Yu. A. Teterin, K. I. Maslakov, A. I. Serokurova, M. N. Smirnova, G. E. Nikiforova, N. N. Novitskii, S. A. Sharko, A. Yu. Teterin, M. N. Markelova, V. A. Amelichev, V. A. Ketsko
{"title":"Gd3Ga5O12衬底上Y2.5Ce0.5Fe2.5Ga2.5O12纳米薄膜的离子和相组成","authors":"Yu. A. Teterin, K. I. Maslakov, A. I. Serokurova, M. N. Smirnova, G. E. Nikiforova, N. N. Novitskii, S. A. Sharko, A. Yu. Teterin, M. N. Markelova, V. A. Amelichev, V. A. Ketsko","doi":"10.1134/S0036023625601369","DOIUrl":null,"url":null,"abstract":"<p>The ionic and phase compositions of a nanosized Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> ferrogarnet film produced by dual ion-beam sputter deposition on a Gd<sub>3</sub>Ga<sub>5</sub>O<sub>12</sub> substrate were studied by X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> target for film production was manufactured by gel combustion followed by vacuum annealing. X-ray powder diffraction verified the phase homogeneity of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> both in powder and in films and the absence of cerium dioxide impurity. X-ray photoelectron spectra showed Ce<sup>4+</sup> ions on the surface of the Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> film along with Ce<sup>3+</sup>.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 7","pages":"952 - 959"},"PeriodicalIF":1.5000,"publicationDate":"2025-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ionic and Phase Compositions of a Nanosized Y2.5Ce0.5Fe2.5Ga2.5O12 Film on a Gd3Ga5O12 Substrate\",\"authors\":\"Yu. A. Teterin, K. I. Maslakov, A. I. Serokurova, M. N. Smirnova, G. E. Nikiforova, N. N. Novitskii, S. A. Sharko, A. Yu. Teterin, M. N. Markelova, V. A. Amelichev, V. A. Ketsko\",\"doi\":\"10.1134/S0036023625601369\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The ionic and phase compositions of a nanosized Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> ferrogarnet film produced by dual ion-beam sputter deposition on a Gd<sub>3</sub>Ga<sub>5</sub>O<sub>12</sub> substrate were studied by X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> target for film production was manufactured by gel combustion followed by vacuum annealing. X-ray powder diffraction verified the phase homogeneity of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> both in powder and in films and the absence of cerium dioxide impurity. X-ray photoelectron spectra showed Ce<sup>4+</sup> ions on the surface of the Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> film along with Ce<sup>3+</sup>.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"70 7\",\"pages\":\"952 - 959\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-08-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023625601369\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023625601369","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Ionic and Phase Compositions of a Nanosized Y2.5Ce0.5Fe2.5Ga2.5O12 Film on a Gd3Ga5O12 Substrate
The ionic and phase compositions of a nanosized Y2.5Ce0.5Fe2.5Ga2.5O12 ferrogarnet film produced by dual ion-beam sputter deposition on a Gd3Ga5O12 substrate were studied by X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The Y2.5Ce0.5Fe2.5Ga2.5O12 target for film production was manufactured by gel combustion followed by vacuum annealing. X-ray powder diffraction verified the phase homogeneity of Y2.5Ce0.5Fe2.5Ga2.5O12 both in powder and in films and the absence of cerium dioxide impurity. X-ray photoelectron spectra showed Ce4+ ions on the surface of the Y2.5Ce0.5Fe2.5Ga2.5O12 film along with Ce3+.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.