通过生命周期评估和工艺优化提高聚碳酸酯生产的可持续性

IF 7.3 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Pan Xu, Jingyi Yao, Haixing Yang, Jianyong Mao, Jijun Ge, Guoxuan Li* and Rongshan Bi*, 
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引用次数: 0

摘要

本研究利用Aspen Plus建立了界面缩聚聚碳酸酯(PC)生产过程的全过程模型。然后对生产过程中各工序进行稳态仿真,得到了整个过程的物料衡算和能量衡算结果。将模拟结果与实际生产相结合,建立了界面缩聚生产PC过程的资源消耗和污染物排放清单。采用生命周期评价(LCA)方法对生产30万吨PC的环境影响进行了分析。调查结果表明,海洋水生毒性潜势(MAP)是主要的环境影响,占总影响的85.35%。具体而言,双酚盐预制阶段成为主要贡献者,占总体影响的56.88%。此外,氢氧化钠的利用显著影响臭氧层消耗,而电力消耗在陆地生态毒性潜力中起着重要作用。该研究强调了双酚A和光气在不同指标上对环境的不同影响。针对这些发现,提出了建议,包括提高原材料效率、改进生产过程和减少能源消耗。这些措施的实施有效地减轻了PC生产对环境的影响,同时提高了效率和经济效益。这项研究为优化PC生产过程、促进可持续发展目标和保护环境健康提供了有价值的见解。根据LCA结果,提出了提高原料利用率、改进原料生产工艺、降低生产过程能耗、控制污染物直接排放的改进建议。这项研究为优化PC生产过程、促进可持续发展目标和保护环境健康提供了有价值的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Improving the Sustainability of Polycarbonate Production through Life Cycle Assessment and Process Optimization

Improving the Sustainability of Polycarbonate Production through Life Cycle Assessment and Process Optimization

In this study, the whole process model of the interfacial polycondensation polycarbonate (PC) production process was established by using Aspen Plus. Then, the steady-state simulation of each process in the production process was carried out, and the material balance and energy balance results of the whole process were obtained. The simulation results were combined with actual production to establish a list of resource consumption and pollutant emissions in the PC production process by interfacial polycondensation. The environmental impact of producing 300,000 tons of PC was analyzed by life cycle assessment (LCA). The investigation reveals that the marine aquatic toxicity potential (MAP) is the predominant environmental impact, accounting for 85.35% of the total impact. Specifically, the bisphenol salt prefabrication stage emerges as the major contributor, representing 56.88% of the overall impact. Furthermore, sodium hydroxide utilization significantly influences ozone layer depletion, while electricity consumption plays a substantial role in the terrestrial ecotoxicity potential. The study highlights the diverse environmental impacts of bisphenol A and phosgene across various indicators. In response to these findings, recommendations are presented, encompassing the enhancement of raw material efficiency, refinement of production processes, and reduction of energy consumption. Implementing these measures effectively alleviates the environmental impact of PC production, concurrently improving the efficiency and economic benefits. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health. Based on the LCA results, improvement suggestions were proposed to increase raw material utilization, improve raw material production processes, reduce energy consumption in the production process, and control direct emissions of pollutants. This research provides valuable insights into optimizing the PC production process, contributing to sustainability goals, and preserving environmental health.

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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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