{"title":"钙钛矿光伏中的微结构紊乱","authors":"Lifang Xie, Yuanyuan Zhou","doi":"10.1007/s11705-025-2600-z","DOIUrl":null,"url":null,"abstract":"<div><p>Perovskites have emerged as promising semiconductors for solar cells and optoelectronics. Despite rapid advancements in device performance over the past decade, a quantitative investigation into structure-property relationships remains absent. The core of these innovations in fabrication lies in controlling long-range and short-range microstructural disorders in perovskites, yet their systematic impact across multiple spatial scales remains underexplored. In this review, we elaborate on hidden microstructural disorders, including interfacial disorders and intra-crystal disorders, further delving into their formation mechanisms and effects on mechanical reliability and long-term operational stability of perovskites. Unraveling these effects requires a combined approach of theoretical modeling and experimental characterization. Furthermore, we discuss theory-driven engineering strategies to mitigate such microstructural disorders, enabling the predictable processing and fabrication of stable and high-efficiency perovskite solar cells. This review aims to establish a foundational framework for transitioning from microstructure observation to microstructure control, which represents a critical frontier in the advancement of perovskite photovoltaics.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 9","pages":""},"PeriodicalIF":4.5000,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11705-025-2600-z.pdf","citationCount":"0","resultStr":"{\"title\":\"Microstructural disorder in perovskite photovoltaics\",\"authors\":\"Lifang Xie, Yuanyuan Zhou\",\"doi\":\"10.1007/s11705-025-2600-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Perovskites have emerged as promising semiconductors for solar cells and optoelectronics. Despite rapid advancements in device performance over the past decade, a quantitative investigation into structure-property relationships remains absent. The core of these innovations in fabrication lies in controlling long-range and short-range microstructural disorders in perovskites, yet their systematic impact across multiple spatial scales remains underexplored. In this review, we elaborate on hidden microstructural disorders, including interfacial disorders and intra-crystal disorders, further delving into their formation mechanisms and effects on mechanical reliability and long-term operational stability of perovskites. Unraveling these effects requires a combined approach of theoretical modeling and experimental characterization. Furthermore, we discuss theory-driven engineering strategies to mitigate such microstructural disorders, enabling the predictable processing and fabrication of stable and high-efficiency perovskite solar cells. This review aims to establish a foundational framework for transitioning from microstructure observation to microstructure control, which represents a critical frontier in the advancement of perovskite photovoltaics.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":571,\"journal\":{\"name\":\"Frontiers of Chemical Science and Engineering\",\"volume\":\"19 9\",\"pages\":\"\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2025-07-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s11705-025-2600-z.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Chemical Science and Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11705-025-2600-z\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-025-2600-z","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Microstructural disorder in perovskite photovoltaics
Perovskites have emerged as promising semiconductors for solar cells and optoelectronics. Despite rapid advancements in device performance over the past decade, a quantitative investigation into structure-property relationships remains absent. The core of these innovations in fabrication lies in controlling long-range and short-range microstructural disorders in perovskites, yet their systematic impact across multiple spatial scales remains underexplored. In this review, we elaborate on hidden microstructural disorders, including interfacial disorders and intra-crystal disorders, further delving into their formation mechanisms and effects on mechanical reliability and long-term operational stability of perovskites. Unraveling these effects requires a combined approach of theoretical modeling and experimental characterization. Furthermore, we discuss theory-driven engineering strategies to mitigate such microstructural disorders, enabling the predictable processing and fabrication of stable and high-efficiency perovskite solar cells. This review aims to establish a foundational framework for transitioning from microstructure observation to microstructure control, which represents a critical frontier in the advancement of perovskite photovoltaics.
期刊介绍:
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.