Doris M. Grössl, Bettina Schlemmer, Virginia Lafranconi, Nina M. Tasch, Christoph Garstenauer, Lara Rezo, Melanie Moosbrugger, Michaela Flock, Roland C. Fischer, Thomas Rath, Ana Torvisco, Gregor Trimmel, Frank Uhlig
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Tin Porphyrins with Germyl- and Silylalkynyl Substitution: Synthesis, Characterization, and Solar Cell Applications
Porphyrins, known for their extensive biological functions, have been adapted for diverse applications through modification of their substitution patterns and metal centers. This study focuses on synthesizing tin porphyrins with germyl- and silyl-alkenyl substituents, addressing gaps in structural characterization and solubility behavior. Additionally, their potential in bulk-heterojunction solar cells is investigated. The synthetic pathways for these porphyrins are established, and their structural properties are analyzed using single crystal X-ray diffraction. The solubility of the synthesized porphyrin (5) is compared with meso-tetraaryl and meso-tetraalkyl free-base porphyrins. Electrochemical properties are studied through cyclic voltammetry, and density functional theory (DFT) calculations provide insights into the highest occupied and lowest unoccupied molecular orbitals. Despite promising optical and electrochemical properties, the solar cell performance of the synthesized porphyrins remains moderate, highlighting the need for further functionalization to enhance the power conversion efficiency.
期刊介绍:
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.