{"title":"光催化水氧化和氧还原反应的供体-受体共价有机框架","authors":"Akhtar Alam, Pekham Chakrabortty, Avanti Chakraborty, Samrat Ghosh, Pradip Pachfule","doi":"10.1002/cctc.202501000","DOIUrl":null,"url":null,"abstract":"<p>Covalent organic frameworks (COFs) are considered as the next generation of organic photocatalysts for the conversion of solar energy into fuels or chemicals. Compared to the traditional heterogeneous photocatalysts, COFs have emerged as organic photocatalysts and have been tested for various photocatalytic transformations such as hydrogen evolution, hydrogen peroxide generation, carbon dioxide reduction and organic transformations. In particular, donor–acceptor (D–A) COFs showed enhanced photocatalytic activity, where electron-rich donor (D) and electron-deficient acceptor (A) are alternately arranged in the framework. The high photocatalytic activity of D–A COFs is attributed to the tunable band gap, efficient charge separation and charge transport through the bicontinuous heterojunction. In recent years, several D–A COFs have been reported for photocatalytic reactions, especially tested for photocatalytic generation of hydrogen and hydrogen peroxide involving water oxidation and oxygen reduction reactions. In this review, we have summarized these reports and presented a critical perspective with the fundamental understanding of D–A COFs. In addition, this review discusses the different design principles adopted and the synthesis of crystalline D–A COFs with different linkages and their effect on the photocatalytic efficiency. Finally, this review will provide an overview of the design of D–A COFs for photocatalysis, addressing the challenges and opportunities involved.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 16","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Donor–Acceptor Covalent Organic Frameworks for Photocatalytic Water Oxidation and Oxygen Reduction Reactions\",\"authors\":\"Akhtar Alam, Pekham Chakrabortty, Avanti Chakraborty, Samrat Ghosh, Pradip Pachfule\",\"doi\":\"10.1002/cctc.202501000\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Covalent organic frameworks (COFs) are considered as the next generation of organic photocatalysts for the conversion of solar energy into fuels or chemicals. Compared to the traditional heterogeneous photocatalysts, COFs have emerged as organic photocatalysts and have been tested for various photocatalytic transformations such as hydrogen evolution, hydrogen peroxide generation, carbon dioxide reduction and organic transformations. In particular, donor–acceptor (D–A) COFs showed enhanced photocatalytic activity, where electron-rich donor (D) and electron-deficient acceptor (A) are alternately arranged in the framework. The high photocatalytic activity of D–A COFs is attributed to the tunable band gap, efficient charge separation and charge transport through the bicontinuous heterojunction. In recent years, several D–A COFs have been reported for photocatalytic reactions, especially tested for photocatalytic generation of hydrogen and hydrogen peroxide involving water oxidation and oxygen reduction reactions. In this review, we have summarized these reports and presented a critical perspective with the fundamental understanding of D–A COFs. In addition, this review discusses the different design principles adopted and the synthesis of crystalline D–A COFs with different linkages and their effect on the photocatalytic efficiency. Finally, this review will provide an overview of the design of D–A COFs for photocatalysis, addressing the challenges and opportunities involved.</p>\",\"PeriodicalId\":141,\"journal\":{\"name\":\"ChemCatChem\",\"volume\":\"17 16\",\"pages\":\"\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-07-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemCatChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202501000\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemCatChem","FirstCategoryId":"92","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202501000","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Donor–Acceptor Covalent Organic Frameworks for Photocatalytic Water Oxidation and Oxygen Reduction Reactions
Covalent organic frameworks (COFs) are considered as the next generation of organic photocatalysts for the conversion of solar energy into fuels or chemicals. Compared to the traditional heterogeneous photocatalysts, COFs have emerged as organic photocatalysts and have been tested for various photocatalytic transformations such as hydrogen evolution, hydrogen peroxide generation, carbon dioxide reduction and organic transformations. In particular, donor–acceptor (D–A) COFs showed enhanced photocatalytic activity, where electron-rich donor (D) and electron-deficient acceptor (A) are alternately arranged in the framework. The high photocatalytic activity of D–A COFs is attributed to the tunable band gap, efficient charge separation and charge transport through the bicontinuous heterojunction. In recent years, several D–A COFs have been reported for photocatalytic reactions, especially tested for photocatalytic generation of hydrogen and hydrogen peroxide involving water oxidation and oxygen reduction reactions. In this review, we have summarized these reports and presented a critical perspective with the fundamental understanding of D–A COFs. In addition, this review discusses the different design principles adopted and the synthesis of crystalline D–A COFs with different linkages and their effect on the photocatalytic efficiency. Finally, this review will provide an overview of the design of D–A COFs for photocatalysis, addressing the challenges and opportunities involved.
期刊介绍:
With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.