{"title":"金属衬底上Ge光栅/SrTiO3 /VO2混合元结构的角度稳健和可调谐中红外吸收","authors":"Xin Cui, Yangyang Dai, Fenglin Xian, Liming Qian and Gaige Zheng","doi":"10.1039/D5DT01725D","DOIUrl":null,"url":null,"abstract":"<p >We propose a dynamically tunable and angle-robust mid-infrared (mid-IR) absorber based on a hybrid metastructure composed of a top-layer Ge grating, an ultrathin SrTiO<small><sub>3</sub></small> polar dielectric layer, a thermochromic VO<small><sub>2</sub></small> film, and a metallic substrate. The optical response of the system is modeled using rigorous coupled-wave analysis (RCWA), revealing broadband and high-efficiency absorption across a wide range of incident angles (0°–80°) under transverse-magnetic (TM) polarization. The absorption behavior is governed by the interplay of multiple resonant mechanisms, including guided-mode resonance (GMR) in the Ge grating, phonon–polariton (PhP) excitation in the SrTiO<small><sub>3</sub></small> layer, and cavity-like modes facilitated by the insulating VO<small><sub>2</sub></small>. By varying structural parameters such as the grating period (<em>p</em> = 6–10 μm), fill factor (<em>f</em> = 0.4–0.7), and the thicknesses of SrTiO<small><sub>3</sub></small> and VO<small><sub>2</sub></small>, we map the design space for optimized performance. Numerical results confirm that strong field confinement and mode hybridization are responsible for the observed angular stability and tunability. This theoretical framework provides critical insights for the design of active mid-IR metastructures with application potential in thermal modulation, reconfigurable optics, and infrared photonic circuitry.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 37","pages":" 13990-14000"},"PeriodicalIF":3.3000,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Angle-robust and tunable mid-infrared absorption in a Ge grating/SrTiO3/VO2 hybrid metastructure on a metallic substrate\",\"authors\":\"Xin Cui, Yangyang Dai, Fenglin Xian, Liming Qian and Gaige Zheng\",\"doi\":\"10.1039/D5DT01725D\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >We propose a dynamically tunable and angle-robust mid-infrared (mid-IR) absorber based on a hybrid metastructure composed of a top-layer Ge grating, an ultrathin SrTiO<small><sub>3</sub></small> polar dielectric layer, a thermochromic VO<small><sub>2</sub></small> film, and a metallic substrate. The optical response of the system is modeled using rigorous coupled-wave analysis (RCWA), revealing broadband and high-efficiency absorption across a wide range of incident angles (0°–80°) under transverse-magnetic (TM) polarization. The absorption behavior is governed by the interplay of multiple resonant mechanisms, including guided-mode resonance (GMR) in the Ge grating, phonon–polariton (PhP) excitation in the SrTiO<small><sub>3</sub></small> layer, and cavity-like modes facilitated by the insulating VO<small><sub>2</sub></small>. By varying structural parameters such as the grating period (<em>p</em> = 6–10 μm), fill factor (<em>f</em> = 0.4–0.7), and the thicknesses of SrTiO<small><sub>3</sub></small> and VO<small><sub>2</sub></small>, we map the design space for optimized performance. Numerical results confirm that strong field confinement and mode hybridization are responsible for the observed angular stability and tunability. This theoretical framework provides critical insights for the design of active mid-IR metastructures with application potential in thermal modulation, reconfigurable optics, and infrared photonic circuitry.</p>\",\"PeriodicalId\":71,\"journal\":{\"name\":\"Dalton Transactions\",\"volume\":\" 37\",\"pages\":\" 13990-14000\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2025-08-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dalton Transactions\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/dt/d5dt01725d\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/dt/d5dt01725d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Angle-robust and tunable mid-infrared absorption in a Ge grating/SrTiO3/VO2 hybrid metastructure on a metallic substrate
We propose a dynamically tunable and angle-robust mid-infrared (mid-IR) absorber based on a hybrid metastructure composed of a top-layer Ge grating, an ultrathin SrTiO3 polar dielectric layer, a thermochromic VO2 film, and a metallic substrate. The optical response of the system is modeled using rigorous coupled-wave analysis (RCWA), revealing broadband and high-efficiency absorption across a wide range of incident angles (0°–80°) under transverse-magnetic (TM) polarization. The absorption behavior is governed by the interplay of multiple resonant mechanisms, including guided-mode resonance (GMR) in the Ge grating, phonon–polariton (PhP) excitation in the SrTiO3 layer, and cavity-like modes facilitated by the insulating VO2. By varying structural parameters such as the grating period (p = 6–10 μm), fill factor (f = 0.4–0.7), and the thicknesses of SrTiO3 and VO2, we map the design space for optimized performance. Numerical results confirm that strong field confinement and mode hybridization are responsible for the observed angular stability and tunability. This theoretical framework provides critical insights for the design of active mid-IR metastructures with application potential in thermal modulation, reconfigurable optics, and infrared photonic circuitry.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.