Najeeb Manhanpally , Praveen Nagarajan , Suman Saha , Sudha Das , Blessen Skariah Thomas , Thandiwe Sithole
{"title":"基于田口的M60级ggbs -白云石基地聚合物混凝土配合比设计参数优化","authors":"Najeeb Manhanpally , Praveen Nagarajan , Suman Saha , Sudha Das , Blessen Skariah Thomas , Thandiwe Sithole","doi":"10.1016/j.scp.2025.102181","DOIUrl":null,"url":null,"abstract":"<div><div>Geopolymer concrete (GPC) has emerged as a sustainable alternative to Portland cement concrete with reduced CO<sub>2</sub> emissions per tonne of concrete. However, its mix design is complex due to multiple interrelated factors such as binder content, binder proportion, alkaline activator to binder ratio (AAS/B), sodium silicate to sodium hydroxide ratio (SS/SH), and NaOH molarity, often requiring numerous trial mixes. This complexity makes the process time-consuming and a barrier to its widespread adoption. This study presents a systematic approach to optimise high-strength (M60 grade) GPC using slag and dolomite as binders under ambient curing conditions. The Taguchi method was used to evaluate five mix parameters at four levels each, reducing the number of experimental trials from 1024 (factorial design) to just 16. The results showed that binder proportion, AAS/B ratio, and NaOH molarity significantly affect both compressive strength and workability. AAS/B ratio was most influential on workability, while binder proportion critically influenced strength. The optimised mix—430 kg/m<sup>3</sup> binder, 80:20 GGBS:dolomite, AAS/B = 0.45, SS/SH = 2, and 10 M NaOH—achieved a 28-day compressive strength of 71.10 N/mm<sup>2</sup>. A regression model is developed using standardised data to predict compressive strength for high strength slag-dolomite based geopolymer concrete, which yielded a high predictive accuracy (R<sup>2</sup> = 0.94, RMSE = 2.01 N/mm<sup>2</sup>, MAE = 1.577 N/mm<sup>2</sup>). The novelty of this work lies in combining GGBS and dolomite in ambient-cured GPC, guided by a robust statistical framework. The Taguchi method is effective in simplifying the optimisation process, offering a cost-efficient, less labour-intensive, and reproducible strategy for mix design in complex geopolymer systems.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102181"},"PeriodicalIF":5.8000,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Taguchi based optimisation of mix design parameters for M60 Grade GGBS-dolomite based geopolymer concrete\",\"authors\":\"Najeeb Manhanpally , Praveen Nagarajan , Suman Saha , Sudha Das , Blessen Skariah Thomas , Thandiwe Sithole\",\"doi\":\"10.1016/j.scp.2025.102181\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Geopolymer concrete (GPC) has emerged as a sustainable alternative to Portland cement concrete with reduced CO<sub>2</sub> emissions per tonne of concrete. However, its mix design is complex due to multiple interrelated factors such as binder content, binder proportion, alkaline activator to binder ratio (AAS/B), sodium silicate to sodium hydroxide ratio (SS/SH), and NaOH molarity, often requiring numerous trial mixes. This complexity makes the process time-consuming and a barrier to its widespread adoption. This study presents a systematic approach to optimise high-strength (M60 grade) GPC using slag and dolomite as binders under ambient curing conditions. The Taguchi method was used to evaluate five mix parameters at four levels each, reducing the number of experimental trials from 1024 (factorial design) to just 16. The results showed that binder proportion, AAS/B ratio, and NaOH molarity significantly affect both compressive strength and workability. AAS/B ratio was most influential on workability, while binder proportion critically influenced strength. The optimised mix—430 kg/m<sup>3</sup> binder, 80:20 GGBS:dolomite, AAS/B = 0.45, SS/SH = 2, and 10 M NaOH—achieved a 28-day compressive strength of 71.10 N/mm<sup>2</sup>. A regression model is developed using standardised data to predict compressive strength for high strength slag-dolomite based geopolymer concrete, which yielded a high predictive accuracy (R<sup>2</sup> = 0.94, RMSE = 2.01 N/mm<sup>2</sup>, MAE = 1.577 N/mm<sup>2</sup>). The novelty of this work lies in combining GGBS and dolomite in ambient-cured GPC, guided by a robust statistical framework. The Taguchi method is effective in simplifying the optimisation process, offering a cost-efficient, less labour-intensive, and reproducible strategy for mix design in complex geopolymer systems.</div></div>\",\"PeriodicalId\":22138,\"journal\":{\"name\":\"Sustainable Chemistry and Pharmacy\",\"volume\":\"47 \",\"pages\":\"Article 102181\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-08-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sustainable Chemistry and Pharmacy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352554125002797\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Chemistry and Pharmacy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352554125002797","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Taguchi based optimisation of mix design parameters for M60 Grade GGBS-dolomite based geopolymer concrete
Geopolymer concrete (GPC) has emerged as a sustainable alternative to Portland cement concrete with reduced CO2 emissions per tonne of concrete. However, its mix design is complex due to multiple interrelated factors such as binder content, binder proportion, alkaline activator to binder ratio (AAS/B), sodium silicate to sodium hydroxide ratio (SS/SH), and NaOH molarity, often requiring numerous trial mixes. This complexity makes the process time-consuming and a barrier to its widespread adoption. This study presents a systematic approach to optimise high-strength (M60 grade) GPC using slag and dolomite as binders under ambient curing conditions. The Taguchi method was used to evaluate five mix parameters at four levels each, reducing the number of experimental trials from 1024 (factorial design) to just 16. The results showed that binder proportion, AAS/B ratio, and NaOH molarity significantly affect both compressive strength and workability. AAS/B ratio was most influential on workability, while binder proportion critically influenced strength. The optimised mix—430 kg/m3 binder, 80:20 GGBS:dolomite, AAS/B = 0.45, SS/SH = 2, and 10 M NaOH—achieved a 28-day compressive strength of 71.10 N/mm2. A regression model is developed using standardised data to predict compressive strength for high strength slag-dolomite based geopolymer concrete, which yielded a high predictive accuracy (R2 = 0.94, RMSE = 2.01 N/mm2, MAE = 1.577 N/mm2). The novelty of this work lies in combining GGBS and dolomite in ambient-cured GPC, guided by a robust statistical framework. The Taguchi method is effective in simplifying the optimisation process, offering a cost-efficient, less labour-intensive, and reproducible strategy for mix design in complex geopolymer systems.
期刊介绍:
Sustainable Chemistry and Pharmacy publishes research that is related to chemistry, pharmacy and sustainability science in a forward oriented manner. It provides a unique forum for the publication of innovative research on the intersection and overlap of chemistry and pharmacy on the one hand and sustainability on the other hand. This includes contributions related to increasing sustainability of chemistry and pharmaceutical science and industries itself as well as their products in relation to the contribution of these to sustainability itself. As an interdisciplinary and transdisciplinary journal it addresses all sustainability related issues along the life cycle of chemical and pharmaceutical products form resource related topics until the end of life of products. This includes not only natural science based approaches and issues but also from humanities, social science and economics as far as they are dealing with sustainability related to chemistry and pharmacy. Sustainable Chemistry and Pharmacy aims at bridging between disciplines as well as developing and developed countries.