反应系统的精确核磁共振扩散测量

IF 1.1 4区物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL

Applied Magnetic Resonance Pub Date : 2025-08-18 DOI:10.1007/s00723-025-01779-8

William S. Price

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引用次数: 0

摘要

核磁共振扩散测量有希望提供深入了解化学反应和过程，包括自组装，反应动力学，结晶和结合。然而，当化学系统在扩散测量的时间尺度上发生变化时，在数据的性能和解释上都必须非常小心。本文考虑了各种核磁共振扩散时间尺度，时变系统产生的一些问题，以及消除或至少减少这些问题的各种方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Accurate NMR Diffusion Measurements of Reacting Systems

NMR diffusion measurements have the promise to provide deep insight into chemical reactions and processes including self-assembly, reaction kinetics, crystallization, and binding. However, when the chemical system alters on the timescale of the diffusion measurement, great care must be taken in both the performance and interpretation of the data. This paper considers the various NMR diffusion timescales, some of the problems that arise with time-variant systems, and various ways that the problems can be removed or at least reduced.

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来源期刊

Applied Magnetic Resonance 物理-光谱学

CiteScore

1.90

自引率

10.00%

发文量

审稿时长

2.3 months

期刊介绍： Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.