{"title":"内页封面：精确限制金属-有机框架中苯基环的旋转，用于沙林的超灵敏和特异比例荧光检测","authors":"Cong Lyu, Chuanfang Zhao, Meimei Wang, Jiawen Li, Zhenzhen Cai, Xincun Dou, Baiyi Zu","doi":"10.1002/agt2.70138","DOIUrl":null,"url":null,"abstract":"<p>A goal-oriented MOF design strategy is proposed to realize the ultra-sensitive and specific detection of sarin through the rotation restricted emission mechanism. The hydrogen bonding and hydrophobic interaction between Eu-MOF and sarin efficiently lead to a dramatic change in molecular configuration, significantly enhancing the fluorescence intensity and realizing the ratiometric detection of sarin. This strategy would provide new insights for functional sensing material exploration (e70053).\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":72127,"journal":{"name":"Aggregate (Hoboken, N.J.)","volume":"6 8","pages":""},"PeriodicalIF":13.7000,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/agt2.70138","citationCount":"0","resultStr":"{\"title\":\"Inside Front Cover: Exactly Restricting the Phenyl Ring Rotation in Metal-Organic Framework for Ultra-Sensitive and Specific Ratiometric Fluorescent Sensing of Sarin\",\"authors\":\"Cong Lyu, Chuanfang Zhao, Meimei Wang, Jiawen Li, Zhenzhen Cai, Xincun Dou, Baiyi Zu\",\"doi\":\"10.1002/agt2.70138\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A goal-oriented MOF design strategy is proposed to realize the ultra-sensitive and specific detection of sarin through the rotation restricted emission mechanism. The hydrogen bonding and hydrophobic interaction between Eu-MOF and sarin efficiently lead to a dramatic change in molecular configuration, significantly enhancing the fluorescence intensity and realizing the ratiometric detection of sarin. This strategy would provide new insights for functional sensing material exploration (e70053).\\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":72127,\"journal\":{\"name\":\"Aggregate (Hoboken, N.J.)\",\"volume\":\"6 8\",\"pages\":\"\"},\"PeriodicalIF\":13.7000,\"publicationDate\":\"2025-08-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/agt2.70138\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Aggregate (Hoboken, N.J.)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/agt2.70138\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Aggregate (Hoboken, N.J.)","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/agt2.70138","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Inside Front Cover: Exactly Restricting the Phenyl Ring Rotation in Metal-Organic Framework for Ultra-Sensitive and Specific Ratiometric Fluorescent Sensing of Sarin
A goal-oriented MOF design strategy is proposed to realize the ultra-sensitive and specific detection of sarin through the rotation restricted emission mechanism. The hydrogen bonding and hydrophobic interaction between Eu-MOF and sarin efficiently lead to a dramatic change in molecular configuration, significantly enhancing the fluorescence intensity and realizing the ratiometric detection of sarin. This strategy would provide new insights for functional sensing material exploration (e70053).
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
