“电极-载流子”预压缩理论

IF 7.5 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY
Zhongyu Wan, Guo-Hua Zhong, Ruiqin Zhang, Hai-Qing Lin
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引用次数: 0

摘要

室温超导主要是在高压氢化物中观察到的,但面临着一个巨大的障碍:这些材料在压力释放时容易分解并丧失其超导能力。因此,在环境条件下稳定室温超导性已成为固体物理学中一个迫切关注的问题。电子化合物是一种独特的化合物,由于其晶格间隙内聚集了高能多余电子而具有特殊的性质。我们的理论概述了通过在电极材料的间隙中战略性地插入氢来实现环境超导性的总体蓝图。这种巧妙的方法利用准分子H2来隔离高能电子,从而在费米能级上产生大量的电子态密度,并培养强大的电子-声子耦合。我们在碱金属电子领域实施了这一策略,通过载流子掺杂效应微调其稳定性,基于对压力诱导化学键的严格量子化学分析。结果表明,KH6化合物在10 GPa下表现出222 K的超导体转变温度,优于先前报道的高压超导体H3S (155 GPa下203 K)和LaH10 (170 GPa下250 K)。此外,空穴掺杂的NaH6化合物在环境压力下表现出超导性,Tc值达到167 K,超过了之前的记录保持者HgBa2Ca2Cu3O8的134 K。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The theory of “electride-carrier” precompression

Room-temperature superconductivity is predominantly observed in high-pressure hydrides, but faces a formidable hurdle: the tendency of these materials to decompose and forfeit their superconducting prowess upon pressure release. Consequently, stabilizing room-temperature superconductivity under ambient conditions has emerged as a pressing concern in solid-state physics. Electrides are unique compounds, possessing exceptional properties attributed to the clustering of high-energy excess electrons within the interstices of their lattices. Our theory outlines a general blueprint for achieving ambient superconductivity through the strategic insertion of hydrogen into the interstitial spaces of electride materials. This ingenious approach harnesses quasimolecular H2 to sequester high-energy electrons, resulting in a substantial density of electronic states at the Fermi level and fostering robust electron-phonon coupling. We implemented this strategy within the realm of alkali metal electrides, fine-tuning their stability via carrier doping effects, grounded in rigorous quantum chemical analyses of pressure-induced chemical bonds. As a result, the KH6 compound exhibits an exceptional superconducting transition temperature of 222 K at a modest 10 GPa, outperforming previously reported high-pressure superconductors like H3S (203 K at 155 GPa) and LaH10 (250 K at 170 GPa). Furthermore, the hole-doped NaH6 compound demonstrates superconductivity at ambient pressure with a remarkable Tc of 167 K, surpassing the previous record-holder HgBa2Ca2Cu3O8 with 134 K.

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来源期刊
Science China Physics, Mechanics & Astronomy
Science China Physics, Mechanics & Astronomy PHYSICS, MULTIDISCIPLINARY-
CiteScore
10.30
自引率
6.20%
发文量
4047
审稿时长
3 months
期刊介绍: Science China Physics, Mechanics & Astronomy, an academic journal cosponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China, and published by Science China Press, is committed to publishing high-quality, original results in both basic and applied research. Science China Physics, Mechanics & Astronomy, is published in both print and electronic forms. It is indexed by Science Citation Index. Categories of articles: Reviews summarize representative results and achievements in a particular topic or an area, comment on the current state of research, and advise on the research directions. The author’s own opinion and related discussion is requested. Research papers report on important original results in all areas of physics, mechanics and astronomy. Brief reports present short reports in a timely manner of the latest important results.
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