闪光通讯：杂双金属钯金配合物的Janus二- n杂环碳烯

IF 2.9 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-08-03 DOI:10.1021/acs.organomet.5c00248

Jia Nuo Leung, and , Han Vinh Huynh*,

引用次数: 0

摘要

采用两步法合成了两个钯(II)/金(I)配合物Janus diNHCs{1,2,4-三唑啉-3,5-二吡啶（ditz）}和苯并双苯（咪唑啉-2-二吡啶）（BBI）}。此外，发现使用三甲基铵基团不足以产生稳定的两性离子Janus diNHC配合物。对Janus dinhc的供体能力进行了评价，并与阳离子前体进行了比较。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Flash Communication: Heterobimetallic Palladium–Gold Complexes of Janus Di-N-Heterocyclic Carbenes

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Flash Communication: Heterobimetallic Palladium–Gold Complexes of Janus Di-N-Heterocyclic Carbenes

Two palladium(II)/gold(I) complexes of the Janus diNHCs {1,2,4-triazolidin-3,5-diylidene (ditz) and benzobis(imidazolin-2-ylidene) (BBI)} were synthesized in a two-step approach. In addition, the use of a trimethylammonium group was found to be insufficient for the generation of a stable zwitterionic Janus diNHC complex. The donating abilities of the Janus diNHCs were evaluated and compared against their cationic intermediate precursors.

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.