通过调整聚丙烯含量和填充密度改变3D打印聚烯烃弹性体/聚丙烯共混结构的压缩特性

IF 2.8 3区 化学 Q3 POLYMER SCIENCE
Yong Liu, Jianwei Wei, Qi Chen, Yunzhong Dai
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引用次数: 0

摘要

在这项研究中,制备了具有不同PP浓度的3D打印聚烯烃弹性体(POE)/聚丙烯(PP)共混物,并对其压缩和吸能应用进行了表征。为了实现这一目标,分别制备了PP浓度为10%、30%和50%的POE/PP共混物。利用熔融颗粒制造(FGF)打印机打印了具有蜂窝图案和两种不同填充密度的立方能量吸收样品,研究了填充密度和共混物组成对压缩性能的影响。利用扫描电子显微镜(SEM)、动态机械热分析(DMTA)、拉伸和压缩测试对共混物进行分析,研究其可打印性、形态、热学和机械性能。扫描电镜结果表明,样品具有明显的两相结构,呈海岛型,在50% PP浓度的共混物中变为共连续相,互溶性较差。此外,在共混物中观察到良好的印刷性,无缺陷。DMTA表明,随着PP含量的增加,样品的熔点升高,而混相降低。拉伸试验显示出很大的弹性,所有样品的应变值从1204到1646%不等。拉伸杨氏模量、极限拉伸强度和韧性随PP含量的增加而增加,而伸长率则随PP含量的增加而降低。压缩试验表明,PP含量的增加提高了材料的吸能和压缩性能。充填密度越高,致密化越早,吸能和压缩性能越好。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Modification of compressive characteristics in 3D printed polyolefin elastomers/polypropylene blend structures through polypropylene content and infill density adjustment

In this research, 3D printed Polyolefin Elastomers (POE)/Polypropylene (PP) blends with varying PP concentrations were prepared and characterized for compressive and energy absorption applications. To achieve this, POE/PP blends with 10%, 30%, and 50% PP concentrations were created. Cubic energy absorption samples with a honeycomb pattern and two different infill densities were printed using a Fused Granule Fabrication (FGF) printer to examine the influence of infill density and blend composition on compressive properties. The blends were analyzed using Scanning Electron Microscopy (SEM), Dynamic Mechanical Thermal Analysis (DMTA), tensile, and compression tests to study their printability, morphological, thermal, and mechanical properties. SEM results showed that the samples had two distinct phases with a sea-island pattern, which changed to co-continuous and less miscible in the 50% PP concentration blend. Additionally, good printability without defects was observed in the blends. DMTA demonstrated that the melting point of the samples increased with higher PP content, while miscibility decreased. Tensile tests revealed great elasticity, with strain values ranging from 1204 to 1646% for all samples. Furthermore, tensile Young’s modulus, Ultimate Tensile Strength (UTS), and toughness increased with increasing PP content, while elongation decreased. Compression tests indicated that increasing PP content enhanced energy absorption and compressive properties. Moreover, higher infill density led to earlier densification and improved energy absorption and compressive properties.

Graphical abstract

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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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