H. B. Yan, Yanjin Shen, Zicheng Zhao, Rong Cai, Qiaochu Chen, G. F. Dong
{"title":"超声和磁场耦合作用下脉冲电铸Ni-ZrO2纳米复合镀层的性能研究","authors":"H. B. Yan, Yanjin Shen, Zicheng Zhao, Rong Cai, Qiaochu Chen, G. F. Dong","doi":"10.1007/s11837-025-07547-0","DOIUrl":null,"url":null,"abstract":"<div><p>Ni-ZrO<sub>2</sub> nanocomposite coatings were successfully fabricated using pulsed electrodeposition (PED), magnetic field-assisted pulsed electrodeposition (MPED), and ultrasonic–magnetic coupled pulsed electrodeposition (CPED). Comparative analysis revealed that the CPED-derived Ni-ZrO<sub>2</sub> composite coating exhibited a refined microstructure with enhanced densification, achieving surface roughness values of Ra = 85 nm and Rq = 119 nm. Furthermore, the CPED method significantly increased the mass fraction of ZrO<sub>2</sub> nanoparticles within the composite coating compared to both PED and MPED processes. Microhardness testing demonstrated that the Ni-ZrO<sub>2</sub> nanocomposite coatings substantially outperformed pure Ni coatings produced by PED and MPED, with the CPED-deposited coating exhibiting the highest hardness of 407 HV. Tribological evaluations indicated that the CPED-synthesized Ni-ZrO<sub>2</sub> nanocomposite coating displayed minimal mass loss and superior wear resistance. Electrochemical characterization through polarization curves and electrochemical impedance spectroscopy (EIS) confirmed the exceptional corrosion resistance of the CPED-prepared Ni-ZrO<sub>2</sub> coating in a 5-wt.% NaCl solution.</p></div>","PeriodicalId":605,"journal":{"name":"JOM","volume":"77 9","pages":"6781 - 6791"},"PeriodicalIF":2.3000,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on Properties of Ni-ZrO2 Nanocomposite Coatings Prepared by Pulsed Electrocasting Under the Coupling Effect of Ultrasonic and Magnetic Field\",\"authors\":\"H. B. Yan, Yanjin Shen, Zicheng Zhao, Rong Cai, Qiaochu Chen, G. F. Dong\",\"doi\":\"10.1007/s11837-025-07547-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Ni-ZrO<sub>2</sub> nanocomposite coatings were successfully fabricated using pulsed electrodeposition (PED), magnetic field-assisted pulsed electrodeposition (MPED), and ultrasonic–magnetic coupled pulsed electrodeposition (CPED). Comparative analysis revealed that the CPED-derived Ni-ZrO<sub>2</sub> composite coating exhibited a refined microstructure with enhanced densification, achieving surface roughness values of Ra = 85 nm and Rq = 119 nm. Furthermore, the CPED method significantly increased the mass fraction of ZrO<sub>2</sub> nanoparticles within the composite coating compared to both PED and MPED processes. Microhardness testing demonstrated that the Ni-ZrO<sub>2</sub> nanocomposite coatings substantially outperformed pure Ni coatings produced by PED and MPED, with the CPED-deposited coating exhibiting the highest hardness of 407 HV. Tribological evaluations indicated that the CPED-synthesized Ni-ZrO<sub>2</sub> nanocomposite coating displayed minimal mass loss and superior wear resistance. Electrochemical characterization through polarization curves and electrochemical impedance spectroscopy (EIS) confirmed the exceptional corrosion resistance of the CPED-prepared Ni-ZrO<sub>2</sub> coating in a 5-wt.% NaCl solution.</p></div>\",\"PeriodicalId\":605,\"journal\":{\"name\":\"JOM\",\"volume\":\"77 9\",\"pages\":\"6781 - 6791\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2025-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"JOM\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11837-025-07547-0\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"JOM","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11837-025-07547-0","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Study on Properties of Ni-ZrO2 Nanocomposite Coatings Prepared by Pulsed Electrocasting Under the Coupling Effect of Ultrasonic and Magnetic Field
Ni-ZrO2 nanocomposite coatings were successfully fabricated using pulsed electrodeposition (PED), magnetic field-assisted pulsed electrodeposition (MPED), and ultrasonic–magnetic coupled pulsed electrodeposition (CPED). Comparative analysis revealed that the CPED-derived Ni-ZrO2 composite coating exhibited a refined microstructure with enhanced densification, achieving surface roughness values of Ra = 85 nm and Rq = 119 nm. Furthermore, the CPED method significantly increased the mass fraction of ZrO2 nanoparticles within the composite coating compared to both PED and MPED processes. Microhardness testing demonstrated that the Ni-ZrO2 nanocomposite coatings substantially outperformed pure Ni coatings produced by PED and MPED, with the CPED-deposited coating exhibiting the highest hardness of 407 HV. Tribological evaluations indicated that the CPED-synthesized Ni-ZrO2 nanocomposite coating displayed minimal mass loss and superior wear resistance. Electrochemical characterization through polarization curves and electrochemical impedance spectroscopy (EIS) confirmed the exceptional corrosion resistance of the CPED-prepared Ni-ZrO2 coating in a 5-wt.% NaCl solution.
期刊介绍：
JOM is a technical journal devoted to exploring the many aspects of materials science and engineering. JOM reports scholarly work that explores the state-of-the-art processing, fabrication, design, and application of metals, ceramics, plastics, composites, and other materials. In pursuing this goal, JOM strives to balance the interests of the laboratory and the marketplace by reporting academic, industrial, and government-sponsored work from around the world.
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