{"title":"部分Ti和Nb取代Ta0.33V0.67合金的氢化物相","authors":"S. A. Lushnikov, T. V. Filippova, S. V. Mitrokhin","doi":"10.1134/S0036023625600558","DOIUrl":null,"url":null,"abstract":"<p>The products of the reaction between hydrogen and the body-centered cubic modification of the Ta<sub>0.33</sub>V<sub>0.67</sub> alloy with partial substitution of its components by titanium and niobium were studied by X-ray powder diffraction. It was found that during hydrogenation of such alloys, hydride samples with different phase compositions and different lattice types are formed. Varying the amount of titanium and niobium in the Ta<sub>0.33</sub>V<sub>0.67</sub> alloy affects the transition of the crystal lattice from body-centered cubic to face-centered. Hydrogenation of the Ta<sub>0.33</sub>V<sub>0.67</sub> alloy with partial substitution of components by titanium and niobium leads to the formation of stable hydrides.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 6","pages":"780 - 790"},"PeriodicalIF":1.5000,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydride Phases Based on Ta0.33V0.67 Alloy with Components Partially Replaced by Ti and Nb\",\"authors\":\"S. A. Lushnikov, T. V. Filippova, S. V. Mitrokhin\",\"doi\":\"10.1134/S0036023625600558\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The products of the reaction between hydrogen and the body-centered cubic modification of the Ta<sub>0.33</sub>V<sub>0.67</sub> alloy with partial substitution of its components by titanium and niobium were studied by X-ray powder diffraction. It was found that during hydrogenation of such alloys, hydride samples with different phase compositions and different lattice types are formed. Varying the amount of titanium and niobium in the Ta<sub>0.33</sub>V<sub>0.67</sub> alloy affects the transition of the crystal lattice from body-centered cubic to face-centered. Hydrogenation of the Ta<sub>0.33</sub>V<sub>0.67</sub> alloy with partial substitution of components by titanium and niobium leads to the formation of stable hydrides.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"70 6\",\"pages\":\"780 - 790\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023625600558\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023625600558","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Hydride Phases Based on Ta0.33V0.67 Alloy with Components Partially Replaced by Ti and Nb
The products of the reaction between hydrogen and the body-centered cubic modification of the Ta0.33V0.67 alloy with partial substitution of its components by titanium and niobium were studied by X-ray powder diffraction. It was found that during hydrogenation of such alloys, hydride samples with different phase compositions and different lattice types are formed. Varying the amount of titanium and niobium in the Ta0.33V0.67 alloy affects the transition of the crystal lattice from body-centered cubic to face-centered. Hydrogenation of the Ta0.33V0.67 alloy with partial substitution of components by titanium and niobium leads to the formation of stable hydrides.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.