Yu-Fang Wang, Yi-Kun Wang, Xi Luo, Tian-Yu Zhao, Li-Ya Wang
{"title":"基于3-（1h -吡唑-4-基）-5-（吡啶-2-基）-1,2,4-三唑和聚羧酸配体的两种Zn（II）配位聚合物的晶体结构和发光性能","authors":"Yu-Fang Wang, Yi-Kun Wang, Xi Luo, Tian-Yu Zhao, Li-Ya Wang","doi":"10.1134/S0036023625601163","DOIUrl":null,"url":null,"abstract":"<p>Two coordination polymers (CPs) {[Zn<sub>2</sub>(HL)(btc)(H<sub>2</sub>O)<sub>2</sub>].4(H<sub>2</sub>O)}<sub><i>n</i></sub> (<b>1</b>) and {[Zn(H<sub>2</sub>L)(btec)<sub>0.5</sub>](H<sub>2</sub>O)}<sub><i>n</i></sub> (<b>2</b>) have been synthesized under hydrothermal conditions by using 3-(1H-pyrazol-4-yl)-5-(pyridin-4-yl)-1,2,4-triazole (H<sub>2</sub>L), 1,3,5-benzenetricarboxylic acid (H<sub>3</sub>btc) and 1,2,4,5-benzenetetracarboxylic acid (H<sub>4</sub>btec) as reagents along with zinc acetate. Compounds <b>1</b> and <b>2</b> have been characterized by elemental analysis, single crystal X-ray diffraction, and IR spectroscopy. Compound <b>1</b> shows a corrugated layered structure, and a 3D supramolecular architecture is further assembled in <b>1</b> via hydrogen-bonding contacts. Compound <b>2</b> exhibits a 3D framework structure. The thermal behavior and the luminescence properties of the two compounds were studied.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 7","pages":"1020 - 1027"},"PeriodicalIF":1.5000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal Structures and Luminescence Properties of Two Zn(II) Coordination Polymers Based on 3-(1H-Pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole and Polycarboxylic Acid Ligands\",\"authors\":\"Yu-Fang Wang, Yi-Kun Wang, Xi Luo, Tian-Yu Zhao, Li-Ya Wang\",\"doi\":\"10.1134/S0036023625601163\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Two coordination polymers (CPs) {[Zn<sub>2</sub>(HL)(btc)(H<sub>2</sub>O)<sub>2</sub>].4(H<sub>2</sub>O)}<sub><i>n</i></sub> (<b>1</b>) and {[Zn(H<sub>2</sub>L)(btec)<sub>0.5</sub>](H<sub>2</sub>O)}<sub><i>n</i></sub> (<b>2</b>) have been synthesized under hydrothermal conditions by using 3-(1H-pyrazol-4-yl)-5-(pyridin-4-yl)-1,2,4-triazole (H<sub>2</sub>L), 1,3,5-benzenetricarboxylic acid (H<sub>3</sub>btc) and 1,2,4,5-benzenetetracarboxylic acid (H<sub>4</sub>btec) as reagents along with zinc acetate. Compounds <b>1</b> and <b>2</b> have been characterized by elemental analysis, single crystal X-ray diffraction, and IR spectroscopy. Compound <b>1</b> shows a corrugated layered structure, and a 3D supramolecular architecture is further assembled in <b>1</b> via hydrogen-bonding contacts. Compound <b>2</b> exhibits a 3D framework structure. The thermal behavior and the luminescence properties of the two compounds were studied.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"70 7\",\"pages\":\"1020 - 1027\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023625601163\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023625601163","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Crystal Structures and Luminescence Properties of Two Zn(II) Coordination Polymers Based on 3-(1H-Pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole and Polycarboxylic Acid Ligands
Two coordination polymers (CPs) {[Zn2(HL)(btc)(H2O)2].4(H2O)}n (1) and {[Zn(H2L)(btec)0.5](H2O)}n (2) have been synthesized under hydrothermal conditions by using 3-(1H-pyrazol-4-yl)-5-(pyridin-4-yl)-1,2,4-triazole (H2L), 1,3,5-benzenetricarboxylic acid (H3btc) and 1,2,4,5-benzenetetracarboxylic acid (H4btec) as reagents along with zinc acetate. Compounds 1 and 2 have been characterized by elemental analysis, single crystal X-ray diffraction, and IR spectroscopy. Compound 1 shows a corrugated layered structure, and a 3D supramolecular architecture is further assembled in 1 via hydrogen-bonding contacts. Compound 2 exhibits a 3D framework structure. The thermal behavior and the luminescence properties of the two compounds were studied.
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
