酸洗乳化酸体系(PEAS):一种很有前途的降低基质酸化阻力的方法

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-08-12 DOI:10.1021/acsomega.5c04098
Ala Al-Dogail, Rahul Gajbhiye*, Abdullah Sultan, Theis Solling, Abdelsalam Alsarkhi and Shirish Patil, 
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引用次数: 0

摘要

基质酸化是一种广泛应用的增产技术,通过溶解地层损伤和形成称为虫孔的导电通道来提高碳酸盐岩储层的油井产能。传统的盐酸(HCl)体系虽然有效,但存在高腐蚀性、过度反应性和热稳定性差等局限性。乳化酸体系(EAS)的出现解决了这些问题,通过引入油相,减缓了酸岩反应,促进了更深的渗透。然而,基于表面活性剂的EAS的高粘度导致泵送阻力增加和能耗增加。本研究介绍了一种皮克林乳化酸体系(PEAS),该体系使用有机粘土(OC)纳米颗粒作为固体颗粒乳化剂来克服这些局限性。由于OC的流变特性和润滑性,PEAS表现出增强的热稳定性、相容性和减阻特性。在25-50°C的温度范围内,与传统的EAS相比,在15%和20% HCl条件下的流动回路对比测试显示,PEAS的摩擦压降显著降低。流后表征包括电导率、稳定性和流变性分析,证实了pea的结构稳健性和现场相关性能。这些发现表明,pea是一种很有前途的环保流体体系,可以改善酸的放置,实现高效的虫孔形成,减少基质酸化作业的能源足迹。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pickering Emulsified Acid Systems (PEAS): A Promising Approach for Reduced Drag in Matrix Acidizing

Matrix acidizing is a widely employed stimulation technique that enhances well productivity in carbonate reservoirs by dissolving formation damage and creating conductive channels known as wormholes. Conventional hydrochloric acid (HCl) systems, while effective, suffer from limitations such as high corrosivity, excessive reactivity, and poor thermal stability. Emulsified acid systems (EAS) have emerged to address these drawbacks by introducing an oil phase that slows the acid–rock reaction and facilitates deeper penetration. However, the high viscosity of surfactant-based EAS leads to increased pumping resistance and energy consumption. This study introduces a Pickering emulsified acid system (PEAS) formulated using organoclay (OC) nanoparticles as solid-particle emulsifiers to overcome these limitations. PEAS exhibits enhanced thermal stability, compatibility, and drag-reducing characteristics due to the rheological behavior and lubricity of OC. Comparative flow-loop tests with 15% and 20% HCl revealed significantly lower frictional pressure drops for PEAS than traditional EAS across a range of temperatures (25–50 °C). Postflow characterization including conductivity, stability, and rheology analyses confirmed the structural robustness and field-relevant performance of PEAS. These findings position PEAS as a promising, environmentally friendly fluid system for improving acid placement, enabling efficient wormhole formation and reducing the energy footprint of matrix acidizing operations.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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