多道线偏振光谱仪,用于同时进行动态紫外-可见,偏振分辨-散射和光致发光测量

IF 4.6 Q1 CHEMISTRY, ANALYTICAL
Rongjing Yan, Qiang Hao, Pathum Wathudura, Max Wamsley, Willard E. Collier and Dongmao Zhang*, 
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引用次数: 0

摘要

动态系统,由其持续的时间演化所定义,是化学、生物学和材料科学进步的核心。利用光吸收、散射和发射的光学技术对于表征这些系统的结构和性质变化至关重要。然而,传统的光学工具,如紫外-可见光谱、荧光和散射技术,只能提供碎片化或不完整的见解,这使得全面理解动态过程并确保可靠的数据解释具有挑战性。在此,我们介绍了一种基于电荷耦合器件(CCD)的多道线偏振光谱仪(MLPS),设计用于同时进行动态紫外-可见、偏振分辨散射和光致发光测量。MLPS有助于同时定量散射和荧光强度和去极化,以及紫外-可见消光,具有亚秒级的时间分辨率。通过将高时间分辨率与捕获互补光谱的能力相结合,MLPS显着增强了光谱学的功能,为更广泛地应用于动态系统分析和推进跨多个科学学科的研究铺平了道路。此外,本文提出的仪器表征和数据预处理方法为未来多道ccd光谱仪的发展提供了有价值的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Multitrack Linearly Polarized Spectrometer for Simultaneous Kinetic UV–Vis, Polarization-Resolved- Scattering, and Photoluminescence Measurements

Dynamic systems, defined by their continuous temporal evolution, are central to advancements in chemistry, biology, and materials science. Optical techniques that leverage light absorption, scattering, and emission are essential for characterizing structural and property changes in these systems. However, conventional optical tools─such as UV–vis spectroscopy, fluorescence, and scattering techniques─provide fragmented or incomplete insights, making it challenging to comprehensively understand dynamic processes and ensure reliable data interpretation. Herein, we introduce a charge-coupled device (CCD)-based multitrack linearly polarized spectrometer (MLPS) designed for simultaneous kinetic UV–vis, polarization-resolved scattering, and photoluminescence measurements. The MLPS facilitates concurrent quantification of scattering and fluorescence intensities and depolarizations, alongside UV–vis extinction, with subsecond temporal resolution. By integrating high temporal resolution with the ability to capture complementary spectra, the MLPS significantly enhances the functionality of optical spectroscopy, paving the way for broader applications in dynamic system analysis and advancing research across multiple scientific disciplines. Furthermore, the instrument characterization and data preprocessing methodologies presented here provide valuable insights for the future development of multitrack CCD-based spectrometers.

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来源期刊
ACS Measurement Science Au
ACS Measurement Science Au 化学计量学-
CiteScore
5.20
自引率
0.00%
发文量
0
期刊介绍: ACS Measurement Science Au is an open access journal that publishes experimental computational or theoretical research in all areas of chemical measurement science. Short letters comprehensive articles reviews and perspectives are welcome on topics that report on any phase of analytical operations including sampling measurement and data analysis. This includes:Chemical Reactions and SelectivityChemometrics and Data ProcessingElectrochemistryElemental and Molecular CharacterizationImagingInstrumentationMass SpectrometryMicroscale and Nanoscale systemsOmics (Genomics Proteomics Metabonomics Metabolomics and Bioinformatics)Sensors and Sensing (Biosensors Chemical Sensors Gas Sensors Intracellular Sensors Single-Molecule Sensors Cell Chips Arrays Microfluidic Devices)SeparationsSpectroscopySurface analysisPapers dealing with established methods need to offer a significantly improved original application of the method.
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