Pan Xu, Jingyi Yao, Haixing Yang, Jianyong Mao, Jijun Ge, Guoxuan Li* and Rongshan Bi*,
{"title":"通过生命周期评估和工艺优化提高聚碳酸酯生产的可持续性","authors":"Pan Xu, Jingyi Yao, Haixing Yang, Jianyong Mao, Jijun Ge, Guoxuan Li* and Rongshan Bi*, ","doi":"10.1021/acssuschemeng.5c05781","DOIUrl":null,"url":null,"abstract":"<p >In this study, the whole process model of the interfacial polycondensation polycarbonate (PC) production process was established by using Aspen Plus. Then, the steady-state simulation of each process in the production process was carried out, and the material balance and energy balance results of the whole process were obtained. The simulation results were combined with actual production to establish a list of resource consumption and pollutant emissions in the PC production process by interfacial polycondensation. The environmental impact of producing 300,000 tons of PC was analyzed by life cycle assessment (LCA). The investigation reveals that the marine aquatic toxicity potential (MAP) is the predominant environmental impact, accounting for 85.35% of the total impact. Specifically, the bisphenol salt prefabrication stage emerges as the major contributor, representing 56.88% of the overall impact. Furthermore, sodium hydroxide utilization significantly influences ozone layer depletion, while electricity consumption plays a substantial role in the terrestrial ecotoxicity potential. The study highlights the diverse environmental impacts of bisphenol A and phosgene across various indicators. In response to these findings, recommendations are presented, encompassing the enhancement of raw material efficiency, refinement of production processes, and reduction of energy consumption. Implementing these measures effectively alleviates the environmental impact of PC production, concurrently improving the efficiency and economic benefits. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health. Based on the LCA results, improvement suggestions were proposed to increase raw material utilization, improve raw material production processes, reduce energy consumption in the production process, and control direct emissions of pollutants. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health.</p>","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"13 34","pages":"14084–14098"},"PeriodicalIF":7.3000,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improving the Sustainability of Polycarbonate Production through Life Cycle Assessment and Process Optimization\",\"authors\":\"Pan Xu, Jingyi Yao, Haixing Yang, Jianyong Mao, Jijun Ge, Guoxuan Li* and Rongshan Bi*, \",\"doi\":\"10.1021/acssuschemeng.5c05781\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >In this study, the whole process model of the interfacial polycondensation polycarbonate (PC) production process was established by using Aspen Plus. Then, the steady-state simulation of each process in the production process was carried out, and the material balance and energy balance results of the whole process were obtained. The simulation results were combined with actual production to establish a list of resource consumption and pollutant emissions in the PC production process by interfacial polycondensation. The environmental impact of producing 300,000 tons of PC was analyzed by life cycle assessment (LCA). The investigation reveals that the marine aquatic toxicity potential (MAP) is the predominant environmental impact, accounting for 85.35% of the total impact. Specifically, the bisphenol salt prefabrication stage emerges as the major contributor, representing 56.88% of the overall impact. Furthermore, sodium hydroxide utilization significantly influences ozone layer depletion, while electricity consumption plays a substantial role in the terrestrial ecotoxicity potential. The study highlights the diverse environmental impacts of bisphenol A and phosgene across various indicators. In response to these findings, recommendations are presented, encompassing the enhancement of raw material efficiency, refinement of production processes, and reduction of energy consumption. Implementing these measures effectively alleviates the environmental impact of PC production, concurrently improving the efficiency and economic benefits. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health. Based on the LCA results, improvement suggestions were proposed to increase raw material utilization, improve raw material production processes, reduce energy consumption in the production process, and control direct emissions of pollutants. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health.</p>\",\"PeriodicalId\":25,\"journal\":{\"name\":\"ACS Sustainable Chemistry & Engineering\",\"volume\":\"13 34\",\"pages\":\"14084–14098\"},\"PeriodicalIF\":7.3000,\"publicationDate\":\"2025-08-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Sustainable Chemistry & Engineering\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acssuschemeng.5c05781\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sustainable Chemistry & Engineering","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acssuschemeng.5c05781","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Improving the Sustainability of Polycarbonate Production through Life Cycle Assessment and Process Optimization
In this study, the whole process model of the interfacial polycondensation polycarbonate (PC) production process was established by using Aspen Plus. Then, the steady-state simulation of each process in the production process was carried out, and the material balance and energy balance results of the whole process were obtained. The simulation results were combined with actual production to establish a list of resource consumption and pollutant emissions in the PC production process by interfacial polycondensation. The environmental impact of producing 300,000 tons of PC was analyzed by life cycle assessment (LCA). The investigation reveals that the marine aquatic toxicity potential (MAP) is the predominant environmental impact, accounting for 85.35% of the total impact. Specifically, the bisphenol salt prefabrication stage emerges as the major contributor, representing 56.88% of the overall impact. Furthermore, sodium hydroxide utilization significantly influences ozone layer depletion, while electricity consumption plays a substantial role in the terrestrial ecotoxicity potential. The study highlights the diverse environmental impacts of bisphenol A and phosgene across various indicators. In response to these findings, recommendations are presented, encompassing the enhancement of raw material efficiency, refinement of production processes, and reduction of energy consumption. Implementing these measures effectively alleviates the environmental impact of PC production, concurrently improving the efficiency and economic benefits. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health. Based on the LCA results, improvement suggestions were proposed to increase raw material utilization, improve raw material production processes, reduce energy consumption in the production process, and control direct emissions of pollutants. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health.
期刊介绍:
ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment.
The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.