively. The adsorption processes include both homogeneous physical and chemical adsorptions, such as electrostatic interaction, hydrogen bonding, and π–π interaction. Furthermore, Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe) showed good regeneration and reusability, indicating that the synthesized adsorbent is highly efficient, relatively cost-effective, and stable.</p></div>","PeriodicalId":684,"journal":{"name":"Korean Journal of Chemical Engineering","volume":"42 11","pages":"2763 - 2776"},"PeriodicalIF":3.2000,"publicationDate":"2025-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Adsorption of Diclofenac Sodium and 2, 4-Dichlorophenoxyacetic on Magnetic MIL-100(Fe) Composite Obtained at Room Temperature\",\"authors\":\"Yanfen Niu,&nbsp;Yuwei Song,&nbsp;Aaron Albert Aryee,&nbsp;Rong Wang,&nbsp;Runping Han\",\"doi\":\"10.1007/s11814-025-00487-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Metal–organic frameworks (MOFs) have found a wide range of applications in the field of water treatment owing to their large specific surface area, well-developed cavities and abundant active centers. In this study, a magnetic MOF composite (Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe)) was synthesized via a one-pot synthesis at room temperature, and its adsorption capacities towards diclofenac sodium (DS) and 2,4-dichlorophenoxyacetic acid (2, 4-D) were assessed. The maximum adsorption capacity of Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe) was 249 mg·g<sup>–1</sup> for DS (pH 6.8, 313 K), whereas it was found to be 163 mg·g<sup>–1</sup> for 2, 4-D (pH 3.0, 293 K). Results from fitting isotherm models with the equilibrium data suggested that both the Langmuir and Koble–Corrigan models be suitable for describing the adsorption equilibrium data. Results from kinetic model analysis suggested that both the pseudo-second-order and double-constant model could describe the uptake of DS and 2, 4-D onto Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe) well, respectively. The adsorption processes include both homogeneous physical and chemical adsorptions, such as electrostatic interaction, hydrogen bonding, and π–π interaction. Furthermore, Fe<sub>3</sub>O<sub>4</sub>/MIL-100(Fe) showed good regeneration and reusability, indicating that the synthesized adsorbent is highly efficient, relatively cost-effective, and stable.</p></div>\",\"PeriodicalId\":684,\"journal\":{\"name\":\"Korean Journal of Chemical Engineering\",\"volume\":\"42 11\",\"pages\":\"2763 - 2776\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Korean Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11814-025-00487-0\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Korean Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11814-025-00487-0","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

金属有机骨架具有比表面积大、空腔发育良好、活性中心丰富等特点,在水处理领域有着广泛的应用前景。本研究在室温下通过一锅法合成了磁性MOF复合物(Fe3O4/MIL-100(Fe)),并对其对双氯芬酸钠(DS)和2,4-二氯苯氧乙酸(2,4-d)的吸附能力进行了评价。Fe3O4/MIL-100(Fe)对DS (pH 6.8, 313 K)的最大吸附量为249 mg·g-1,对2,4 - d (pH 3.0, 293 K)的最大吸附量为163 mg·g-1。等温线模型与平衡数据的拟合结果表明,Langmuir模型和Koble-Corrigan模型都适合描述吸附平衡数据。动力学模型分析结果表明,拟二阶模型和双常数模型均能较好地描述DS和2,4 - d在Fe3O4/MIL-100(Fe)上的吸附。吸附过程包括均匀的物理吸附和化学吸附,如静电相互作用、氢键和π -π相互作用。此外,Fe3O4/MIL-100(Fe)表现出良好的再生性和可重复使用性,表明所合成的吸附剂高效、经济、稳定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Adsorption of Diclofenac Sodium and 2, 4-Dichlorophenoxyacetic on Magnetic MIL-100(Fe) Composite Obtained at Room Temperature

Metal–organic frameworks (MOFs) have found a wide range of applications in the field of water treatment owing to their large specific surface area, well-developed cavities and abundant active centers. In this study, a magnetic MOF composite (Fe3O4/MIL-100(Fe)) was synthesized via a one-pot synthesis at room temperature, and its adsorption capacities towards diclofenac sodium (DS) and 2,4-dichlorophenoxyacetic acid (2, 4-D) were assessed. The maximum adsorption capacity of Fe3O4/MIL-100(Fe) was 249 mg·g–1 for DS (pH 6.8, 313 K), whereas it was found to be 163 mg·g–1 for 2, 4-D (pH 3.0, 293 K). Results from fitting isotherm models with the equilibrium data suggested that both the Langmuir and Koble–Corrigan models be suitable for describing the adsorption equilibrium data. Results from kinetic model analysis suggested that both the pseudo-second-order and double-constant model could describe the uptake of DS and 2, 4-D onto Fe3O4/MIL-100(Fe) well, respectively. The adsorption processes include both homogeneous physical and chemical adsorptions, such as electrostatic interaction, hydrogen bonding, and π–π interaction. Furthermore, Fe3O4/MIL-100(Fe) showed good regeneration and reusability, indicating that the synthesized adsorbent is highly efficient, relatively cost-effective, and stable.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Korean Journal of Chemical Engineering
Korean Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
4.60
自引率
11.10%
发文量
310
审稿时长
4.7 months
期刊介绍: The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信