{"title":"利用蓝桉叶提取物绿色合成和表征二氧化钛纳米颗粒:温和热处理的影响","authors":"Abouelkacem Sahraoui , Mouna Hamlaoui , Sara Chikhi , Safia Harrat , Oualid Baghriche , Abdennour Zertal , Sergio Vernuccio","doi":"10.1016/j.mtsust.2025.101193","DOIUrl":null,"url":null,"abstract":"<div><div>Current research efforts are directing considerable attention towards the green synthesis of nanomaterials, such as titanium dioxide nanoparticles (NPs) known for their versatile technological applications. The present work is the first to report on the synthesis of TiO<sub>2</sub> NPs using eucalyptus globulus leaf extract - a gentle, renewable, and non-toxic agent - in conjunction with titanium butoxide as a precursor in a mild thermal treatment. The results comprise four distinct biosynthesised material samples, each obtained by applying different techniques, including single and double-thermal treatments of NPs. Initially characterized by Fourier-transform infrared (FT-IR) and UV–visible spectroscopy, the plant extract plays a dual role in both reduction and stabilisation, leading to a remarkable NPs stability. The phytochemicals components, including phenolic and flavonoid acids, are believed to reduce the Ti<sup>4+</sup> ions, aiding in the creation of related NPs. The successfully synthesised TiO<sub>2</sub> samples were characterised with diffuse reflectance UV–visible spectroscopy (DRS), FT-IR, Raman, X-ray powder diffraction (XRD), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). The findings from these investigations highlighted the pure, uniform structure, and arrangement of all NP samples, exhibiting a spherical morphology and a predominance of the anatase form. The characteristic parameters of the NPs including particle size, band gap energy, crystallinity, and lattice constants, were calculated and compared to those of commercial TiO<sub>2</sub>. The double thermally treated sample exhibits a closer resemblance to commercial TiO<sub>2</sub> compared to both the singal thermally treated sample and the untreated counterpart. This suggests that the proposed mild thermal treatment can serve as an alternative approach for the effective and environmentally friendly preparation of TiO<sub>2</sub> NPs, ensuring good physico-chemical characteristics for a broad spectrum of advanced and sustainable applications.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"31 ","pages":"Article 101193"},"PeriodicalIF":7.9000,"publicationDate":"2025-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Green synthesis and characterization of titanium dioxide nanoparticles using Eucalyptus globulus leaf extract: Impacts of the mild thermal treatment\",\"authors\":\"Abouelkacem Sahraoui , Mouna Hamlaoui , Sara Chikhi , Safia Harrat , Oualid Baghriche , Abdennour Zertal , Sergio Vernuccio\",\"doi\":\"10.1016/j.mtsust.2025.101193\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Current research efforts are directing considerable attention towards the green synthesis of nanomaterials, such as titanium dioxide nanoparticles (NPs) known for their versatile technological applications. The present work is the first to report on the synthesis of TiO<sub>2</sub> NPs using eucalyptus globulus leaf extract - a gentle, renewable, and non-toxic agent - in conjunction with titanium butoxide as a precursor in a mild thermal treatment. The results comprise four distinct biosynthesised material samples, each obtained by applying different techniques, including single and double-thermal treatments of NPs. Initially characterized by Fourier-transform infrared (FT-IR) and UV–visible spectroscopy, the plant extract plays a dual role in both reduction and stabilisation, leading to a remarkable NPs stability. The phytochemicals components, including phenolic and flavonoid acids, are believed to reduce the Ti<sup>4+</sup> ions, aiding in the creation of related NPs. The successfully synthesised TiO<sub>2</sub> samples were characterised with diffuse reflectance UV–visible spectroscopy (DRS), FT-IR, Raman, X-ray powder diffraction (XRD), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). The findings from these investigations highlighted the pure, uniform structure, and arrangement of all NP samples, exhibiting a spherical morphology and a predominance of the anatase form. The characteristic parameters of the NPs including particle size, band gap energy, crystallinity, and lattice constants, were calculated and compared to those of commercial TiO<sub>2</sub>. The double thermally treated sample exhibits a closer resemblance to commercial TiO<sub>2</sub> compared to both the singal thermally treated sample and the untreated counterpart. This suggests that the proposed mild thermal treatment can serve as an alternative approach for the effective and environmentally friendly preparation of TiO<sub>2</sub> NPs, ensuring good physico-chemical characteristics for a broad spectrum of advanced and sustainable applications.</div></div>\",\"PeriodicalId\":18322,\"journal\":{\"name\":\"Materials Today Sustainability\",\"volume\":\"31 \",\"pages\":\"Article 101193\"},\"PeriodicalIF\":7.9000,\"publicationDate\":\"2025-08-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Today Sustainability\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2589234725001228\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Today Sustainability","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589234725001228","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Green synthesis and characterization of titanium dioxide nanoparticles using Eucalyptus globulus leaf extract: Impacts of the mild thermal treatment
Current research efforts are directing considerable attention towards the green synthesis of nanomaterials, such as titanium dioxide nanoparticles (NPs) known for their versatile technological applications. The present work is the first to report on the synthesis of TiO2 NPs using eucalyptus globulus leaf extract - a gentle, renewable, and non-toxic agent - in conjunction with titanium butoxide as a precursor in a mild thermal treatment. The results comprise four distinct biosynthesised material samples, each obtained by applying different techniques, including single and double-thermal treatments of NPs. Initially characterized by Fourier-transform infrared (FT-IR) and UV–visible spectroscopy, the plant extract plays a dual role in both reduction and stabilisation, leading to a remarkable NPs stability. The phytochemicals components, including phenolic and flavonoid acids, are believed to reduce the Ti4+ ions, aiding in the creation of related NPs. The successfully synthesised TiO2 samples were characterised with diffuse reflectance UV–visible spectroscopy (DRS), FT-IR, Raman, X-ray powder diffraction (XRD), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). The findings from these investigations highlighted the pure, uniform structure, and arrangement of all NP samples, exhibiting a spherical morphology and a predominance of the anatase form. The characteristic parameters of the NPs including particle size, band gap energy, crystallinity, and lattice constants, were calculated and compared to those of commercial TiO2. The double thermally treated sample exhibits a closer resemblance to commercial TiO2 compared to both the singal thermally treated sample and the untreated counterpart. This suggests that the proposed mild thermal treatment can serve as an alternative approach for the effective and environmentally friendly preparation of TiO2 NPs, ensuring good physico-chemical characteristics for a broad spectrum of advanced and sustainable applications.
期刊介绍:
Materials Today Sustainability is a multi-disciplinary journal covering all aspects of sustainability through materials science.
With a rapidly increasing population with growing demands, materials science has emerged as a critical discipline toward protecting of the environment and ensuring the long term survival of future generations.