{"title":"水葫芦作为生物纤维素聚合物的原料:军事可持续性的潜在能量材料和生命周期评估","authors":"Achmad Fadjar Maulana Firdaus , Bayu Hanif Priambodo , Hamzah Fansuri , Hosta Ardhyananta , Alief Wikarta , Rendra Panca Anugraha , Maria Anityasari , Holilah Holilah , Liyana Labiba Zulfa , Komang Nickita Sari , Ninik Safrida , Widyastuti Widyastuti","doi":"10.1016/j.ijbiomac.2025.146923","DOIUrl":null,"url":null,"abstract":"<div><div>A vital component in military-grade propellants, nitrocellulose (NC) is still mostly imported from Indonesia as domestic availability of premium cellulose sources like cotton linters is so limited. Especially under international systems like the Missile Technology Control Regime (MTCR), this reliance creates major strategic and financial weaknesses. In response, this study looks at the viability of using fast-growing, extremely invasive aquatic plant common in Rawa Pening, Indonesia, water hyacinth (<em>Eichhornia crassipes</em>), as a sustainable and locally plentiful alternative for NC manufacturing. High-purity α-cellulose (93.20 ± 0.18 %) was effectively achieved by means of an environmentally acceptable extraction method including organosolv pretreatment, alkaline hydrolysis, and bleaching. With a nitrogen concentration of 13.43 %, great thermal stability, and high solubility (98.19 %), the synthetic NC displayed military-grade qualities. With significant effects on Human Health (355.28), Ecosystems (30.45), and Resource Depletion (1.26), a Life Cycle Assessment (LCA) done using the ReCiPe 2016H End-Point approach found the stability phase as the most environmentally intensive step. These results highlight the need of focused process optimization to raise general sustainability level. In the end, this study shows the possible environmental and strategic benefits of water hyacinth as a suitable, eco-friendly feedstock for domestic NC manufacture.</div></div>","PeriodicalId":333,"journal":{"name":"International Journal of Biological Macromolecules","volume":"322 ","pages":"Article 146923"},"PeriodicalIF":8.5000,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Water hyacinth as feedstock for bio-cellulose polymers: Potential energetic materials and life cycle assessment for military sustainability\",\"authors\":\"Achmad Fadjar Maulana Firdaus , Bayu Hanif Priambodo , Hamzah Fansuri , Hosta Ardhyananta , Alief Wikarta , Rendra Panca Anugraha , Maria Anityasari , Holilah Holilah , Liyana Labiba Zulfa , Komang Nickita Sari , Ninik Safrida , Widyastuti Widyastuti\",\"doi\":\"10.1016/j.ijbiomac.2025.146923\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A vital component in military-grade propellants, nitrocellulose (NC) is still mostly imported from Indonesia as domestic availability of premium cellulose sources like cotton linters is so limited. Especially under international systems like the Missile Technology Control Regime (MTCR), this reliance creates major strategic and financial weaknesses. In response, this study looks at the viability of using fast-growing, extremely invasive aquatic plant common in Rawa Pening, Indonesia, water hyacinth (<em>Eichhornia crassipes</em>), as a sustainable and locally plentiful alternative for NC manufacturing. High-purity α-cellulose (93.20 ± 0.18 %) was effectively achieved by means of an environmentally acceptable extraction method including organosolv pretreatment, alkaline hydrolysis, and bleaching. With a nitrogen concentration of 13.43 %, great thermal stability, and high solubility (98.19 %), the synthetic NC displayed military-grade qualities. With significant effects on Human Health (355.28), Ecosystems (30.45), and Resource Depletion (1.26), a Life Cycle Assessment (LCA) done using the ReCiPe 2016H End-Point approach found the stability phase as the most environmentally intensive step. These results highlight the need of focused process optimization to raise general sustainability level. In the end, this study shows the possible environmental and strategic benefits of water hyacinth as a suitable, eco-friendly feedstock for domestic NC manufacture.</div></div>\",\"PeriodicalId\":333,\"journal\":{\"name\":\"International Journal of Biological Macromolecules\",\"volume\":\"322 \",\"pages\":\"Article 146923\"},\"PeriodicalIF\":8.5000,\"publicationDate\":\"2025-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Biological Macromolecules\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S014181302507480X\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"BIOCHEMISTRY & MOLECULAR BIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Biological Macromolecules","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S014181302507480X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}
Water hyacinth as feedstock for bio-cellulose polymers: Potential energetic materials and life cycle assessment for military sustainability
A vital component in military-grade propellants, nitrocellulose (NC) is still mostly imported from Indonesia as domestic availability of premium cellulose sources like cotton linters is so limited. Especially under international systems like the Missile Technology Control Regime (MTCR), this reliance creates major strategic and financial weaknesses. In response, this study looks at the viability of using fast-growing, extremely invasive aquatic plant common in Rawa Pening, Indonesia, water hyacinth (Eichhornia crassipes), as a sustainable and locally plentiful alternative for NC manufacturing. High-purity α-cellulose (93.20 ± 0.18 %) was effectively achieved by means of an environmentally acceptable extraction method including organosolv pretreatment, alkaline hydrolysis, and bleaching. With a nitrogen concentration of 13.43 %, great thermal stability, and high solubility (98.19 %), the synthetic NC displayed military-grade qualities. With significant effects on Human Health (355.28), Ecosystems (30.45), and Resource Depletion (1.26), a Life Cycle Assessment (LCA) done using the ReCiPe 2016H End-Point approach found the stability phase as the most environmentally intensive step. These results highlight the need of focused process optimization to raise general sustainability level. In the end, this study shows the possible environmental and strategic benefits of water hyacinth as a suitable, eco-friendly feedstock for domestic NC manufacture.
期刊介绍:
The International Journal of Biological Macromolecules is a well-established international journal dedicated to research on the chemical and biological aspects of natural macromolecules. Focusing on proteins, macromolecular carbohydrates, glycoproteins, proteoglycans, lignins, biological poly-acids, and nucleic acids, the journal presents the latest findings in molecular structure, properties, biological activities, interactions, modifications, and functional properties. Papers must offer new and novel insights, encompassing related model systems, structural conformational studies, theoretical developments, and analytical techniques. Each paper is required to primarily focus on at least one named biological macromolecule, reflected in the title, abstract, and text.