水葫芦作为生物纤维素聚合物的原料:军事可持续性的潜在能量材料和生命周期评估

IF 8.5 1区 化学 Q1 BIOCHEMISTRY & MOLECULAR BIOLOGY
Achmad Fadjar Maulana Firdaus , Bayu Hanif Priambodo , Hamzah Fansuri , Hosta Ardhyananta , Alief Wikarta , Rendra Panca Anugraha , Maria Anityasari , Holilah Holilah , Liyana Labiba Zulfa , Komang Nickita Sari , Ninik Safrida , Widyastuti Widyastuti
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引用次数: 0

摘要

作为军用级推进剂的重要组成部分,硝化纤维(NC)仍然主要从印度尼西亚进口,因为国内优质纤维素来源(如棉絮)的供应非常有限。特别是在导弹及其技术控制制度(MTCR)等国际体系下,这种依赖造成了重大的战略和财政弱点。作为回应,本研究着眼于利用在印度尼西亚拉瓦潘宁常见的快速生长、极具入侵性的水生植物水葫芦(Eichhornia crassipes)作为NC制造的可持续和当地丰富的替代品的可行性。采用有机溶剂预处理、碱水解、漂白等环境可接受的提取方法,可有效地获得高纯度α-纤维素(93.20±0.18%)。合成NC的氮浓度为13.43%,热稳定性好,溶解度高(98.19%),具有军用级的性能。由于对人类健康(355.28)、生态系统(30.45)和资源消耗(1.26)有显著影响,使用ReCiPe 2016H终点方法进行的生命周期评估(LCA)发现,稳定阶段是环境最密集的步骤。这些结果突出了重点流程优化的必要性,以提高总体可持续性水平。最后,本研究显示了水葫芦作为国内数控制造的一种合适的、环保的原料可能带来的环境和战略效益。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Water hyacinth as feedstock for bio-cellulose polymers: Potential energetic materials and life cycle assessment for military sustainability
A vital component in military-grade propellants, nitrocellulose (NC) is still mostly imported from Indonesia as domestic availability of premium cellulose sources like cotton linters is so limited. Especially under international systems like the Missile Technology Control Regime (MTCR), this reliance creates major strategic and financial weaknesses. In response, this study looks at the viability of using fast-growing, extremely invasive aquatic plant common in Rawa Pening, Indonesia, water hyacinth (Eichhornia crassipes), as a sustainable and locally plentiful alternative for NC manufacturing. High-purity α-cellulose (93.20 ± 0.18 %) was effectively achieved by means of an environmentally acceptable extraction method including organosolv pretreatment, alkaline hydrolysis, and bleaching. With a nitrogen concentration of 13.43 %, great thermal stability, and high solubility (98.19 %), the synthetic NC displayed military-grade qualities. With significant effects on Human Health (355.28), Ecosystems (30.45), and Resource Depletion (1.26), a Life Cycle Assessment (LCA) done using the ReCiPe 2016H End-Point approach found the stability phase as the most environmentally intensive step. These results highlight the need of focused process optimization to raise general sustainability level. In the end, this study shows the possible environmental and strategic benefits of water hyacinth as a suitable, eco-friendly feedstock for domestic NC manufacture.
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来源期刊
International Journal of Biological Macromolecules
International Journal of Biological Macromolecules 生物-生化与分子生物学
CiteScore
13.70
自引率
9.80%
发文量
2728
审稿时长
64 days
期刊介绍: The International Journal of Biological Macromolecules is a well-established international journal dedicated to research on the chemical and biological aspects of natural macromolecules. Focusing on proteins, macromolecular carbohydrates, glycoproteins, proteoglycans, lignins, biological poly-acids, and nucleic acids, the journal presents the latest findings in molecular structure, properties, biological activities, interactions, modifications, and functional properties. Papers must offer new and novel insights, encompassing related model systems, structural conformational studies, theoretical developments, and analytical techniques. Each paper is required to primarily focus on at least one named biological macromolecule, reflected in the title, abstract, and text.
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