砷化镓纳米结构对硅基薄膜太阳能电池的影响

IF 5.45 Q1 Physics and Astronomy
Arnab Panda , Kanik Palodhi , Prabhakar Sharma , Ritesh Kumar Mishra
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引用次数: 0

摘要

硅基薄膜太阳能电池性能不佳的主要问题是由于光程较短和吸收系数低而限制了光吸收。砷化镓纳米线可以通过增加光捕获和降低载流子复合率来大大提高其效率。本文详细研究了在硅基薄膜太阳能电池上嵌入砷化镓纳米线以提高其性能的方法。为了分析结构的光学和电学性能,分别采用时域有限差分法和有限元法。可见,纳米线的位置、取向、尺寸、周期、倾斜角度的变化以及活性物质掺杂浓度对转换效率和光吸收都有影响。为了获得最大的转换效率,对上述参数进行了优化。我们提出的结构在AM1.5 G标准太阳辐照度下的转换效率为17.25 %,短路电流密度为31.02 mA/cm2,开路电压为0.662 V,典型的7 µm × 5µm表面积和2µm厚的有源层中17%是GaAs, 83%是晶体硅。考虑到良好的结构稳定性,可以考虑将砷化镓纳米线生长在硅活性材料层上,并用苯并环丁烯(BCB)填充线隙。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of GaAs nanostructures on silicon based thin film solar cells
The limitation of optical absorption due to a shorter optical path and a low absorption coefficient are the main issues concerning the poor performance of silicon-based thin film solar cells. GaAs nanowires can greatly enhance their efficiency by increasing light trapping and decreasing carrier recombination rate. In this work, a detailed study is done to get an improvement of performance of silicon based thin film solar cell by embedding GaAs nanowire on this structure. To analyse the optical and electrical performance of the structures, finite difference time domain analysis and finite element method respectively are considered. It is seen that the conversion efficiency as well as optical absorption gets effected by the change in position, orientation, dimension, period and angle of inclination of nanowires and also the doping concentration of active material. In order to obtain maximum conversion efficiency, all mentioned parameters are optimised. Our proposed structure under AM1.5 G standard solar irradiance achieves a conversion efficiency of 17.25 % with short circuit current density 31.02 mA/cm2 and open circuit voltage 0.662 V for a typical 7 µm × 5 µm surface area and 2 µm thick active layer out of which 17 % is GaAs and 83 % is crystalline silicon. Considering the good degree of structural stability, GaAs nanowires are considered to be grown on silicon active material layer and the interwire gaps are filled with benzo cyclobutene (BCB).
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来源期刊
Nano-Structures & Nano-Objects
Nano-Structures & Nano-Objects Physics and Astronomy-Condensed Matter Physics
CiteScore
9.20
自引率
0.00%
发文量
60
审稿时长
22 days
期刊介绍: Nano-Structures & Nano-Objects is a new journal devoted to all aspects of the synthesis and the properties of this new flourishing domain. The journal is devoted to novel architectures at the nano-level with an emphasis on new synthesis and characterization methods. The journal is focused on the objects rather than on their applications. However, the research for new applications of original nano-structures & nano-objects in various fields such as nano-electronics, energy conversion, catalysis, drug delivery and nano-medicine is also welcome. The scope of Nano-Structures & Nano-Objects involves: -Metal and alloy nanoparticles with complex nanostructures such as shape control, core-shell and dumbells -Oxide nanoparticles and nanostructures, with complex oxide/metal, oxide/surface and oxide /organic interfaces -Inorganic semi-conducting nanoparticles (quantum dots) with an emphasis on new phases, structures, shapes and complexity -Nanostructures involving molecular inorganic species such as nanoparticles of coordination compounds, molecular magnets, spin transition nanoparticles etc. or organic nano-objects, in particular for molecular electronics -Nanostructured materials such as nano-MOFs and nano-zeolites -Hetero-junctions between molecules and nano-objects, between different nano-objects & nanostructures or between nano-objects & nanostructures and surfaces -Methods of characterization specific of the nano size or adapted for the nano size such as X-ray and neutron scattering, light scattering, NMR, Raman, Plasmonics, near field microscopies, various TEM and SEM techniques, magnetic studies, etc .
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