单畴结构对铈取代钴铁氧体纳米粒子光催化脱除染料的影响

IF 4.6 2区物理与天体物理 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Results in Physics Pub Date : 2025-08-19 DOI:10.1016/j.rinp.2025.108405

Dede Djuhana , Candra Kurniawan , Adiana Musadewi , Nurdiyantoro Putra Prasetya , Utari , Suharno , Dong-Hyun Kim , Budi Purnama

{"title":"单畴结构对铈取代钴铁氧体纳米粒子光催化脱除染料的影响","authors":"Dede Djuhana , Candra Kurniawan , Adiana Musadewi , Nurdiyantoro Putra Prasetya , Utari , Suharno , Dong-Hyun Kim , Budi Purnama","doi":"10.1016/j.rinp.2025.108405","DOIUrl":null,"url":null,"abstract":"<div><div>This paper discusses the impact of single domain realization on the performance of dye removal-photocatalyst of Congo Red. Cerium-substituted cobalt ferrite (CoCe0.1Fe1.9O4) nanoparticles preparing coprecipitation-route with varying annealing temperatures were used in this experiment. The XRD characterization and Rietveld-fullprof analysis showed that the diffraction pattern was in accordance with ICDD no. ICDD 22–1086 showed a face-centered cubic (fcc) structure with a space group of Fd-3 m, which is the pristine crystalline structure of cobalt ferrite. Calculation of the crystallite size D in hkl (311) orientation using the Scherer equation shows that increasing the annealing temperature promotes a larger of the D. The FTIR results show the presence of two typical absorption peaks within the range of v1 ∼ 400/cm and v2 ∼ 600/cm which indicates the absorption of metal oxide belonging to spinel cobalt ferrite. VSM results show that the magnetic properties are modified by annealing temperature. The largest coercive field Hc = 3.62 kOe for the non-annealed (NA) sample indicated the presence of a single domain configuration. TEM results show the presence of fine nanoclusters for the NA sample and disappear after the annealing process, which is indicated to support the presence of a single domain configuration. Micromagnetic simulations were also performed to evaluate the effect of domain configuration (single or multi domain) on the coercive field. Finally, the NA sample presented the highest dye removal performance of 97.47 %, which suggested the contribution of single domain realization in the photocatalytic process.</div></div>","PeriodicalId":21042,"journal":{"name":"Results in Physics","volume":"76 ","pages":"Article 108405"},"PeriodicalIF":4.6000,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Impact of single domain configuration on photocatalytic dye removal in cerium-substituted cobalt ferrite nanoparticles\",\"authors\":\"Dede Djuhana , Candra Kurniawan , Adiana Musadewi , Nurdiyantoro Putra Prasetya , Utari , Suharno , Dong-Hyun Kim , Budi Purnama\",\"doi\":\"10.1016/j.rinp.2025.108405\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This paper discusses the impact of single domain realization on the performance of dye removal-photocatalyst of Congo Red. Cerium-substituted cobalt ferrite (CoCe0.1Fe1.9O4) nanoparticles preparing coprecipitation-route with varying annealing temperatures were used in this experiment. The XRD characterization and Rietveld-fullprof analysis showed that the diffraction pattern was in accordance with ICDD no. ICDD 22–1086 showed a face-centered cubic (fcc) structure with a space group of Fd-3 m, which is the pristine crystalline structure of cobalt ferrite. Calculation of the crystallite size D in hkl (311) orientation using the Scherer equation shows that increasing the annealing temperature promotes a larger of the D. The FTIR results show the presence of two typical absorption peaks within the range of v1 ∼ 400/cm and v2 ∼ 600/cm which indicates the absorption of metal oxide belonging to spinel cobalt ferrite. VSM results show that the magnetic properties are modified by annealing temperature. The largest coercive field Hc = 3.62 kOe for the non-annealed (NA) sample indicated the presence of a single domain configuration. TEM results show the presence of fine nanoclusters for the NA sample and disappear after the annealing process, which is indicated to support the presence of a single domain configuration. Micromagnetic simulations were also performed to evaluate the effect of domain configuration (single or multi domain) on the coercive field. Finally, the NA sample presented the highest dye removal performance of 97.47 %, which suggested the contribution of single domain realization in the photocatalytic process.</div></div>\",\"PeriodicalId\":21042,\"journal\":{\"name\":\"Results in Physics\",\"volume\":\"76 \",\"pages\":\"Article 108405\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Results in Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2211379725002992\",\"RegionNum\":2,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Results in Physics","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2211379725002992","RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

