{"title":"质子束辐照下Cr、Si、Mg共掺Al2O3陶瓷板的热释光性能","authors":"Ayano Okubo , Yutaro Mori , Tomonori Isobe , Takeji Sakae , Yusuke Koba , Weishan Chang , Kiyomitsu Shinsho","doi":"10.1016/j.jlumin.2025.121477","DOIUrl":null,"url":null,"abstract":"<div><div>This study evaluates the thermoluminescence (TL) properties of Cr, Si, and Mg co-doped Al<sub>2</sub>O<sub>3</sub> (Al<sub>2</sub>O<sub>3</sub>:Cr,Si,Mg) ceramic plates under 200 MeV proton beam irradiation, aiming to assess their potential for high-resolution two-dimensional dosimetry in proton therapy. Spectral measurements revealed a dominant TL emission peak at 693 nm, corresponding to the <sup>2</sup>E → <sup>4</sup>A<sub>2</sub> transition of Cr<sup>3+</sup> ions. The glow curves exhibited consistent peak temperature and shape regardless of dose and linear energy transfer (LET), indicating the stability of the trap and recombination centers. The TL response showed excellent linearity with absorbed dose, agreeing within ±1.5 % with ionization chamber measurements, and demonstrated minimal dependence on LET. Furthermore, large-area (200 mm × 200 mm) TL ceramic plates were used to obtain two-dimensional dose distribution maps. The off-axis ratio and percent depth dose distributions measured using TL imaging were in good agreement (within ±1–6 %) with those obtained from standard dosimeters, and the spatial resolution reached 156 μm. These results suggest that Al<sub>2</sub>O<sub>3</sub>:Cr,Si,Mg ceramics are suitable for accurate, reusable, and high-resolution proton dosimetry, offering a promising alternative to conventional film- or ionization-based detectors for quality assurance in particle therapy.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"287 ","pages":"Article 121477"},"PeriodicalIF":3.6000,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermoluminescence properties of Cr, Si, and Mg co-doped Al2O3 ceramics plates under proton beam irradiation\",\"authors\":\"Ayano Okubo , Yutaro Mori , Tomonori Isobe , Takeji Sakae , Yusuke Koba , Weishan Chang , Kiyomitsu Shinsho\",\"doi\":\"10.1016/j.jlumin.2025.121477\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study evaluates the thermoluminescence (TL) properties of Cr, Si, and Mg co-doped Al<sub>2</sub>O<sub>3</sub> (Al<sub>2</sub>O<sub>3</sub>:Cr,Si,Mg) ceramic plates under 200 MeV proton beam irradiation, aiming to assess their potential for high-resolution two-dimensional dosimetry in proton therapy. Spectral measurements revealed a dominant TL emission peak at 693 nm, corresponding to the <sup>2</sup>E → <sup>4</sup>A<sub>2</sub> transition of Cr<sup>3+</sup> ions. The glow curves exhibited consistent peak temperature and shape regardless of dose and linear energy transfer (LET), indicating the stability of the trap and recombination centers. The TL response showed excellent linearity with absorbed dose, agreeing within ±1.5 % with ionization chamber measurements, and demonstrated minimal dependence on LET. Furthermore, large-area (200 mm × 200 mm) TL ceramic plates were used to obtain two-dimensional dose distribution maps. The off-axis ratio and percent depth dose distributions measured using TL imaging were in good agreement (within ±1–6 %) with those obtained from standard dosimeters, and the spatial resolution reached 156 μm. These results suggest that Al<sub>2</sub>O<sub>3</sub>:Cr,Si,Mg ceramics are suitable for accurate, reusable, and high-resolution proton dosimetry, offering a promising alternative to conventional film- or ionization-based detectors for quality assurance in particle therapy.</div></div>\",\"PeriodicalId\":16159,\"journal\":{\"name\":\"Journal of Luminescence\",\"volume\":\"287 \",\"pages\":\"Article 121477\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-08-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Luminescence\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S002223132500417X\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Luminescence","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002223132500417X","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}
Thermoluminescence properties of Cr, Si, and Mg co-doped Al2O3 ceramics plates under proton beam irradiation
This study evaluates the thermoluminescence (TL) properties of Cr, Si, and Mg co-doped Al2O3 (Al2O3:Cr,Si,Mg) ceramic plates under 200 MeV proton beam irradiation, aiming to assess their potential for high-resolution two-dimensional dosimetry in proton therapy. Spectral measurements revealed a dominant TL emission peak at 693 nm, corresponding to the 2E → 4A2 transition of Cr3+ ions. The glow curves exhibited consistent peak temperature and shape regardless of dose and linear energy transfer (LET), indicating the stability of the trap and recombination centers. The TL response showed excellent linearity with absorbed dose, agreeing within ±1.5 % with ionization chamber measurements, and demonstrated minimal dependence on LET. Furthermore, large-area (200 mm × 200 mm) TL ceramic plates were used to obtain two-dimensional dose distribution maps. The off-axis ratio and percent depth dose distributions measured using TL imaging were in good agreement (within ±1–6 %) with those obtained from standard dosimeters, and the spatial resolution reached 156 μm. These results suggest that Al2O3:Cr,Si,Mg ceramics are suitable for accurate, reusable, and high-resolution proton dosimetry, offering a promising alternative to conventional film- or ionization-based detectors for quality assurance in particle therapy.
期刊介绍:
The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid.
We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.