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具有光致变色、热致变色和发光特性的紫配体为基础的新型铬镉（II）主客体配合聚合物

IF 1.5 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Russian Journal of Inorganic Chemistry Pub Date : 2025-07-09 DOI:10.1134/S0036023625600078
Jiayun Zou, Xiangju Meng, Runwei Wang
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引用次数: 0

摘要

以CdCl2·2.5H2O、H4PTA（邻苯二甲酸）和Bcbpy·2Cl（1,1′-双（3-氰苯基）-[4,4′-联吡啶]-1,1′-diium）自组装合成了一种新型的铬镉（II）主客体配位聚合物[Cd(PTA)0.5 cl](Bcbpy)0.5(1)]。配合物1很少表现出光致变色和热致变色的性质，这是由电子转移过程和紫基形成的。同时，研究了配合物1的光致发光和热致发光性质。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Novel Chromic Cadmium(II) Host-Guest Coordination Polymer Based on a Viologen Ligand Exhibiting Photochromism, Thermochromism, and Luminescent Properties

Novel Chromic Cadmium(II) Host-Guest Coordination Polymer Based on a Viologen Ligand Exhibiting Photochromism, Thermochromism, and Luminescent Properties

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Novel Chromic Cadmium(II) Host-Guest Coordination Polymer Based on a Viologen Ligand Exhibiting Photochromism, Thermochromism, and Luminescent Properties

A novel chromic Cd(II) host-guest coordination polymer [Cd(PTA)0.5Cl](Bcbpy)0.5 (1) has been synthesized through the self-assembly of CdCl2·2.5H2O, H4PTA (pyromelliticacid), and Bcbpy·2Cl (1,1'- bis(3-cyanobenzyl)-[4,4'-bipyridine]-1,1'-diium). Complex 1 exhibits rarely properties of photochromism and thermochromism, which arise from electron transfer progress and form the viologen radicals. Meanwhile, photo- and thermoluminescence properties of complex 1 was studied.

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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍： Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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