Yan Zhang , Juan Liang , Peng Jing , Kaiwen Chi , Junchao Yu , Xiaozheng Jia , Xuan Xu , Baocang Liu , Tao Bai , Jun Zhang
{"title":"LaOF对铈基磨料化学机械抛光性能的促进作用","authors":"Yan Zhang , Juan Liang , Peng Jing , Kaiwen Chi , Junchao Yu , Xiaozheng Jia , Xuan Xu , Baocang Liu , Tao Bai , Jun Zhang","doi":"10.1016/j.jre.2024.10.001","DOIUrl":null,"url":null,"abstract":"<div><div>CeO<sub>2</sub><span> is increasingly recognized as a viable polishing abrasive for SiO</span><sub>2</sub><span>-based substrates, such as K9 glass, leveraging its intrinsic chemical mechanical polishing property. Although LaOF can improve the performance of CeO</span><sub>2</sub> abrasive, the specific mechanism underlying this enhancement remains elusive. Herein, LaOF-CeO<sub>2</sub> composite abrasive was prepared by co-precipitation method, aiming to elaborate on the influence of LaOF on the abrasive's polishing efficiency. It is found that the integration of LaOF results in the formation of LaOF-CeO<sub>2</sub> composite characterized by a remarkably reduced primary particle size of approximately 41 nm, which primarily accounts for the improvement in polishing performance. Furthermore, the increasement in Ce<sup>3+</sup><span> content and the Zeta potential<span> both contribute to the superior function of the composite abrasive. Notably, the synergistic effect<span> of these parameters is manifested in an elevated material removal rate reaching 1091.197 nm/min, coupled with a minimized surface roughness of as low as 0.546 nm when applied to K9 glass surface. The findings of this work offer novel insights into the role of LaOF in facilitating the performance of Ce-based abrasives, potentially influencing future advancements in the field of precision surface processing.</span></span></span></div></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"43 9","pages":"Pages 2005-2015"},"PeriodicalIF":7.2000,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Promoting effect of LaOF on chemical mechanical polishing performance of cerium-based abrasives\",\"authors\":\"Yan Zhang , Juan Liang , Peng Jing , Kaiwen Chi , Junchao Yu , Xiaozheng Jia , Xuan Xu , Baocang Liu , Tao Bai , Jun Zhang\",\"doi\":\"10.1016/j.jre.2024.10.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>CeO<sub>2</sub><span> is increasingly recognized as a viable polishing abrasive for SiO</span><sub>2</sub><span>-based substrates, such as K9 glass, leveraging its intrinsic chemical mechanical polishing property. Although LaOF can improve the performance of CeO</span><sub>2</sub> abrasive, the specific mechanism underlying this enhancement remains elusive. Herein, LaOF-CeO<sub>2</sub> composite abrasive was prepared by co-precipitation method, aiming to elaborate on the influence of LaOF on the abrasive's polishing efficiency. It is found that the integration of LaOF results in the formation of LaOF-CeO<sub>2</sub> composite characterized by a remarkably reduced primary particle size of approximately 41 nm, which primarily accounts for the improvement in polishing performance. Furthermore, the increasement in Ce<sup>3+</sup><span> content and the Zeta potential<span> both contribute to the superior function of the composite abrasive. Notably, the synergistic effect<span> of these parameters is manifested in an elevated material removal rate reaching 1091.197 nm/min, coupled with a minimized surface roughness of as low as 0.546 nm when applied to K9 glass surface. The findings of this work offer novel insights into the role of LaOF in facilitating the performance of Ce-based abrasives, potentially influencing future advancements in the field of precision surface processing.</span></span></span></div></div>\",\"PeriodicalId\":16940,\"journal\":{\"name\":\"Journal of Rare Earths\",\"volume\":\"43 9\",\"pages\":\"Pages 2005-2015\"},\"PeriodicalIF\":7.2000,\"publicationDate\":\"2024-10-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Rare Earths\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S100207212400351X\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Rare Earths","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S100207212400351X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Promoting effect of LaOF on chemical mechanical polishing performance of cerium-based abrasives
CeO2 is increasingly recognized as a viable polishing abrasive for SiO2-based substrates, such as K9 glass, leveraging its intrinsic chemical mechanical polishing property. Although LaOF can improve the performance of CeO2 abrasive, the specific mechanism underlying this enhancement remains elusive. Herein, LaOF-CeO2 composite abrasive was prepared by co-precipitation method, aiming to elaborate on the influence of LaOF on the abrasive's polishing efficiency. It is found that the integration of LaOF results in the formation of LaOF-CeO2 composite characterized by a remarkably reduced primary particle size of approximately 41 nm, which primarily accounts for the improvement in polishing performance. Furthermore, the increasement in Ce3+ content and the Zeta potential both contribute to the superior function of the composite abrasive. Notably, the synergistic effect of these parameters is manifested in an elevated material removal rate reaching 1091.197 nm/min, coupled with a minimized surface roughness of as low as 0.546 nm when applied to K9 glass surface. The findings of this work offer novel insights into the role of LaOF in facilitating the performance of Ce-based abrasives, potentially influencing future advancements in the field of precision surface processing.
期刊介绍:
The Journal of Rare Earths reports studies on the 17 rare earth elements. It is a unique English-language learned journal that publishes works on various aspects of basic theory and applied science in the field of rare earths (RE). The journal accepts original high-quality original research papers and review articles with inventive content, and complete experimental data. It represents high academic standards and new progress in the RE field. Due to the advantage of abundant RE resources of China, the research on RE develops very actively, and papers on the latest progress in this field emerge every year. It is not only an important resource in which technicians publish and obtain their latest research results on RE, but also an important way of reflecting the updated progress in RE research field.
The Journal of Rare Earths covers all research and application of RE rare earths including spectroscopy, luminescence and phosphors, rare earth catalysis, magnetism and magnetic materials, advanced rare earth materials, RE chemistry & hydrometallurgy, RE metallography & pyrometallurgy, RE new materials, RE solid state physics & solid state chemistry, rare earth applications, RE analysis & test, RE geology & ore dressing, etc.