Chenlong Wei , Xuexiang Wang , Jiayu Fang , Huihui Qiao , Jun Wen , Peng Tong
{"title":"微波烧结添加金属铼制备高强度钨合金的研究","authors":"Chenlong Wei , Xuexiang Wang , Jiayu Fang , Huihui Qiao , Jun Wen , Peng Tong","doi":"10.1016/j.ijrmhm.2025.107378","DOIUrl":null,"url":null,"abstract":"<div><div>Tungsten alloys are widely used in military, industrial and medical fields due to their excellent mechanical properties. However, they also face the problem of insufficient strength in extreme environments at the same time. In this study, green embryos were prepared by powder metallurgy and sintered in a microwave tube furnace at different temperatures. Tungsten alloy samples of 90 W-7Ni-3Fe (90 W) and 90 W-7Ni-3Fe with an additional 1 wt% Re(90 W-Re) were successfully prepared. The surface and cross-sectional morphologies of both were analyzed, and the influence of adding rhenium on the grain size and mechanical properties of tungsten alloys was studied. In this experiment, 90 W-Re achieved a density of 98.93 % at 1475 °C and a maximum bending strength of 2024.1 MPa at 1500 °C, which was 229.1 MPa higher than that of 90 W under the same conditions. It was explored that with the increase of temperature, the fracture mode changed from being dominated by intergranular fracture to transgranular fracture and the dissociation of tungsten from the binder phase γ(Ni, Fe) was dominated. Comprehensively considered, 90 W and 90 W-Re were held at 1475 °C for 10 min to obtain the optimal sintering points of this experiment. The preparation of 90 W-Re through microwave sintering provides a new way to improve the bending strength of tungsten alloys.</div></div>","PeriodicalId":14216,"journal":{"name":"International Journal of Refractory Metals & Hard Materials","volume":"133 ","pages":"Article 107378"},"PeriodicalIF":4.6000,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the high intensity tungsten alloys with the addition of rhenium metal prepared by microwave sintering\",\"authors\":\"Chenlong Wei , Xuexiang Wang , Jiayu Fang , Huihui Qiao , Jun Wen , Peng Tong\",\"doi\":\"10.1016/j.ijrmhm.2025.107378\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Tungsten alloys are widely used in military, industrial and medical fields due to their excellent mechanical properties. However, they also face the problem of insufficient strength in extreme environments at the same time. In this study, green embryos were prepared by powder metallurgy and sintered in a microwave tube furnace at different temperatures. Tungsten alloy samples of 90 W-7Ni-3Fe (90 W) and 90 W-7Ni-3Fe with an additional 1 wt% Re(90 W-Re) were successfully prepared. The surface and cross-sectional morphologies of both were analyzed, and the influence of adding rhenium on the grain size and mechanical properties of tungsten alloys was studied. In this experiment, 90 W-Re achieved a density of 98.93 % at 1475 °C and a maximum bending strength of 2024.1 MPa at 1500 °C, which was 229.1 MPa higher than that of 90 W under the same conditions. It was explored that with the increase of temperature, the fracture mode changed from being dominated by intergranular fracture to transgranular fracture and the dissociation of tungsten from the binder phase γ(Ni, Fe) was dominated. Comprehensively considered, 90 W and 90 W-Re were held at 1475 °C for 10 min to obtain the optimal sintering points of this experiment. The preparation of 90 W-Re through microwave sintering provides a new way to improve the bending strength of tungsten alloys.</div></div>\",\"PeriodicalId\":14216,\"journal\":{\"name\":\"International Journal of Refractory Metals & Hard Materials\",\"volume\":\"133 \",\"pages\":\"Article 107378\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-08-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Refractory Metals & Hard Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0263436825003439\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Refractory Metals & Hard Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0263436825003439","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Study on the high intensity tungsten alloys with the addition of rhenium metal prepared by microwave sintering
Tungsten alloys are widely used in military, industrial and medical fields due to their excellent mechanical properties. However, they also face the problem of insufficient strength in extreme environments at the same time. In this study, green embryos were prepared by powder metallurgy and sintered in a microwave tube furnace at different temperatures. Tungsten alloy samples of 90 W-7Ni-3Fe (90 W) and 90 W-7Ni-3Fe with an additional 1 wt% Re(90 W-Re) were successfully prepared. The surface and cross-sectional morphologies of both were analyzed, and the influence of adding rhenium on the grain size and mechanical properties of tungsten alloys was studied. In this experiment, 90 W-Re achieved a density of 98.93 % at 1475 °C and a maximum bending strength of 2024.1 MPa at 1500 °C, which was 229.1 MPa higher than that of 90 W under the same conditions. It was explored that with the increase of temperature, the fracture mode changed from being dominated by intergranular fracture to transgranular fracture and the dissociation of tungsten from the binder phase γ(Ni, Fe) was dominated. Comprehensively considered, 90 W and 90 W-Re were held at 1475 °C for 10 min to obtain the optimal sintering points of this experiment. The preparation of 90 W-Re through microwave sintering provides a new way to improve the bending strength of tungsten alloys.
期刊介绍:
The International Journal of Refractory Metals and Hard Materials (IJRMHM) publishes original research articles concerned with all aspects of refractory metals and hard materials. Refractory metals are defined as metals with melting points higher than 1800 °C. These are tungsten, molybdenum, chromium, tantalum, niobium, hafnium, and rhenium, as well as many compounds and alloys based thereupon. Hard materials that are included in the scope of this journal are defined as materials with hardness values higher than 1000 kg/mm2, primarily intended for applications as manufacturing tools or wear resistant components in mechanical systems. Thus they encompass carbides, nitrides and borides of metals, and related compounds. A special focus of this journal is put on the family of hardmetals, which is also known as cemented tungsten carbide, and cermets which are based on titanium carbide and carbonitrides with or without a metal binder. Ceramics and superhard materials including diamond and cubic boron nitride may also be accepted provided the subject material is presented as hard materials as defined above.