具有Germyl-和silyl炔基取代的锡卟啉:合成、表征和太阳能电池应用

IF 2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Doris M. Grössl, Bettina Schlemmer, Virginia Lafranconi, Nina M. Tasch, Christoph Garstenauer, Lara Rezo, Melanie Moosbrugger, Michaela Flock, Roland C. Fischer, Thomas Rath, Ana Torvisco, Gregor Trimmel, Frank Uhlig
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引用次数: 0

摘要

卟啉以其广泛的生物学功能而闻名,通过改变其取代模式和金属中心,卟啉已适应于各种应用。本研究的重点是合成具有乙烯基和硅基烯基取代基的锡卟啉,解决结构表征和溶解度行为方面的空白。此外,还研究了它们在异质结太阳能电池中的应用潜力。建立了这些卟啉的合成途径,并用单晶x射线衍射分析了它们的结构性质。将合成的卟啉(5)与中-四芳基和中-四烷基游离基卟啉进行了溶解度比较。通过循环伏安法研究了电化学性质,密度泛函理论(DFT)计算提供了对最高占据和最低未占据分子轨道的见解。尽管所合成的卟啉具有良好的光学和电化学性能,但其太阳能电池性能仍不理想,因此需要进一步功能化以提高功率转换效率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Tin Porphyrins with Germyl- and Silylalkynyl Substitution: Synthesis, Characterization, and Solar Cell Applications

Tin Porphyrins with Germyl- and Silylalkynyl Substitution: Synthesis, Characterization, and Solar Cell Applications

Tin Porphyrins with Germyl- and Silylalkynyl Substitution: Synthesis, Characterization, and Solar Cell Applications

Tin Porphyrins with Germyl- and Silylalkynyl Substitution: Synthesis, Characterization, and Solar Cell Applications

Tin Porphyrins with Germyl- and Silylalkynyl Substitution: Synthesis, Characterization, and Solar Cell Applications

Tin Porphyrins with Germyl- and Silylalkynyl Substitution: Synthesis, Characterization, and Solar Cell Applications

Porphyrins, known for their extensive biological functions, have been adapted for diverse applications through modification of their substitution patterns and metal centers. This study focuses on synthesizing tin porphyrins with germyl- and silyl-alkenyl substituents, addressing gaps in structural characterization and solubility behavior. Additionally, their potential in bulk-heterojunction solar cells is investigated. The synthetic pathways for these porphyrins are established, and their structural properties are analyzed using single crystal X-ray diffraction. The solubility of the synthesized porphyrin (5) is compared with meso-tetraaryl and meso-tetraalkyl free-base porphyrins. Electrochemical properties are studied through cyclic voltammetry, and density functional theory (DFT) calculations provide insights into the highest occupied and lowest unoccupied molecular orbitals. Despite promising optical and electrochemical properties, the solar cell performance of the synthesized porphyrins remains moderate, highlighting the need for further functionalization to enhance the power conversion efficiency.

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来源期刊
European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
4.30
自引率
4.30%
发文量
419
审稿时长
1.3 months
期刊介绍: The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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