Melena Groß, Patrick Schmidt, Carl P. Romao, David Enseling, Thomas Jüstel, Mykhailo Brytskyi, Scott Kroeker, Hans-Jürgen Meyer
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Hydrothermal Synthesis and Characterization of the Melamine-Based Second-Harmonic Generation Material HgCl2(C3N6H6)
The pursuit of efficient nonlinear optical materials is critical for advancing optoelectronic applications. This study focuses on the synthesis and characterization of HgCl2(C3N6H6), a melamine-based hybrid metal halide. Structural analysis reveals a non-centrosymmetric lattice facilitated by large asymmetric secondary building units and a π-conjugated system. The compound exhibits a strong second-harmonic generation efficiency. Density functional theory calculations, optical band gap measurements, and photoluminescence measurements specify the electronic properties. For completeness and analytical comparison, the centrosymmetric compound Hg2Cl2(C3N6H6)2 is also introduced.
期刊介绍:
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.