高温自扩散合成新型多孔材料及其在车辆中和催化剂中的应用

IF 0.6 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
A. I. Khvadagiani, M. E. Iremadze, R. M. Topuria, D. G. Zalkaliani, R. M. Pilia
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引用次数: 0

摘要

目前,汽车尾气是造成环境污染的主要因素之一。这一问题在发展中国家尤为严重,因为在发展中国家,二手车的比例很高,因为二手车的催化转化器部分或经常完全失灵,导致空气中一氧化碳、一氧化氮和碳氢化合物等有毒物质增加。我们利用SHS方法获得了一种新型的催化底物,其中贵金属(铂、钯、铑)可以部分或完全被铜、镍、铬等金属取代。当用SHS法获得催化底物时,正确选择反应初始充电材料的化学成分是最终导致获得具有所需性能的产品的决定性因素。添加剂金属(铜、铬、镍等)由于分散程度高,不参与反应,因此不形成化合物,在最终产物中分布均匀,显著提高了其催化活性的质量。所得样品的孔隙率受初始样品密度的显著影响。通过改变样品的初始孔隙率,可以改变最终产品的孔隙率从5%到45%。该技术的应用降低了中和剂催化剂的生产成本,解决了中和剂催化剂稀缺的问题。所获得的材料可用于所有类型的内燃机车辆,以及废气和液体催化净化的企业。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Obtaining New Porous Materials by Self-Propagating High-Temperature Synthesis and Using Them as Neutralizing Catalysts in Vehicles

At present, vehicle exhausts are among the major factors of environmental pollution. This problem is particularly acute in developing countries, where the share of used cars is high because the catalytic converters in used cars are partially or often completely out of order, which leads to the increase of toxic substances in the air such as carbon monoxide, nitric oxides, and hydrocarbons. We used the SHS method to obtain a new type of catalytic substrate, in which precious metals (platinum, palladium, rhodium) can be partially or completely replaced with metals such as copper, nickel, chromium, etc. When obtaining the catalytic substrate by the SHS method, the correct selection of a chemical composition of the initial charging material of the reaction is a determining factor that ultimately leads to obtaining products with the desired properties. Due to the high degree of dispersion of additive metals (copper, chromium, nickel, etc.), they do not participate in the reaction, therefore, they do not form chemical compounds, and they are evenly distributed in the final product, which significantly increases the quality of their catalytic activity. The porosity of the obtained sample is significantly affected by the density of the initial sample. By changing the initial porosity of the sample, it is possible to vary the porosity of the final product from 5 to 45%. Application of the proposed technology reduces the neutralizer-catalyst’s production cost and solves the problem of its scarcity. The obtained materials can be used in all types of vehicles with internal combustion engines, as well as in enterprises where catalytic purification of exhaust gases and liquids takes place.

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来源期刊
CiteScore
1.00
自引率
33.30%
发文量
27
期刊介绍: International Journal of Self-Propagating High-Temperature Synthesis  is an international journal covering a wide range of topics concerned with self-propagating high-temperature synthesis (SHS), the process for the production of advanced materials based on solid-state combustion utilizing internally generated chemical energy. Subjects range from the fundamentals of SHS processes, chemistry and technology of SHS products and advanced materials to problems concerned with related fields, such as the kinetics and thermodynamics of high-temperature chemical reactions, combustion theory, macroscopic kinetics of nonisothermic processes, etc. The journal is intended to provide a wide-ranging exchange of research results and a better understanding of developmental and innovative trends in SHS science and applications.
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