通过与两种商用碳的比较,从甘蔗渣中提取一种创新的定型碳的技术特征

IF 3.9 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Katrin Markuske , Katja Schaldach , Thomas Storch , Kabriil Khajryan , Volker Herdegen , Tobias Michael Fieback
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引用次数: 0

摘要

利用可再生原料开发吸附剂,为减少对充填床流体净化对化石资源的依赖提供了一种可持续的选择。甘蔗渣是一种具有高生态和增值潜力的有前途的原料,从甘蔗渣中提取颗粒状碳吸附剂是本研究的重点。进行了全面的物理力学和吸附特性(如比表面积、孔径分布、孔体积)。在特定的应用领域,用重量法测定了蔗渣成型碳在293 K下对CO₂、N₂和CH₄的吸附行为,以及其在压力变化(0.1/3.0 MPa)下的循环稳定性,并与两种商用活性炭(Norit®ROW和HOK®activated Lignite)进行了比较。此外,利用突破行为和评价碘和亚甲基蓝数在水分离应用中的适用性表明了工业性能。从甘蔗渣中提取的成型碳表现出了良好的性能,包括球盘硬度为~ 99%,比表面积为~ 390 m²/g。这项研究强调了甘蔗渣衍生的形状碳作为一种可持续和有效的吸附剂的潜力。研究结果提供了材料的全面分类,使其能够根据材料特性有针对性地选择气体和水分离任务。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Technological characterisation of an innovative, shaped carbon from bagasse by comparison to two commercially available carbons

Technological characterisation of an innovative, shaped carbon from bagasse by comparison to two commercially available carbons
Developing adsorbents from renewable raw materials offers a sustainable alternative to reduce reliance on fossil resources for fluid stream purification in packed beds. This study focuses on a pelletised shaped carbon adsorbent derived from bagasse, an agricultural by-product of sugar production, as a promising raw material with high ecological and value-enhancing potential. Comprehensive physico-mechanical and adsorption-specific characterisations (e.g., specific surface area, pore size distribution, pore volume) were conducted. With regard to specific areas of application, the adsorption behaviour of the shaped carbon from bagasse for CO₂, N₂, and CH₄ at 293 K, as well as its cycle stability under pressure variations (0.1/3.0 MPa), were determined gravimetrically and compared to two commercial activated carbons (Norit® ROW and HOK® Activated Lignite). In addition, industrial performance is indicated using breakthrough behaviour and evaluating the suitability for aqueous separation applications by iodine and methylene blue number.
The shaped carbon from bagasse demonstrated promising properties, including a ball pan hardness of ∼ 99 % and a specific surface area of ∼ 390 m²/g. This study highlights the potential of bagasse-derived shaped carbon as a sustainable and efficient adsorbent. The findings provide a comprehensive classification of the material, enabling its targeted selection for gaseous and aqueous separation tasks based on material properties.
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来源期刊
Carbon Trends
Carbon Trends Materials Science-Materials Science (miscellaneous)
CiteScore
4.60
自引率
0.00%
发文量
88
审稿时长
77 days
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