聚合物稳定胆甾液晶的电控指纹织构和衍射模式

IF 3.8
Kyung Min Lee*, Robert L. Dupont, Steven M. Wolf, Nicholas P. Godman, Timothy J. Bunning and Michael E. McConney*, 
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引用次数: 0

摘要

手性向列液晶中形成的指纹纹理可以与光相互作用,产生复杂的、随机的传输或反射图案,可以用于光学器件、防伪措施、可调衍射光学和微流体器件等多种应用。本文报道了利用聚合物稳定胆甾液晶(FP-PSCLCs)制备的电控指纹纹理及其相关衍射图案的制备和性能。每次施加和去除电场时,FP-CLCs表现出不同的指纹纹理,而用少量聚合物稳定的FP-PSCLCs在施加和去除低交流电压时表现出相同的指纹纹理。对FP- psclcs施加足够高的交流电压可以诱导离子电荷的随机运动(即流体动力学不稳定性),从而导致不同的FP结构。对FP- psclc样品施加机械力也可以诱导出独立于电诱导FP织构的临时织构。在没有外界刺激的情况下,观察到初始FP织构和变形的临时FP织构在几个月内保持不变,由于FP- psclc的聚合物网络的记忆效应,表现出双稳态行为。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Electrically Controllable Fingerprint Texture and Diffraction Pattern of Polymer-Stabilized Cholesteric Liquid Crystals

Electrically Controllable Fingerprint Texture and Diffraction Pattern of Polymer-Stabilized Cholesteric Liquid Crystals

Fingerprint textures formed in chiral nematic liquid crystals can interact with light to generate complex, random transmitted or reflective patterns and can be used in several applications, optical devices, anticounterfeiting measures, tunable diffractive optics, and microfluidic devices. Here, we report the fabrication and properties of electrically controllable fingerprint textures and their associated diffraction patterns using polymer-stabilized cholesteric liquid crystals (FP-PSCLCs). While FP-CLCs exhibit different fingerprint textures each time an electric field is applied and removed, FP-PSCLCs stabilized with a small amount of polymer show the same fingerprint texture upon application and removal of a low AC voltage. Applying a sufficiently high AC voltage to FP-PSCLCs can induce random movement of ionic charges (i.e., hydrodynamic instability), leading to a different FP texture. The application of mechanical force to the FP-PSCLC sample can also induce a temporary texture independent of the electrically induced FP texture. In the absence of external stimulation, both the initial FP texture and the deformed temporary FP texture were observed to remain unchanged for several months, demonstrating a bistable behavior due to the memory effect of the polymer network of the FP-PSCLC.

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来源期刊
ACS Applied Optical Materials
ACS Applied Optical Materials 材料科学-光学材料-
CiteScore
1.10
自引率
0.00%
发文量
0
期刊介绍: ACS Applied Optical Materials is an international and interdisciplinary forum to publish original experimental and theoretical including simulation and modeling research in optical materials complementing the ACS Applied Materials portfolio. With a focus on innovative applications ACS Applied Optical Materials also complements and expands the scope of existing ACS publications that focus on fundamental aspects of the interaction between light and matter in materials science including ACS Photonics Macromolecules Journal of Physical Chemistry C ACS Nano and Nano Letters.The scope of ACS Applied Optical Materials includes high quality research of an applied nature that integrates knowledge in materials science chemistry physics optical science and engineering.
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