二硫化钼对聚酰胺-6物理、机械和工艺性能的影响

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED
D. N. Karpov, O. O. Nikolaev
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引用次数: 0

摘要

本文考虑了以二硫化钼为基础的添加剂改性聚酰胺-6的特点,大大扩展了其应用范围。然而,聚合物改性不仅改变了目标的性质,而且可能影响其他特性,有时是负面的。复合材料开发人员的主要任务是选择一种平衡的成分来达到预期的目标——获得一种抗摩擦、耐磨的复合材料。本研究基于过去5-7年(16个来源,包括交叉引用)的文献综述,简要分析了二硫化钼对聚合物复合材料整体性能的影响。研究了二硫化钼对聚酰胺-6物理力学性能和工艺性能的影响。此外,还讨论了制造聚合物复合材料的各种方法。最初,研究了相当广泛的添加剂浓度范围,并确定了其合理有效使用的一小部分。在研究的第二阶段,改变了聚合物改性的方法。采用了以大规模生产为重点的改性方案。根据初步研究的结果,分析了这方面的国际经验。在使用改性二硫化钼样品制备纳米复合材料时,也观察到类似的效果,但聚合物材料的一般行为和所获得的特性不同。该研究强调了通过在双螺杆挤出机中直接混合组分来生产mos2基复合材料的挑战,并提出了一种使用精矿生产的方法。研究了聚合物组分在极限变形区域的行为,揭示了抗拉强度的增加和破坏机制的变化,并提出了关于其性质的假设。有人指出,在聚酰胺-6复合材料形成高取向状态的背景下,最终变形区可能是一个进一步研究的主题。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The Effect of Molybdenum Disulfide on the Physical, Mechanical, and Technological Properties of Polyamide-6

The Effect of Molybdenum Disulfide on the Physical, Mechanical, and Technological Properties of Polyamide-6

The Effect of Molybdenum Disulfide on the Physical, Mechanical, and Technological Properties of Polyamide-6

The article considers the features of polyamide-6 modification with additives based on molybdenum disulfide, which significantly expands the scope of its application. However, polymer modification not only alters the target properties but may also affect other characteristics, sometimes negatively. The main task for developers of composite material is to select a balanced composition to achieve the desired goal—obtaining an antifriction, wear-resistant composite. The study presents a brief analysis of the effect of molybdenum disulfide on the overall properties of the polymer composites based on a literature review of publications from the last 5–7 years (16 sources, including cross-references). The effect of molybdenum disulfide on the physico-mechanical and technological properties of polyamide-6 has been investigated. In addition, various approaches to the creation of polymer composites are discussed. Initially, a fairly wide range of additive concentrations was studied and a narrow sector of its rational and effective use was determined. In the second stage of the study, the approach to polymer modification was changed. A modification scheme focused on large-scale production of polymer products was used. Based on the results of preliminary studies, international experience in this area was analyzed. It was noted that similar effects were observed when creating nanocomposites using modified molybdenum disulfide samples, but the general behavior of the polymer material and the achieved characteristics are different. The study highlights the challenges in producing MoS2-based composites via direct mixing of components in a twin-screw extruder and proposes a method for their production using concentrates. The behavior of polymer compositions in the areas of ultimate deformations were investigated, revealing an increase in tensile strength and a change in the destruction mechanisim with hypotheses proposed regarding their nature. It was noted that the zone of ultimate deformations could be a subject of further research and is of interest in the context of forming highly oriented states in polyamide-6 composites.

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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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