讨论了单畴实现对刚果红脱色光催化剂性能的影响。采用不同退火温度的铈取代钴铁氧体（coce0.1 fe1.90 o4）纳米颗粒制备共沉淀法。XRD表征和Rietveld-fullprof分析表明，该材料的衍射图符合ICDD no。ICDD 22-1086为面心立方（fcc）结构，空间群为Fd-3 m，为钴铁氧体的原始晶体结构。利用Scherer方程计算hkl（311）取向的晶粒尺寸D，结果表明，退火温度的升高促进了晶粒尺寸D的增大。FTIR结果表明，在v1 ~ 400/cm和v2 ~ 600/cm范围内存在两个典型的吸收峰，表明尖晶石钴铁氧体金属氧化物的吸收。VSM结果表明，退火温度改变了材料的磁性能。未退火（NA）样品的最大矫顽力场Hc = 3.62 kOe，表明存在单畴构型。TEM结果表明，NA样品中存在细小的纳米团簇，退火后纳米团簇消失，这表明NA样品中存在单畴结构。微磁模拟还评估了畴结构（单畴或多畴）对矫顽力场的影响。最后，NA样品的染料去除率最高，达到97.47%，表明单畴实现在光催化过程中的贡献。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Impact of single domain configuration on photocatalytic dye removal in cerium-substituted cobalt ferrite nanoparticles

This paper discusses the impact of single domain realization on the performance of dye removal-photocatalyst of Congo Red. Cerium-substituted cobalt ferrite (CoCe_0.1Fe_1.9O₄) nanoparticles preparing coprecipitation-route with varying annealing temperatures were used in this experiment. The XRD characterization and Rietveld-fullprof analysis showed that the diffraction pattern was in accordance with ICDD no. ICDD 22–1086 showed a face-centered cubic (fcc) structure with a space group of Fd-3 m, which is the pristine crystalline structure of cobalt ferrite. Calculation of the crystallite size D in hkl (311) orientation using the Scherer equation shows that increasing the annealing temperature promotes a larger of the D. The FTIR results show the presence of two typical absorption peaks within the range of v₁ ∼ 400/cm and v₂ ∼ 600/cm which indicates the absorption of metal oxide belonging to spinel cobalt ferrite. VSM results show that the magnetic properties are modified by annealing temperature. The largest coercive field H_c = 3.62 kOe for the non-annealed (NA) sample indicated the presence of a single domain configuration. TEM results show the presence of fine nanoclusters for the NA sample and disappear after the annealing process, which is indicated to support the presence of a single domain configuration. Micromagnetic simulations were also performed to evaluate the effect of domain configuration (single or multi domain) on the coercive field. Finally, the NA sample presented the highest dye removal performance of 97.47 %, which suggested the contribution of single domain realization in the photocatalytic process.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Results in Physics MATERIALS SCIENCE, MULTIDISCIPLINARYPHYSIC-PHYSICS, MULTIDISCIPLINARY

CiteScore

8.70

自引率

9.40%

发文量

754

审稿时长

50 days

期刊介绍： Results in Physics is an open access journal offering authors the opportunity to publish in all fundamental and interdisciplinary areas of physics, materials science, and applied physics. Papers of a theoretical, computational, and experimental nature are all welcome. Results in Physics accepts papers that are scientifically sound, technically correct and provide valuable new knowledge to the physics community. Topics such as three-dimensional flow and magnetohydrodynamics are not within the scope of Results in Physics. Results in Physics welcomes three types of papers: 1. Full research papers 2. Microarticles: very short papers, no longer than two pages. They may consist of a single, but well-described piece of information, such as: - Data and/or a plot plus a description - Description of a new method or instrumentation - Negative results - Concept or design study 3. Letters to the Editor: Letters discussing a recent article published in Results in Physics are welcome. These are objective, constructive, or educational critiques of papers published in Results in Physics. Accepted letters will be sent to the author of the original paper for a response. Each letter and response is published together. Letters should be received within 8 weeks of the article''s publication. They should not exceed 750 words of text and 10 references.