沿海盐渍化土壤中微塑料的赋存特征及影响因素

Q2 Environmental Science
Wei-Ming Li, Lei Xu, Li-Chang Zhang, Cai-Ling Shi, Wen-Jun Xie
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引用次数: 0

摘要

微塑料在陆地和海洋环境中广泛存在。沿海土壤作为陆地与海洋的过渡地带,具有独特的微塑料污染特征。为揭示滨海土壤微塑料污染特征,以无棣县沿海不同盐渍化程度的土壤为研究对象。通过密度分离、氧化消化和微拉曼光谱技术分析了微塑料的分布特征及其与土壤理化性质的关系。采用污染物负荷指数法对其生态风险进行评价。结果表明:无地县沿海土壤51个采样点检测到微塑料,微塑料丰度在550 ~ 3 950 n·kg-1之间;聚乙烯(PE)、聚对苯二甲酸乙二醇酯(PET)、聚丙烯(PP)、聚苯乙烯(PS)和聚氯乙烯(PVC)分别占53.1%、13.9%、16.4%、8.4%和8.2%。微塑料的形状主要有薄膜状(占62.0%)、纤维状(占13.7%)、球形(占13.2%)和片状(占11.1%)。粒径小于1 000 μm的微塑料占85.0%。微塑料丰度在盐碱化程度最高的裸地中最低,在未盐碱化的棉田中最高。微塑料丰度与土壤盐渍化水平显著相关(P<;0.05)。随着盐水水平的升高,微塑料的总丰度以及薄膜、PE和PET微塑料的丰度显著降低(P<;0.05)。晶粒尺寸大于1 000 μm的微塑料比例显著降低(P<;0.05),但粒径小于100 μm的微塑料比例显著增加(P<;0.05)。这可能是由于不同土壤利用类型和不同盐碱度土壤中微塑料的不同来源造成的。土壤有机碳(SOC)与微塑料丰度呈显著正相关(P<;0.05)。所有土壤样品的风险负荷指数(PLI)在1.19 ~ 2.41之间,为低风险污染水平。其中高盐碱度荒地和裸地的PLI值较低,低盐碱度土壤的PLI值较高。研究结果可为了解滨海盐渍土微塑料污染状况,探索土壤性质与微塑料分布特征之间的关系提供重要依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[Occurrence Characteristics of Microplastics and Influencing Factors in Coastal Salinized Soil].

Microplastics are widespread in terrestrial and marine environments. As a transition zone between land and ocean, coastal soils have unique microplastic pollution characteristics. To reveal the characteristics of microplastic pollution in coastal soils, soils with different salinization levels were collected from Wudi County toward the sea. The distribution characteristics of microplastics and their relationship with soil physical and chemical properties were analyzed through density separation, oxidative digestion, and micro-Raman spectroscopy techniques. The pollutant load index method was used to assess its ecological risk. The results showed that microplastics were detected in 51 sampling points of coastal soil in Wudi County, and the abundance of microplastics ranged from 550 to 3 950 n·kg-1. Polyethylene (PE), polyethylene terephthalate (PET), polypropylene (PP), polystyrene (PS), and polyvinyl chloride (PVC) accounted for 53.1%, 13.9%, 16.4%, 8.4%, and 8.2%, respectively. The shapes of microplastics mainly included film (accounting for 62.0%), fiber (accounting for 13.7%), sphere (accounting for 13.2%), and sheet (accounting for 11.1%). Microplastics with grain size less than 1 000 μm accounted for 85.0%. The lowest abundance of microplastics appeared in the bare land with the highest degree of salinization, and the highest abundance appeared in the non-salinized cotton soil. The abundance of microplastics was significantly correlated with soil salinization levels (P< 0.05). With saline level increasing, the total abundance of microplastics and the abundance of film, PE, and PET microplastics decreased significantly (P< 0.05). The proportion of microplastics with grain size greater than 1 000 μm decreased significantly (P< 0.05), but the proportion of microplastics with grain size less than 100 μm increased significantly (P< 0.05). This may be because of the different soil use types and different sources of microplastics in soils with varied saline levels. Soil organic carbon (SOC) was significantly positively correlated with the abundance of microplastics (P< 0.05). The risk load index (PLI) values of all soil samples ranged from 1.19 to 2.41, which were low risk level pollution. Among them, the PLI values of wasteland and bare land with high saline level were lower, and the PLI values of soils with low saline level were higher. The results of this study can provide an important basis for understanding the microplastic pollution and exploring the relationship between soil properties and microplastic distribution characteristics in coastal saline soils.

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环境科学
环境科学 Environmental Science-Environmental Science (all)
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