{"title":"库伦德MetaKaolin沸石- y催化剂工艺开发:实验数据建模、工艺优化、计算机辅助放大技术经济及沸石- y催化剂在生物柴油生产中的应用","authors":"Kazeem Kolapo Salam , Emmanuel Olusola Oke , Dauda Olurotimi Araromi , Mujidat Omolara Aremu , Christopher Tunji Oloyede , Idayat Adebukola Olowonyo , Monsuru Olatunji Dauda , Temitope Olabisi Adesina","doi":"10.1016/j.biteb.2025.102262","DOIUrl":null,"url":null,"abstract":"<div><div>Most existing studies on zeolite-Y synthesis remain at the laboratory-scale, limiting process design and industrial application. This study optimized key variables: acid concentration, quench time, and NaOH:KMK for the synthesis of zeolite-Y from the Kulende Metakaolin. The optimal zeolite-Y synthesis condition was simulated, scaled-up and its feasibility study was performed through Techno economic analysis. The synthesized zeolite-Y was tested in the transesterification process. Optimal conditions (65.97 % acid, 3.89 min quenching, and 1.99 NaOH:KMK) was used for zeolite-Y synthesis. The lab-optimized process was simulated and scaled up to 4000 kg/batch, achieving 104 batches/year, 0.65 kg/min production rate, and 5.8 million kJ total energy consumed. Techno-economic analysis confirmed feasibility, with a 15-year investment yielding a NPV of $9.59 million, 27.23 % IRR, and 27 % ROI. The synthesized zeolite-Y was successfully tested for biodiesel production, with both products respectively characterized. This study demonstrates that zeolite-Y from KMK is scalable, economically viable, and suitable for industrial biodiesel production.</div></div>","PeriodicalId":8947,"journal":{"name":"Bioresource Technology Reports","volume":"31 ","pages":"Article 102262"},"PeriodicalIF":0.0000,"publicationDate":"2025-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Process development of zeolite-Y-catalyst from Kulende MetaKaolin: Experimental data modelling, process optimization, computer-aided scale-up techno-economics and zeolite-Y-catalyst application for biodiesel production\",\"authors\":\"Kazeem Kolapo Salam , Emmanuel Olusola Oke , Dauda Olurotimi Araromi , Mujidat Omolara Aremu , Christopher Tunji Oloyede , Idayat Adebukola Olowonyo , Monsuru Olatunji Dauda , Temitope Olabisi Adesina\",\"doi\":\"10.1016/j.biteb.2025.102262\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Most existing studies on zeolite-Y synthesis remain at the laboratory-scale, limiting process design and industrial application. This study optimized key variables: acid concentration, quench time, and NaOH:KMK for the synthesis of zeolite-Y from the Kulende Metakaolin. The optimal zeolite-Y synthesis condition was simulated, scaled-up and its feasibility study was performed through Techno economic analysis. The synthesized zeolite-Y was tested in the transesterification process. Optimal conditions (65.97 % acid, 3.89 min quenching, and 1.99 NaOH:KMK) was used for zeolite-Y synthesis. The lab-optimized process was simulated and scaled up to 4000 kg/batch, achieving 104 batches/year, 0.65 kg/min production rate, and 5.8 million kJ total energy consumed. Techno-economic analysis confirmed feasibility, with a 15-year investment yielding a NPV of $9.59 million, 27.23 % IRR, and 27 % ROI. The synthesized zeolite-Y was successfully tested for biodiesel production, with both products respectively characterized. This study demonstrates that zeolite-Y from KMK is scalable, economically viable, and suitable for industrial biodiesel production.</div></div>\",\"PeriodicalId\":8947,\"journal\":{\"name\":\"Bioresource Technology Reports\",\"volume\":\"31 \",\"pages\":\"Article 102262\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bioresource Technology Reports\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2589014X25002440\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Environmental Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bioresource Technology Reports","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589014X25002440","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Environmental Science","Score":null,"Total":0}
Process development of zeolite-Y-catalyst from Kulende MetaKaolin: Experimental data modelling, process optimization, computer-aided scale-up techno-economics and zeolite-Y-catalyst application for biodiesel production
Most existing studies on zeolite-Y synthesis remain at the laboratory-scale, limiting process design and industrial application. This study optimized key variables: acid concentration, quench time, and NaOH:KMK for the synthesis of zeolite-Y from the Kulende Metakaolin. The optimal zeolite-Y synthesis condition was simulated, scaled-up and its feasibility study was performed through Techno economic analysis. The synthesized zeolite-Y was tested in the transesterification process. Optimal conditions (65.97 % acid, 3.89 min quenching, and 1.99 NaOH:KMK) was used for zeolite-Y synthesis. The lab-optimized process was simulated and scaled up to 4000 kg/batch, achieving 104 batches/year, 0.65 kg/min production rate, and 5.8 million kJ total energy consumed. Techno-economic analysis confirmed feasibility, with a 15-year investment yielding a NPV of $9.59 million, 27.23 % IRR, and 27 % ROI. The synthesized zeolite-Y was successfully tested for biodiesel production, with both products respectively characterized. This study demonstrates that zeolite-Y from KMK is scalable, economically viable, and suitable for industrial biodiesel production.