Kyung Min Lee*, Robert L. Dupont, Steven M. Wolf, Nicholas P. Godman, Timothy J. Bunning and Michael E. McConney*,
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Electrically Controllable Fingerprint Texture and Diffraction Pattern of Polymer-Stabilized Cholesteric Liquid Crystals
Fingerprint textures formed in chiral nematic liquid crystals can interact with light to generate complex, random transmitted or reflective patterns and can be used in several applications, optical devices, anticounterfeiting measures, tunable diffractive optics, and microfluidic devices. Here, we report the fabrication and properties of electrically controllable fingerprint textures and their associated diffraction patterns using polymer-stabilized cholesteric liquid crystals (FP-PSCLCs). While FP-CLCs exhibit different fingerprint textures each time an electric field is applied and removed, FP-PSCLCs stabilized with a small amount of polymer show the same fingerprint texture upon application and removal of a low AC voltage. Applying a sufficiently high AC voltage to FP-PSCLCs can induce random movement of ionic charges (i.e., hydrodynamic instability), leading to a different FP texture. The application of mechanical force to the FP-PSCLC sample can also induce a temporary texture independent of the electrically induced FP texture. In the absence of external stimulation, both the initial FP texture and the deformed temporary FP texture were observed to remain unchanged for several months, demonstrating a bistable behavior due to the memory effect of the polymer network of the FP-PSCLC.
期刊介绍:
ACS Applied Optical Materials is an international and interdisciplinary forum to publish original experimental and theoretical including simulation and modeling research in optical materials complementing the ACS Applied Materials portfolio. With a focus on innovative applications ACS Applied Optical Materials also complements and expands the scope of existing ACS publications that focus on fundamental aspects of the interaction between light and matter in materials science including ACS Photonics Macromolecules Journal of Physical Chemistry C ACS Nano and Nano Letters.The scope of ACS Applied Optical Materials includes high quality research of an applied nature that integrates knowledge in materials science chemistry physics optical science and engineering.